Assessment of bioavailability and effects of chemicals due to remediation actions with caging mussels (Anodonta anatina) at a creosote-contaminated lake sediment site

A study was conducted at Lake J?ms?nvesi in Central Finland, to identify the potential ecotoxicological risks of the remediation operation of a creosote-/PAH-contaminated lake sediment, made by capping during the years 1998-1999. Mussels (Anodonta anatina) were deployed to the lake at the same time as the remediation operation was started in November 1998. The contaminated area (0.5 ha) was covered by a filter geotextile (polypropylene), gravel and sand (1-1.5m) which were spread out on the ice and let to sink onto the bottom of the lake when the ice melted in May 1999. The possible impacts of capping to the adjacent environment were assessed from mussels exposed and particulate material settled (SPM) to collectors placed on the lake bottom. Mussel tissue, SPM, the water inside the collector were analyzed for polycyclic aromatic compounds (PAH)-compounds. Biological endpoints included body condition, glycogen and protein contents of adductor muscle. Mussels and SPM exposed downstream to the contaminated site (Site 3) contained the highest total PAH concentrations. Biota-sediment accumulation factors of acenaphthene, phenanthrene, anthracene, fluoranthene, pyrene and benzo(a)anthracene of mussels varied from 0.79 to 1.45. The glycogen and protein concentrations were lowest in adductor muscle from mussels exposed to conditions at Site 3. Concentrations of some PAH-compounds were found distinctly increased adjacent to the remediated area, possibly due to the agitation of contaminated sediment due to the capping. It is also possible that resuspension of sediment around remediated area (containing some PAHs) spread the deposited PAH-compounds.     

Decision support by rapid simulation using simulation nets

The working of a tool, Simulation Nets, for designing and executing models for simulation of systems is presented. The tool is an extension of the theoretically attractive Petri Nets, whose suitability in general simulation modeling has largely been overlooked in the simulation community. Simulation Nets helps in obtaining a correct simulation model because of their good graphical properties, their strength in describing concurrent processes, and because of the possibility in proving correctness for some parts of the model by applying the well known reachability tree technique. The resulting graphical model consists of a number of submodels. The submodels are exact enough to permit simulation experiments to be performed without the need of programming. This permits easy incremental validation of the model, i.e., validation of the submodels and a hierarchy of coupled submodels. Simulation nets thus facilitates rapid modeling and experimentation and thus supports the decision maker in obtaining the data needed for him to make his decision. Experiences with a working prototype are presented.     

Performance evaluation of an automation system — determination of a benchmzrk process

An average “real” process is determined from 55 processes automated by an automation system. This a first step in developing realistic benchmark processes for making objective evaluation tests between the performance of different automation systems. The most important properties of the average process that are independent of the automation system used and that are important performance indicators are presented in the paper.The real process, representing the statistical mean of the process data best, is a papermachine with a pulp making department. The process has 141 analog inputs, 50 binary inputs, 90 analog outputs, 63 binary outputs, 77 motor controls, 8 motor value controls, 308 process interfaces, and 165 displays.     

A simple method to estimate the maximum nontrivial correlation of some sets of sequences

Code division multiple access and many other applications require large families of sequences with good correlation properties. In this paper we show that the moduli of certain character sums can be estimated in an easy way by using a method of Sidelnikov. These results yield a simple method to estimate the maximum nontrivial correlations of several well-known sets of sequences.Supported by the Technology Development Center of Finland, Elektrobit Company, Finnish Air Force, Nokia Mobile Phones Inc. and Nokia Cellular Systems Inc.Partially supported by the Academy of Finland     

Pentachlorophenol accumulation in the freshwater mussels Anodonta anatina and Pseudanodonta complanata, and some physiological consequences of laboratory maintenance

Freshwater mussels Anodanta anatina and Pseudanodonta complanata were exposed to (14C)-pentachlorophenol. The wet weight based bioconcentration factor (BCF = activity in animal per activity in water) at steady state varied from 80 to 120 for A. anatina and from 61 to 85 for P. complanata. The species did not differ significantly in their wet weight or lipid based BCFs but dry weight based values were significantly higher (40-50%) for A. anatina. The soft tissue dry weight and dry weight based condition index of A. anatina (Cl4 = soft tissue dry weight per shell length) differed significantly between natural mussel populations. In animals kept from 4 to 8 months in laboratory conditions, the soft tissue dry weight and glycogen content decreased more rapidly when mussels were maintained at 15 than at 5 degrees C. However, glycogen content in the digestive gland or adductor muscle did not differ in mussels maintained in the laboratory (5 degrees C) when compared to the natural population. The adductor muscle protein content differed between laboratory maintained animals and the natural population in Lake H?yti?nen but there was no difference in the soft tissue lipid content. Trace metal concentrations and calcium in the soft tissue were in general higher in laboratory maintained mussels. In addition, laboratory maintenance affected the reproductive cycle of A. anatina.     

A field methodology to study effects of UV radiation on fish larvae

There is a considerable lack of in situ specific information about the effects of UV-B radiation on limnic animals studied in the field. We exposed larval pike (Esox lucius L.) in two types of cuvettes (glass and quartz) placed at different depths (5 or 15 cm) to natural solar UV or to artificially enhanced UV-B (lamps on 3 h per day), simulating the scenarios for coming decades. Dose realism and comparability with earlier laboratory experiments was the main purpose, and therefore UV-B irradiances to the surface as well as underwater irradiances were directly measured. Result showed that UV-B dose rates in natural waters are low even though DOC concentration was low (4.8 mg/l) in our study lake. A slight increase in ambient UV-B dose rates was enough to cause neurobehavioral symptoms in pike larvae. However, the dose rates applied were inadequate to affect superoxide dismutase (SOD) or HSP70. While assessing the suggested risks due to increased UV, conclusions emphasize the importance of conducting field UV studies as supplements to laboratory experiments. We also recommend direct measurements of UV-radiation at sites where the target organisms are actually exposed.     

Detection of copper in water using on-line plasma-excited atomic absorption spectroscopy (AAS)

A measurement method and apparatus was developed to measure continuously toxic metal compounds in industrial water samples. The method was demonstrated by using copper as a sample metal. Water was injected into the sample line and subsequently into a nitrogen plasma jet, in which the samples comprising the metal compound dissolved in water were decomposed. The transmitted monochromatic light was detected and the absorbance caused by copper atoms was measured. The absorbance and metal concentration were used to calculate sensitivity and detection limits for the studied metal. The sensitivity, limit of detection, and quantification for copper were 0.45 ± 0.02, 0.25 ± 0.01, and 0.85 ± 0.04 ppm, respectively.     

Long Binary Narrow-Sense BCH Codes Are Normal

Let C be the binary narrow-sense BCH code of length where m is the order of 2 modulo n. Using characters of finite fields and a theorem of Weil, and results of Vladut-Skorobogatov and Lang-Weil we prove that the code C is normal in the non-primitive case if and in the primitive case if where the constant depends only on t. Received January 4, 1994