Synthesis,characterization and ion exchange properties of zirconium(IV) tungstoiodophosphate,a new cation exchanger

Zirconium(IV) tungstoiodophosphate has been synthesized under a variety of conditions. The most chemically and thermally stable sample is prepared by adding a mixture of aqueous solutions of 0·5 mol L⁻¹ sodium tungstate, potassium iodate and 1 mol L⁻¹ orthophosphoric acid to aqueous solution of 0·1 mol L⁻¹ zirconium(IV) oxychloride. Its ion exchange capacity for Na⁺ and K⁺ was found to be 2·20 and 2·35 meq g⁻¹ dry exchanger, respectively. The material has been characterized on the basis of chemical composition, pH titration, Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis. The effect on the exchange capacity of drying the exchanger at different temperatures has been studied. The analytical importance of the material has been established by quantitative separation of Pb²⁺ from other metal ions.     

用低成本FPGA实现HD／SD SDI收发器

引言HDTV、IPTV、VoD和YouTube市场不断扩大,与此同时,FPGA的功能也在增强,价格稳步下降,串行数字接口(SDI)标准定义了需要通过75Ω同轴电缆传送未压缩的数字视频信号,如果FPGA用于     

Performance analysis of multimedia based web traffic with QoS constraints

During the recent years, there has been a tremendous growth in the development and deployment of multimedia based networked applications such as video streaming, IP telephony, interactive games, among others. These applications, in contrast to elastic applications such as email and data sharing, are delay and delay jitter sensitive but can tolerate certain level of packet loss. A vital element of end-to-end delay and delay jitter is the random queueing delays in network switches and routers. Analysis of robust mechanisms for buffer management at network routers needs to be carried out in order to reduce end-to-end delay for traffic generated by multimedia applications. In this context, a threshold based buffer management scheme for accommodating multiple class multimedia traffic in network routers has been analysed. This technique effectively controls the allocation of buffer to various traffic classes according to their delay constraints. The forms of the joint state probabilities, as well as basic performance measures such as blocking probabilities are analytically established at equilibrium. Typical numerical experiments are included to illustrate the credibility of the proposed mechanism in the context of different quality of service (QoS) grades for various network traffic classes. This model, therefore, can be used as a powerful tool to provide a required grade of service to a particular class of multimedia based web traffic in any heterogeneous network.     

Optical,DC and AC electrical investigations of 4-hydroxy coumarin molecule as an organic Schottky diode

The current–voltage (I–V) and optical characteristics of 4-hydroxy coumarin Schottky diode were investigated. The conventional methods related with device were used to extract the various diode parameters. From dielectric study low dielectric constant and loss was observed. From its optical study, an indirect allowed transition is shown by this compound. The optical band gap (E _g ) was found to be around 3.78 eV. The observed properties shown by this molecule give a bright opportunity to explore its application for different organic devices.     

Experimental Investigations on Cryogenic Cooling in the Drilling of Titanium Alloy

In this study, a drilling experiment was conducted on titanium ASTM B265 Grade 2 material using PVD coated carbide inserts. Two types of coolants (Wet and LN₂) were used. The variables in the experiment were feed rate (f) and cutting speed (V_c). The depth of the drilling was constant. Cutting temperature (T), thrust force (F_t), surface roughness (R_a), and the hole quality (circularity, cylindricity, and perpendicularity) were analyzed. The tool wear and chip morphology were studied. The result of the experiment indicates that there is 6–59% reduction in cutting temperature when LN₂ is used, high thrust force values were recorded for LN₂ coolant condition, surface roughness (R_a) values were higher for LN₂ coolants. Hole quality is not favorable in LN₂ coolant supply.     

Structural and magnetic properties of Zn1-xcoxO nanorods prepared by microwave irradiation technique

We have successfully synthesized large-scale aggregative flowerlike Zn1-xCo(x)O (0.0 < or = x < or = 0.07) nanostructures, consisting of many branches of nanorods at different orientations with diameter within 100-150 nm (tip diameter approximately 50 nm) and length of approximately 1 microm. The rods were prepared using Zinc nitrate, cobalt nitrate and KOH in 180 Watt microwave radiation for short time interval. The synthesized nanorods were characterized using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), field emission transmission electron microscopy (FETEM) and DC magnetization measurements. XRD and TEM results indicate that the novel flowerlike nanostructures are hexagonal with wurtzite structure and Co ions were successfully incorporated into the lattice position of Zn ions in ZnO matrix. The selected area electron diffraction (SAED) pattern reveals that the nanorods are single crystal in nature and preferentially grow along [0 0 1] direction. Magnetic studies show that Zn1-xCo(x)O nanorods exhibit room temperature ferromagnetism. This novel nanostructure could be a promising candidate for a variety of future spintronic applications.     

Scattering of Electromagnetic Waves by a Coated Nihility Cylinder

An analytical solution for the scattering of electromagnetic plane waves from an infinitely long nihility cylinder, coated with a double positive (DPS), double negative (DNG), epsilon negative (ENG), or mu negative (MNG) layer of uniform thickness is presented. The solution is determined by solving the scalar wave equation in the cylindrical coordinates, for different regions and applying the appropriate boundary conditions at the interfaces. Both TM and TE polarizations as incident plane have been considered in the analysis. Comparison of behaviors of a coated nihility cylinder with a coated PEC cylinder has been made. It is noted that two situations are more closer for DNG coating as compared to DPS coating.     

Observer-based leader-following consensus of one-sided Lipschitz multi-agent systems over input saturation and directed graphs

This paper investigates a local observer-based leader-following consensus control of one-sided Lipschitz (OSL) multi-agent systems (MASs) under input saturation. The proposed consensus control scheme has been formulated by using the OSL property, input saturation, directed graphs, estimated states, and quadratic inner-boundedness condition by attaining the regional stability. It is assumed that the graph always includes a (directed) spanning tree with respect to the leader root to develop matrix inequalities for investigating parameters of the proposed observer and consensus protocols. Further, a new observer-based consensus tracking method for MASs with saturation, concerning independent topologies for communicating outputs and estimates over the network, is explored to deal with a more perplexing and realistic situation. In contrast to the traditional methods, the proposed consensus approach considers output feedback and deals with the input saturation for a generalized class of nonlinear systems. The efficiency of the obtained results is illustrated via application to a group of five moving agents in the Cartesian coordinates.     

为以太网服务扩展SPI4.2功能

引言由于载体和电缆供应商开始为客户大量提供三重播放和VoD服务,原始设备制造商投入更多的精力大量生产基于IP(Internet协议)的系统,包括PON、CMTS、IP DSLAM、多服务交换、其