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排序方式: 共有390条查询结果,搜索用时 0 毫秒
1.
Two lignite samples, Beulah No. 3 and Big Brown No. 1, were liquefied at 420 °C using H2 and synthesis gas to determine the optimum beneficial amount of H2S in the batch autoclave reactor. Under the conditions employed, 50–100 psi partial pressure of H2S, nominally 4–10 wt% of daf lignite, was optimum for both samples. Synthesis gas outperformed H2 with and without H2S for the liquefaction of the two coals. 相似文献
2.
Patricia Mortreau Reinhard Berndt 《Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment》2004,530(3):559-567
The traditional method used to non-destructively determine the uranium enrichment with an NaI detector is based on the “enrichment meter principle” (Progress report LA-4605-MS, Los Alamos National Laboratory, NNM, 1970, p. 19), which involves measuring the intensity of the 186 keV line of 235U by selecting two regions of interest for the peak and the background. This type of method suffers from several limitations, the most limiting of which are the impossibility to make wall thickness correction or to take the inference of foreign radioisotopes into account. The NaIGEM software (A guide for using NaIGEM code, version 1.5 for DOS and Windows, 2001; Nucl. Instr. and Meth. A 458 (2001) 196) was developed to overcome these limitations by calculating the 186 keV line intensity with a fitting procedure. The code was tested in different measurement conditions on the wide variety of certified samples, in particular, on reprocessed uranium and on depleted material with thick steel filters interposed between the source and the detector. The results are presented to illustrate the performance and limitations of the tested version (A guide for using NaIGEM code, version 1.5 for DOS and Windows, 2001). The general performance is good except in the case of low-enriched uranium in thick containers. 相似文献
3.
The interactions of VOHPO4· 0.5H2O and (VO)2P2O7 with the ammoxidation feed and the single components such as ammonia, oxygen, water and component mixtures were studied in detail using XRD and temperature-programmed reaction spectroscopy. The aim of this work was to improve the knowledge of the formation of the active phases or active sites of the catalysts from their precursors under the condition of the ammoxidation reaction. Similar catalytic properties of various applied VPO materials were discussed in terms of the presence of similar structure elements (domains of adjacent edge-sharing VO6 octahedra-units and P-O-NH4 groups). 相似文献
4.
Woo Y. Lee † F Kevin M. Cooley† Christopher C. Berndt ‡ Debra L. Joslin † David P. Stinton † 《Journal of the American Ceramic Society》1996,79(10):2759-2762
The potential application of Ca05Sr05Zr4P6O24 (CS50) as a corrosion-resistant coating material for Si-based ceramics and as a thermal barrier coating material for Ni-based superalloys was explored. A ∼200 (xm thick CS50 coating was prepared by air plasma spray with commercially available powder. A Nicalon/SiC ceramic matrix composite and a Ni-based superalloy coated with a ∼200 (xm thick metallic bond coat layer were used as substrate materials. Both the powder and coating contained ZrP2O7 as an impurity phase, and the coating was highly porous as-deposited. The coating deposited on the Nicalon/SiC substrate was chemically stable upon exposure to air and Na2SO4/O2 atmospheres at 1000°C for 100 h. In contrast, the coating sprayed onto the superalloy substrate significantly reacted with the bond coat surface after similar oxidation in air. 相似文献
5.
6.
7.
EVALUATION OF A METHOD FOR MEASURING MIXING TIME USING NUMERICAL SIMULATION AND EXPERIMENTAL DATA 总被引:10,自引:0,他引:10
Martin Lund n Olle Stenberg Bengt Andersson 《Chemical Engineering Communications》1995,139(1):115-136
A method for measuring mixing performance in large-scale vessels is investigated. The method is evaluated experimentally in a pilotscale reactor and by using a model based on the three-dimensional calculation of the flow field. The method is based on injection of a tracer and measuring the concentration with several detectors at different locations. The mixing performance is measured as the decay rate of the difference between the concentration at the detectors and the final concentration.
The model predicts a strong dependence on injection point. The assumption of a first-order decay rate of the concentration deviation is more appropriate for some injection points. 相似文献
The model predicts a strong dependence on injection point. The assumption of a first-order decay rate of the concentration deviation is more appropriate for some injection points. 相似文献
8.
The reaction pathway of the ammoxidation of toluene on (VO)2P2O7 used as catalyst and the interaction of potential intermediates with the pyrophosphate were studied by spectroscopic techniques (FTIR, EPR), temperature-programmed chemisorptions/ reactions (TPD, TPRS) and transient studies such as the temporal analysis of products (TAP) technique. NH3 is chemisorbed on the catalyst surface, forming three different species, i.e., NH
4
+
ions located on BrØnsted sites, coordinatively bound NH3 on Lewis sites and NH
2
–
groups, presumably P-NH2. Toluene that is probably adsorbed on Lewis sites reacts in a first step to a benzyl radical. A subsequent partial oxidation by interaction of VIV=O groups generates a V...O=CH-C6H5 surface structure. This benzaldehyde-like surface species reacts with adsorbed NH3 according to a Langmuir-Hinshelwood mechanism. TAP experiments on ammonium-containing vanadium phosphates revealed that NH
4
+
ions could act as potential N-insertion species. No formation of benzylamine as well as the generation of V=NH surface groups as possible intermediates or N-insertion sites were observed. 相似文献
9.
Urethanes of cellobiose and cellulose-containing uretdione groups are synthesized by the reaction of aliphatic and aromatic diisocyanate uretdiones with the saccharides. The syntheses are performed as a heterogeneous reaction in dimethyl acetamide using dibutyl tin dilaurate as a catalyst, as well as a homogeneous reaction in dimethyl acetamide-lithium chloride. Thus, Semisynthetic prepolymers are formed that offer the reactivity of (blocked) isocyanate groups. To demonstrate their reactivity, ring opening of the uretdiones is performed by the addition of a secondary amine to yield the corresponding ureas. 相似文献
10.
F. Y. Yan K. A. Gross G. P. Simon C. C. Berndt 《Polymer Engineering and Science》2004,44(8):1448-1459
Polymer‐ceramic composite coatings manufactured from calcium carbonate and ethylene‐methacrylic acid copolymer (EMAA) were prepared via a thermal spray process employing different CaCO3 filler sizes (average size of 2.8, 9 or 36 μm) and loading levels from about 2.5 to 7 wt%. The optimum filler feeding characteristics, deposition efficiency and deposition rate were obtained with a 36 μm sized CaCO3. Tensile properties, peel strength, and the erosion resistance of a pure EMAA and CaCO3‐EMAA composite coatings were investigated. It was found that the tensile strain at fracture of the composite coating decreased with the addition of filler to a greater degree than that observed in compression‐molded polymer composites. This is attributed to an inhomogenous distribution of the filler, with more being concentrated at the boundaries of the deposited polymer particles, thereby establishing a rigid framework within the coating. Only a small filler content is necessary to establish large changes in the mechanical properties of the coating. The peel strength of a composite coating decreases with filler content, both on a mild steel substrate and a previously sprayed polymer coating. Bonding to the latter is significantly higher and offers a possibility as a bonding layer between substrates and composite coatings. The coefficient of friction is lowered with the addition of a filler. Erosion testing has shown that the erosion resistance of PF111 is little improved overall with filler addition, although some increase is found for filler contents less than 5 vol%. Polym. Eng. Sci. 44:1448–1459, 2004. © 2004 Society of Plastics Engineers. 相似文献