邻菲罗啉-硫氰酸钾-水体系液固分离钴(Ⅱ)

当分析元素含量极低时,往往要求在测定之前辅以化学分离预富集手段以纯化富集待测物和除去干扰基体。实验利用邻菲罗啉和硫氰酸钾作为微痕量Co²⁺的络合剂,建立了一种液固体系分离富集微痕量Co²⁺的新方法。分别考察了邻菲罗啉溶液用量、硫氰酸钾溶液用量、酸度对分离效率的影响。结果表明,当体系中Co²⁺含量为100 μg时,控制体系pH=2~6,加入1.00 mL 1.5 g/L邻菲罗啉溶液、1.00 mL 0.1 mol/L硫氰酸钾溶液、1.00 mL 10 g/L EDTA溶液、1.00 mL 40 g/L硫脲溶液,震荡静置后,Co²⁺与邻菲罗啉、硫氰酸钾反应生成的离子缔合物定量沉淀到溶液底部,而Cd²⁺、Fe³⁺、Zn²⁺、Ni²⁺、Cu²⁺、Pb²⁺、Al³⁺、Ag⁺等离子仍留在水相中,从而实现了Co²⁺与这些离子的定量分离。方法成功用于合成水样中微痕量Co²⁺的定量分离,富集率在97.2%～98.6%之间。     

Effect of Mode of Drying on Microstructure of Potato

Potato v. Irga was subjected to blanching, and thereafter was dried by convection, puff-drying, and freeze-drying. Microstructure of raw, blanched, and dried tissue was analyzed under the light microscope using computer image analysis. It was found that the tissue of the investigated variety is built up from cells much smaller than those described in literature for other cultivars. Blanching caused starch gelatinization and increase of cross-sectional area of cells. There was no evidence of broken cell walls. Convective drying resulted in cell shrinkage and some breaking of cell walls. It was estimated that some 12% of cells lost integrity during drying. Limited disintegration of the tissue caused by convective drying is attributed to small size of cells, large contact area, and high cohesive forces between cells. Puff-drying damaged the tissue much more than the convective drying. The most devastating to tissue microstructure was freeze-drying, probably freezing per se.     

循环冷却水系统无垢低腐蚀率的技术改进

泸天化公司大氮肥循环冷却水系统投用以来，经优选水稳剂配方、改进加氯方式、增设旁滤池、提高补充水质量等措施，年腐蚀率从0．3366mm降至0．0241mm，换热器运行一年无结垢现象。     

物联网环境下移动边缘计算安全问题

物联网时代多类型流量的接入与应用场景的多样性,从计算能力、存储和业务时延等多个方面对当前集中式云计算架构提出新的挑战.移动边缘计算(MEC)作为一种在网络边缘为用户提供服务的解决方案,能够满足物联网多样性的业务需求.针对移动边缘计算在物联网中的安全问题,对移动边缘计算的概念、应用场景和安全进程进行介绍,着重从数据传输安全、存储安全和计算安全3个方面阐述了移动边缘计算在物联网时代所面临的安全挑战.     

新型雨水径流计量用复合堰的设计及率定

针对其他流量计量方法不易监测雨水径流流量的问题,提出一种新型复合堰,用于测量雨水径流流量,新设计的堰由下部三角形堰和上部矩形堰复合而成。根据不同重现期下的雨水峰值流量,确定堰的量程和基本尺寸。通过率定试验,得出不同水头下的流量系数以及流量-水头关系曲线。新型复合堰不仅可以精确测量小流量,而且对大流量也可有效测量,具有较高的量程比和较大的泄流能力。     

一种基于聚类分析的R~*树结点重叠判定算法

聚类分析可以对大量空间对象进行聚类划分,优化R*树的结点.根据R*树的强制重插原则,在聚类分析基础上提出一种扩展MBR的对角线段对相交算法以判定类结点的重叠.从根本上改变以往在解决R*树结点重叠时仅将MBR形状改变或单纯紧致正交MBR所存在的问题,以此为判定条件可以控制聚类算法迭代次数,减少噪声点对聚类的影响.其中判定算法时间复杂性为O(nlogn)级.实验结果表明在范围查询中引入基于聚类分析的对角线段对相交判定算法的查询效率优于基于R*树的Gain/Loss度量的贪婪算法和基于SR树的算法的查询效率.     

Ultrahigh Energy Storage Capacitors Based on Freestanding Single-Crystalline Antiferroelectric Membrane/PVDF Composites

Inorganic/organic dielectric composites are very attractive for high energy density electrostatic capacitors. Usually, linear dielectric and ferroelectric materials are chosen as inorganic fillers to improve energy storage performance. Antiferroelectric (AFE) materials, especially single-crystalline AFE oxides, have relatively high efficiency and higher density than linear dielectrics or ferroelectrics. However, adding single-crystalline AFE oxides into polymers to construct composite with improved energy storage performance remains elusive. In this study, high-quality freestanding single-crystalline PbZrO₃ membranes are obtained by a water-soluble sacrificial layer method. They exhibit classic AFE behavior and then 2D–2D type PbZrO₃/PVDF composites with the different film thicknesses of PbZrO₃ (0.1-0.4 µm) is constructed. Their dielectric properties and polarization response improve significantly as compared to pure PVDF and are optimized in the PbZrO₃(0.3 µm)/PVDF composite. Consequently, a record-high energy density of 43.3 J cm⁻³ is achieved at a large breakdown strength of 750 MV m⁻¹. Phase-field simulation indicates that inserting PbZrO₃ membranes effectively reduces the breakdown path. Single-crystalline AFE oxide membranes will be useful fillers for composite-based high-power capacitors.     

Virtual RF system platform dedicated to heterogeneous complex SoC design

In this paper, we propose to develop a hierarchical library associated with various simulators that can be used in a single platform, called TrustMe-ViP, which enables a unique simulation framework and full model interoperability. Such platform is dedicated to complex SoC design, such as trusted personal devices where cost and time-to-market are very important constraints. To validate this methodology, we present the estimation of BER and power consumption for a Bluetooth transceiver.