Palladium(II) complexes with Pd2S2 rings. Synthesis and theoretical characterization of [Pd2(dppe)2(μ-S)2] and X-ray characterization of [Pd3(dppe)3(μ3-S)2]Cl2

The use of the dppe ligand and the fine tuning of the experimental conditions has allowed isolation of [Pd₂(dppe)₂)(μ-S)₂], whose structural characterization has been achieved by ab initio MP2 calculations, and of [Pd₃(dppe)₃(μ₃-S)₂]Cl₂, the X-ray structure of which is also reported.     

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