Behavior of ZrO2-C Refractories in Thin-strip Casting of Steel

Zirconia graphite refractory is used as a core-nozzle in the thin-strip casting of steel. Post-mortem analysis of used refractory was performed in an effort to establish the failure mechanism. Corrosion behavior was studied against molten steel with Mn O- SiO 2based liquid inclusions. Corrosion of these materials involves dissolution and oxidation of graphite in the matrix followed by penetration of liquid slag leading to degradation of ZrO 2particles. Thermodynamic equilibrium calculations were performed to study this corrosion mechanism.     

酸酐法合成乙酸酯类物质的一种新型催化体系的研究

以DMAP+I_2作为催化体系,考察了其在叔丁醇与乙酸酐的酰化反应中的催化性能,实验结果表明,该催化剂可使乙酸酐与高位阻的叔丁醇顺利进行酯化反应,乙酸叔丁酯收率可高达70%以上,并且反应条件温和、催化体系易被回收和重复使用。同样通过实验验证该催化体系也可高效作用于正丁醇、仲丁醇与乙酸酐的反应。DMAP+I_2催化体系经核磁共振、质谱仪进行表征分析,发现DMAP和碘单质之间发生了配位或者酸碱反应,重复反应多次,催化剂组分没有发成改变。     

WAVE INTERACTION WITH PERFORATED CAISSON BREAKWATERS

The reflection coefficient of perforated caissons and the total horizontal forces acting on them were experimentally and numerically analyzed and discussed when wave propagates normally. To consider the viscosity effect of fluid and nonlinear action of waves on structures, the VOF (Volume Of Fluid) method combined with the k-ε turbulence model was used to simulate the interaction between waves and structures. Governing equations were solved with the finite difference method. Through 2D experimental study in the wave flume, the empirical relationship between the reflection coefficient of perforated caissons and the main affecting factors were obtained from the experimental data using the least square method. Also the correlation between the ratio of the total horizontal force acting on perforated caisson and the force acting on solid caisson and the main affecting factors were regressed from the experimental data.     

Charge： Glowing in the Dark

Many areas of structure analysis have focused on finding the locations of the atoms. If, instead of the atoms, we knew the positions of the electrons we would in fact know much more, and in most respects knowing where the nuclei are is not important. There is a long history of measurements using precise electron diffraction or X-ray diffraction of the average charge density in materials, but extending beyond to local charge density is, as yet, an unexplored area.     

多媒体的未来:与通信技术相结合

一、多媒体必须与通信技术相结合目前，多媒体计算机的发展方兴未艾，性能不断提高，几乎每星期都有新产品问世，但是，多媒体迄今尚未得到普及。     

可全部取回的小井眼伽马随钻测量(MWD)系统可将水平钻井的风险减至最小

一种特别适用于水平井实时大地转向的小井眼伽马定向测量MWD工具已研制成功。这是第一个能利用钢丝全部取回并进行更换的测量系统。它可以将卡钻和“井内花费”的风险减至最小。此外,它还可以将因发生故障而更换工具需要进行的起下钻次数减至最少,从而降低钻井成本。 该系统可以下入内径小到2.19英寸(56mm)和钻铤内,且已经下入过外径为3(1/2)英寸(89mm)的钻铤。它还下入过钻井作业用的盘管内。 本文将介绍井下系统及其校准方法,并与普通绳索测井进行比较。 文中还介绍了几个现场水平井应用的实例,着重说明如何利用伽马射线使水平泄油井“大地转向”而保持在油层内,以及如何在钻井期向跟踪地层倾角的方向。这样做可以减小水平钻井的风险,增大收回投资的可能性。     

纳米SiOx对乙酸乙烯酯乳胶漆性能影响之初探

通过一定的表面处理方法对纳米SiOx进行表面改性处理后,将其按不同的比例添加到乙酸乙烯酯反应的分散介质中,经聚合反应制备得到乙酸乙烯酯乳胶漆;将适量的纳米SiOx按照纳米尺寸均分散于乙酸乙烯酯乳胶漆中,能有效地提高其耐洗涮性、剪切强度,并能明显缩短其成膜干燥时间,对施工涂装性能和其它技术指标无不良影响。     

气体运移速率的现场实例

由 5个油田的现场实例说明 ,最近的研究向传统的气体流入 (气体侵入井内 )概念提出了挑战。以往现场人员一直使用“经验法则” ,即气体以 10 0 0ft h的速率运移。但现场实例表明 ,气体可能移动 ,也可能不移动 ,其运移速率受多种因素影响 ,同时建议不能完全依赖井口压力增加来准确分析和预测气体运移特征