Drying Kinetics of a Porous Spherical Particle and the Inversion Temperature

A model is presented for drying of a single porous particle with superheated steam and humid air. Experimental data for spherical porous ceramic particle reported in the literature were used for the validation of the model. An inversion temperature at which the evaporation rates within superheated steam and humid air are equal was predicted. The effect of thermophysical properties of the particle (permeability 10^-14 - 10^-17 m², diameter 3 × 10^-3 - 10 × 10^-3 m) and operating variables (gas mass flux 0.26 - 0.78 kg m^-2 s^-1, drying agent temperature 120-200°C) is tested. The inversion temperature is shown to be affected by the thermophysical properties of the porous particle and of the drying agent.     

Graphic approach for the determination of the existence of sequences guaranteeing observability of switched linear systems

This paper deals with the design of sequences allowing the observability of the state of a switched linear system. The proposed method, based on a graph-theoretic approach, needs only the knowledge of the system’s structure. The necessary and sufficient conditions for the existence of at least one switching sequence guaranteeing the observability of a switched structured system are provided. Such conditions are particularly intuitive and they can be implemented with classic algorithms of the graph theory.     

Methodology for WEEE assessment in Algeria

Waste electrical and electronic equipment (WEEE) generated in emerging countries is increasing. This study presents a methodology to improve assessment and monitoring WEEE in Algeria. The proposed methodology is a two-step approach. The first step is the collection and collation of existing data from different national and international sources. In the second step, different assessment and forecasting methods are applied. Forecasting methods were selected from those models which provided minimum error indices. The paper considers also the availability and reliability of data in order to provide a future reliable assessment of WEEE in Algeria. The study revealed that the forecasting methods do not have a big influence on the results contrary to the inputs of the model.     

N-3 Polyunsaturated Fatty Acids Modulate In-Vitro T Cell Function in Type I Diabetic Patients

In this work, we assessed the in-vitro effects of eicosapentaenoic acid (EPA; C20:5n-3) and docosahexaenoic acid (DHA; C22:6n-3) (final concentration, 15 microM) on T cell blastogenesis, interleukin-2 and -4 (IL-2, IL-4) secretion, fatty acid composition and intracellular oxidative status in type I diabetic patients with or without complications. Con A stimulated lymphocyte proliferation, glucose uptake, intracellular reduced glutathione levels and catalase activity were lower in diabetics as compared to controls, regardless to the presence of complications. EPA and DHA diminished T-lymphocyte proliferation and IL-2 production but enhanced IL-4 secretion in both diabetic and control groups. No changes in the levels of reduced glutathione and in the activities of catalase and SOD were observed in control T cells cultured in the presence of EPA and DHA. However, in diabetic patients, addition of n-3 PUFA to culture induced an increase in T cell levels of reduced glutathione and hydroperoxide, and in activities of catalase and SOD. Low levels of arachidonic acid (C20:4n-6) were found in plasma membrane phospholipids of lymphocytes from diabetic patients compared to controls. Incubation of lymphocytes with EPA and DHA was associated with an incorporation of these fatty acids in membrane phospholipids. In conclusion, the beneficial effects of n-3 PUFA on T cell functions in type I diabetes could be attributed to their suppressive action and modulation of cytokine secretion, and to the improvement of intracellular oxidative status.     

Tubular shaped composites made from polythiophene covalently linked to Prato functionalized N-doped carbon nanotubes

A simple methodology to produce tubular nitrogen-doped carbon nanotube/polythiophene covalently linked composites is described. Nitrogen doped carbon nanotubes (N-CNTs) were made by the floating catalyst CVD method using toluene, ferrocene and tetramethylethylenediamine (TMEDA) as reagents. Functionalization of the N-CNTs was achieved using 3-thiophenecarboxaldehyde and N-methylglycine in 1,2-dichlorobenzene (Prato reaction). Elemental analysis showed nitrogen incorporation of N into the N-CNTs (1.8%) and also the N-methylglycine functionalized N-CNTs (f-N-CNTs; 6.2%). A series of f-N-CNT/thiophene monomer mixtures (weight ratios 1:3, 1:10 and 1:20) were used to make f-N-CNT/polythiophene tubular composites. As the amount of thiophene monomer was increased, the overall diameter of the polymer layer attached onto the N-CNTs increased. Polymer thickness also varied with reaction time (1 h, 12 h and 24 h). The combination of acid functionalization and N–doping gives the best coverage of the CNTs by polythiophene, in which the polythiophene preferentially binds to the f-N-CNTs to give tubular structures.     

Influence des fumées de silice sur l’évolution de l’hydratation des pâtes de chaux ou de Ciment Portland

The silica fume (SF) is used in civil engineering, in particular for the manufacture of high performance concrete.In order to better understand the gain in strength of the concretes containing SF, the microstructural aspect has been examined.Mixtures of SF–Lime pastes present a hydraulic setting which is due to the formation of a C–S–H phase (calcium silicate hydrate). The latter is semi-crystallized. It is characterized by the lines of X-ray diffraction, hk0 such as: 3,06 Å (220), 2,80 Å (400) and 1,83 Å (040).The mix design SF–Lime paste is thus a simplified approach of that of the mixtures SF–OPC in which the main reaction is the fixation, by the SF, of lime coming from the hydration of C₃S in the form of C–S–H.Tests have been carried out on two varieties of SF resulting from the same furnace with the presence of lime or Portland cement. The results show that the presence of certain impurities, by their actions on the solubility of silica plays a significant role on the evolution of the hydration of the principal components of Portland cements and the kinetics of lime fixation by the SF.Among the impurities contained in the SF, carbon delays considerably the hydration of the principal components of Portland cement (C₃S and C₃A) as well as the pozzolanic reactivity of the silica fume without removing it.     

Ring-opening Metathesis Co-polymerization of a C60-cyclopentadiene Cycloadduct and Norbornene with the Grubbs Second-generation Catalyst

A series of C₆₀-containing polymers were synthesized by the co-polymerization of a C₆₀-cyclopentadiene cycloadduct and norbornene in varying ratios. The polymerization was facilitated by a catalytic amount of Grubbs second generation catalyst and the co-polymers formed were investigated by spectroscopic and thermal techniques.