Design optimization of 3D reinforced concrete structures

This paper presents a computer-based method for the optimal design of three-dimensional reinforced concrete (RC) skeletal structures having members subjected to biaxial moments, biaxial shears and axial loads. The width, depth and area of longitudinal reinforcement of member sections are taken as the design variables. The optimality criteria (OC) method is applied to minimize the cost of the concrete, steel and formwork for the structure. The primary focus of the paper concerns fundamental issues related to the formulation of design performance constraints on combined axial load, biaxial moments and biaxial shears. An example problem is solved with and without account for biaxial shear constraints to illustrate their influence on the design.     

Highly efficient synthesis of coumarin derivatives in the presence of H14[NaP5W30O110] as a green and reusable catalyst

A variety of heteropolyanions including: Keggin, Dawson, Preyssler, mixed addenda and sandwich types, catalyzed the formation of 4-methylnaphtho-(1,2-b)-pyran-2-one (coumarin) from the condensation of α-naphthol and ethylacetoacetate in a solvent free system and under heating conditions. Our data vividly indicate that sodium30–tungsto pentaphosphate, [NaP₅W₃₀O₁₁₀]¹⁴⁻, which so-called Preyssler’s anion, with high hydrolytic (pH 0–12) and thermal stability is the catalyst of choice. This catalyst catalyzed the synthesis of other coumarin derivatives in high yields and good selectivity.     

Design optimization of 3D reinforced concrete structures having shear walls

This paper presents a computer-based method for the optimal design of three-dimensional Reinforced Concrete (RC) structures having beams subjected to shear force and bending moment, columns subjected to biaxial moments, biaxial shears and axial loads, and shear walls subjected to pure shear. Regarding the beams and columns, the design variables are the width, depth and area of longitudinal reinforcement of member sections. The design variables for the shear walls are the thickness of the wall, the area of vertical reinforcement, horizontal distance between the vertical stirrups, the area of horizontal reinforcement, vertical space between the horizontal stirrups, and the area of vertical flexural reinforcement. The Optimality Criteria (OC) method is applied to minimize the cost of the concrete, steel and formwork for the structure. ACI code [1] provisions concerning the strength and ductility of beams, columns and shear walls are taken as constraints. The constraints also impose upper and lower bounds on the dimensions of beams and columns, and on shear wall thickness, reinforcement area and the maximum and minimum vertical and horizontal spaces between the stirrups of the shear walls. Sensitivity analysis is conducted for both internal forces and the capacities of the sections of the beams, columns and shear walls. The features of the design method are illustrated by a solved example.     

Highly efficient synthesis of benzopyranopyridines via ZrP2O7 nanoparticles catalyzed multicomponent reactions of salicylaldehydes with malononitrile and thiols

ZrP₂O₇ nanoparticles as an efficient catalyst have been used for the preparation of benzopyrano[2,3-b]pyridines from the four-component condensation reaction of salicylalde-hydes, thiols, and 2 equiv. of malononitrile under reflux conditions in ethanol in excellent yields and short reaction times.     

Nickel‐Catalyzed Reductive Benzylation of Aldehydes with Benzyl Halides and Pseudohalides

The reductive benzylation of aromatic and aliphatic aldehydes with benzylic halides is reported using a nickel/zinc catalyst system. In addition to benzylic halides, the first report on the addition of benzylic triflates, acetates, tosylates and tritylates to aldehydes is also presented. By this new method a range of alcohols was synthesized efficiently from aldehydes and benzylic substrates at room temperature in moderate to high yields. The mild reaction conditions and good functional group tolerance make this nickel‐catalyzed process synthetically useful for the synthesis of diverse benzylic alcohols.

     

Effect of ionic strength on the reactivity ratios of acrylamide/acrylic acid (sodium acrylate) copolymerization

The ionic strength (IS) of polyelectrolyte solutions plays an important role in influencing reaction kinetics. The largely unstudied effect of IS on monomer reactivity ratios and copolymerization rates of acrylamide (AAm) and acrylic acid (AAc), in the form of sodium acrylate (NaAc), is investigated. Salt addition affects the nature of overall charges of the polyelectrolyte solution and diminishes the electrostatic repulsions between reacting chains. Therefore, changing the IS of the solution by incorporating salts affect not only the point estimates of the monomer reactivity ratios but also the overall behavior of the copolymerization (with a transition to azeotropic behavior). Experimental results on copolymerization rates confirm the observed trends in reactivity ratio behavior. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40949.     

A CUSUM-based method for monitoring simple linear profiles

In most statistical process control applications, the quality of a process or product is characterized by univariate or multivariate quality characteristics and monitored by the corresponding univariate and multivariate control charts, respectively. However, sometimes, the quality of a process or a product is better characterized by a relationship between a response variable and one or more explanatory variables. This relationship, which can be linear, nonlinear, or even a complicated model, is referred to as a profile. So far, several methods have been proposed for monitoring simple linear profiles. In this paper, a new method based on cumulative sum statistics is proposed to enhance monitoring of linear profiles in phase II. The performance of the proposed method is evaluated by average run length criterion. A comprehensive comparison is also conducted between the performance of the proposed method and the existing methods for monitoring simple linear profiles. The results show that the proposed method performs satisfactorily. In addition, the effects of reference value, sample size, and corrected sum of squares of explanatory variables on the performance of the proposed method are investigated.