Charge transfer resistance of spray deposited and compressed counter electrodes for dye-sensitized nanoparticle solar cells on plastic substrates

Electrochemical impedance spectroscopy was used to determine the effective charge transfer resistances of porous dye-sensitized solar cell counter electrodes prepared by low-temperature spray deposition and compression of conductive carbon and platinized Sb-doped SnO₂ powders on indium tin oxide-coated plastic substrates. The charge transfer resistances were 0.5–2 and 8–13 Ω cm², respectively, when using 3-methoxypropionitrile as the electrolyte solvent. The manufacturing method used lends itself to produce mechanically stable and even-quality electrodes in an easy and fast manner.     

无动力处理方式在农村生活污水处理中的应用

论述了北方某镇采用无动力处理技术处理农村生活污水的方法,工艺流程为新型化粪池-人工湿地-氧化塘工艺。运行结果表明,工程出水中污染物日均浓度COD为35~55 mg/L、BOD5为10~20 mg/L、SS为5~18mg/L、氨氮为3~5 mg/L,均能达到《农田灌溉水质标准》(GB 5084-2005)中蔬菜a标准。处理后的出水用于周边农田灌溉,既治理了污染,又节约了资源,是绿色、低碳城镇建设的一个典范,非常适合北方乡镇新农村建设的生活污水处理和利用。     

Comparison of molecular changes in lung cancers in HIV-positive and HIV-indeterminate subjects

CONTEXT: Human immunodeficiency virus (HIV) infection has been associated with an increasing incidence of malignancy, and HIV-infected persons have an increased incidence of primary lung carcinoma compared with the general population. OBJECTIVE: To investigate the molecular changes present in HIV-associated lung tumors and compare them with those present in lung carcinomas arising in HIV-indeterminate subjects ("sporadic tumors"). DESIGN: Convenience sample. SUBJECTS: Archival tissues from 11 HIV-positive persons and from 35 persons of indeterminate HIV status. SETTING: University-based medical centers and affiliated hospitals. MAIN OUTCOME MEASURES: Analysis of frequency of loss of heterozygosity (LOH) and microsatellite alteration (MA) using polymerase chain reaction and 16 polymorphic microsatellite markers at 8 chromosomal regions frequently deleted in lung cancer. Presence of HIV and human papillomavirus (HPV) sequences. RESULTS: The overall frequency of LOH at all chromosomal regions tested and the frequencies at most of the individual regions were similar in the 2 groups. Frequency of MA present in the HIV-associated tumors (0.18) was 6-fold higher than in sporadic tumors (0.03) (P<.001). At least 1 MA was present in 10 (91%) of 11 HIV-associated tumors vs 17 (48%) of 35 sporadic tumors (P=.02). Molecular changes were independent of tumor stage and gender. HIV and HPV sequences were not detected in the HIV-associated lung carcinomas. CONCLUSIONS: Microsatellite alterations, which reflect widespread genomic instability, occur at greatly increased frequency in HIV-associated lung carcinomas. Although the mechanism underlying the development of increased MAs is unknown, it may play a crucial role in the development of many HIV-associated tumors.     

Effect of Anisotropy and Destructuration on the Behavior of Murro Test Embankment

This paper investigates the influence of anisotropy and destructuration on the behavior of a test embankment on soft clay. The test embankment at Murro, Finland, was commissioned in 1993 by the Finnish Road Administration and has been monitored for over 10?years. The construction and consolidation of Murro test embankment is analyzed with finite element method using three different constitutive models to represent the soft soil. The results are compared with field observations. The constitutive models used include two recently proposed constitutive models, namely S-CLAY1 that accounts for initial and plastic strain induced anisotropy and its extension, called S-CLAY1S. The S-CLAY1S model accounts, additionally, for interparticle bonding and degradation of bonds. For comparison, the test embankment is also analyzed using the isotropic Modified Cam Clay model. The simulations demonstrate that for this type of problem, it is important to account for the anisotropy, whereas destructuration appears to have less influence on predicted deformations. However, only a model incorporating destructuration can explain the decrease in undrained shear strength during consolidation that was measured in field.     

一种配网单相接地选线的频带自适应获取方法

小电流接地系统单相故障选线中,目前频带的选择方法中被广泛采用的是首容性频带方法,但是这种方法易受配网运行方式、线路参数不精确等因素的影响。为了克服以上缺点,提出一种基于矩阵束算法的配电网单相接地选线频带自适应获取方法。频带下限在不接地系统中为0,经消弧线圈接地为150 Hz;频带上限的确定方法为首先通过矩阵束算法提取各出线零序电流的共有频率以及对应的相位,然后找到满足相位关系的最大频率,此最大频率就是频带的上限。PSCAD仿真和故障录波验证了该方法在各种故障情况下的有效性。此方法有望提高小电流接地系统单相接地故障时的选线正确率。     

Introducing the prebound effect: the gap between performance and actual energy consumption

German regulations for the thermal renovation of existing homes demand high thermal standards, which the government claims are technically and economically feasible. This paper examines existing data on 3400 German homes; their calculated energy performance ratings (EPR) are then plotted against the actual measured consumption. The results indicate that occupants consume, on average, 30% less heating energy than the calculated rating. This phenomenon is identified as the ‘prebound’ effect and increases with the calculated rating. The opposite phenomenon, the rebound effect, tends to occur for low-energy dwellings, where occupants consume more than the rating. A similar phenomenon has been recognized in recent Dutch, Belgian, French and UK studies, suggesting policy implications in two directions. Firstly, using a dwelling's energy rating to predict fuel and CO₂ savings through retrofits tends to overestimate savings, underestimate the payback time and possibly discourage cost-effective, incremental improvements. Secondly, the potential fuel and CO₂ savings through non-technical measures such as occupant behaviour may well be far larger than is generally assumed in policies so policy-makers need a better understanding of what drives or inhibits occupants' decisions.

La réglementation allemande relative à la rénovation thermique des logements existants exige des normes thermiques élevées, que le gouvernement prétend être techniquement et économiquement applicables. Cet article examine les données existantes sur 3400 logements allemands; leurs classes d'efficacité énergétique (CEE) calculées sont ensuite comparées à la consommation réelle mesurée. Les résultats indiquent que les occupants consomment, en moyenne, 30 % d'énergie de chauffage en moins que la classe calculée. Ce phénomène est identifié en raison de l'accroissement de l'effet de « pré-bond » avec la classe calculée. Le phénomène opposé, l'effet de rebond, tend à se produire dans les logements à basse consommation d'énergie, dans lesquels les occupants ont une consommation supérieure à la classe. Un phénomène similaire a été reconnu dans des études récentes néerlandaises, belges, françaises et britanniques, suggérant des implications en termes de politiques dans deux directions. En premier lieu, l'utilisation de la classe énergétique d'un logement pour prévoir les économies de combustible et de CO₂ pouvant être obtenues grâce à des rénovations a tendance à surestimer les économies, à sous-estimer le délai d'amortissement et éventuellement à dissuader d'effectuer des améliorations incrémentielles rentables. En second lieu, les économies potentielles de combustible et de CO₂ pouvant être obtenues par des mesures non techniques telles que le comportement des occupants peuvent se révéler être bien plus importantes que cela n'est supposé en règle générale dans les politiques, de sorte que les décideurs ont besoin de mieux comprendre ce qui motive ou empêche les décisions des occupants.

Mots clés: performance des bâtiments, rénovations thermiques, politique climatique, classe énergétique, politique énergétique, comportement de consommation énergétique     

Improvement of actuation performance of dielectric elastomers by barium titanate and carbon black fillers

Dielectric elastomers are promising materials for actuators resembling human muscle. Among elastomers, acrylic rubbers (ACM) have shown good actuation performance but its use is limited by the high operating voltages required. The present work demonstrates that simultaneous incorporation of nanostructured carbon black and dielectric fillers offers an increase in a dielectric permittivity and a suitable modulus of the elastomers matrix, enabling an improved electro‐mechanical actuation performance at low voltages. By the use of reinforcing carbon black and barium titanate in an acrylic elastomer matrix a sixfold increase in the dielectric permittivity was realized. A fine tuning of the actuation stress and, consequently, actuation strain can be done by a judicial selection of the different filler concentrations in the soft rubber matrix. Finally, a synergistic effect of the fillers was observed in the improved actuation performance of the developed materials. This work may pave the way to design dielectric elastomers for actuator fabrication. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44116.     

An analysis of students’ spontaneous computer-mediated help seeking: A step toward the design of ecologically valid supporting tools

This study analyzes middle school students’ spontaneous mathematics-related help-seeking behavior, in view of making ecologically valid recommendations for the design of supporting tools or “help systems”. Our aim was to investigate the content of students’ help-seeking messages – Are there different forms of help-seeking messages and do they evolve with age? We used the archives of a French forum that provides students with free individualized help in mathematics. The data consisted of 206 messages sent by French middle school students over a period of 42 months. The constituent categories of the messages were identified. The results showed that not all middle school students use the same help-seeking “format”. Compared to sixth graders, ninth graders wrote messages containing more constituent categories, i.e., they provided the online expert with more kinds of information. A detailed analysis of the categories further showed that older students’ messages more often contained explicit help requests and contextual information than did younger students’ messages. Thus, the messages of the oldest students (age 15) were both cognitively more understandable and socially more acceptable than those of the youngest students (age 11). The interpretation of these findings and their implications for designing help systems are discussed.     

Use of adipose stem cells and polylactide discs for tissue engineering of the temporomandibular joint disc

There is currently no suitable replacement for damaged temporomandibular joint (TMJ) discs after discectomy. In the present study, we fabricated bilayer biodegradable polylactide (PLA) discs comprising a non-woven mat of poly(L/D)lactide (P(L/D)LA) 96/4 and a P(L/DL)LA 70/30 membrane plate. The PLA disc was examined in combination with adipose stem cells (ASCs) for tissue engineering of the fibrocartilaginous TMJ disc in vitro. ASCs were cultured in parallel in control and chondrogenic medium for a maximum of six weeks. Relative expression of the genes, aggrecan, type I collagen and type II collagen present in the TMJ disc extracellular matrix increased in the ASC-seeded PLA discs in the chondrogenic medium. The hypertrophic marker, type X collagen, was moderately induced. Alcian blue staining showed accumulation of sulphated glycosaminoglycans. ASC differentiation in the PLA discs was close to that observed in pellet cultures. Comparison of the mRNA levels revealed that the degree of ASC differentiation was lower than that in TMJ disc-derived cells and tissue. The pellet format supported the phenotype of the TMJ disc-derived cells under chondrogenic conditions and also enhanced their hyalinization potential, which is considered part of the TMJ disc degeneration process. Accordingly, the combination of ASCs and PLA discs has potential for the development of a tissue-engineered TMJ disc replacement.     

Tissue reactions of subcutaneously implanted mixture of ε-caprolactone-lactide copolymer and tricalcium phosphate. An electron microscopic evaluation in sheep

Biodegradable polymers, mainly derivates of -hydroxy acids, are widely used today in oral- and maxillofacial surgery, orthopedics, and other fields of surgery. These biomaterials are well tolerated by living tissue and fracture fixation devices made of polylactic or polyglycolic acid are clinically widely used today. Still, there are some problems in application of biodegradable polymers. Abacterial inflammatory reactions have been noticed after the clinical introduction of these devices. Both swelling and pain at the site of implantation have also been reported. The etiology of this inflammatory reaction is still unknown, despite the numerous studies. Therefore, the aim of the present study was to further characterize this inflammatory reaction in detail, by electronmicroscopy. We prepared a mixture of -caprolactone–lactide copolymer and tricalcium phosphate and placed it in the dermis in 12 sheep. Follow-up times were 9, 14, 24, and 52 weeks. We found that the mixture caused a mild inflammatory reaction. There were no signs of cell damage. Fibroblasts, macrophages, and eosinophils were found adjacent to the copolymer. The mixture is easy to handle and can be moulded into different shapes in room temperature. The results encourage us to continue our studies to develop a filling material for bone defects.