Improvement of flexural bond strength of zirconia-resin cement by surface patterning using sub-nanosecond UV laser

Zirconia is a dental material that shows excellent biocompatibility and high strength in clinical applications. This study aims to evaluate the effects of ultrafast laser applications. The surface nanostructures were classified into three groups. Group 1 was generated using the burst mode, with three different distances between dots: 52 µm (Group 1a), 104 µm (Group 1b), and 156 µm (Group 1c). Group 2 was processed using the scanning mode configuration, with a set of parallel lines. Group 3 was also processed using this scanning configuration creating a set of square-shaped patterning. Group 4 was the control group. After the surface treatments, a pair of zirconia specimens was bonded end to end with resin cement. Flexural bond strength (FBS) test was applied in a universal test machine. Multiple comparisons were performed using a one-way analysis of variance and the Tukey's HSD test. All the samples that were treated with the laser showed higher FBS values than the untreated surface. Using the burst mode, preformed circular-shaped surface on an angle of 90⁰ at 52 µm distance (Group 1a) showed the highest FBS values among all groups (p < .05). Groups 2 and 3 had significantly higher values than 1b and 1c.     

Estimation of Peak Flood Discharges at Ungauged Sites Across Turkey

The reliable forecasting of the peak flood discharge at river basins is a common problem, and it becomes more complicated when there is inadequate recorded data. The statistical methods commonly used for the estimation of peak flood discharges are generally considered to be inadequate because of the complexity of this problem. Recently, genetic programming (GP) which is a branch of soft computing methods has attracted the attention of the hydrologists. In this study, gene-expression programming (GEP) and linear genetic programming (LGP), which are extensions to GP, in addition to logistic regression (LR) were employed in order to forecast peak flood discharges. The study covered 543 ungauged sites across Turkey. Drainage area, elevation, latitude, longitude, and return period were used as the inputs while the peak flood discharge was the output. Model comparison results revealed that GEP predicted the peak flood discharges with R ²?=?57.4?% correlation, LGP with 56?% and LR model with 42.3?%, respectively. The peak flood discharges in all river basins can now be determined using the single equation provided by the GEP model.     

Electrically controlled release of 5-fluorouracil from conductive gelatin methacryloyl-based hydrogels

Herein, electro-responsive hydrogels were obtained by incorporation of poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT/PSS) into the gelatin methacryloyl (GelMA) by using photopolymerization technique. Hydrogels were characterized by FTIR and scanning electron microscopy analyses. Cytotoxicity tests were performed by L929 cell lines to determine cell compatibility. Swelling tests were conducted to investigate the water uptake capacity of hydrogels. 5-fluorouracil (5-FU) was selected as a model drug as it is known as a topical drug for some skin cancer type treatment. The release of 5-FU from the hydrogel was provided in efficient and controlled manner at simulated skin cancer (pH = 5.5) and under 0 and 1.5 V. The simulated drug delivery experiments conducted in vitro revealed that the drug releasing amount was higher when voltage is applied to the hydrogels. All results visualized that the obtained GelMA-based PEDOT/PSS hydrogels with enhanced electrical properties could be a potential candidate as an electrically sensitive drug carrier for treatment of skin cancer in the future applications. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 46914.     

Using of Photoluminescent Tile for Evacuation of the Buildings During Electrical Failure

Photoluminescent pigments could be successfully applied on the wall tiles, floor tiles and porcelain tiles as well as glass substrates （glass mosaics, borders, and cutted glass with various designs）. For this applications, these products can be used for different purposes. In this study, these pigments are applied on the ceramic tiles and glass mosaics/tiles with traditional ceramic production line. These products are intentended to provide guidance in the event of a power failure. With this study also aimed to prevent potential accidents and injury during evacuation of building.     

The Water-Soluble Peripheral Substituted Phthalocyanines as Corrosion Inhibitors for Copper in 0.1 N HCl: Gravimetric,Electrochemical, SEM-EDS,and Quantum Chemical Calculations

Protection of Metals and Physical Chemistry of Surfaces - Corrosion inhibition effects of water-soluble peripheral substituted cobalt, copper and zinc metallophthalocyanines (CoPc (1), CuPc (2) and...     

Geochemical characteristics of major and trace elements in Sahinali Coals,Aydin, Turkey

In this study, geochemical behavior of elements is investigated in 25 coal samples collected at 10 locations of ?ahinli coaliferous units at southeast of Ayd?n, Turkey. In all the samples, X-ray powder diffraction and inductively coupled plasma mass spectrometry analyses were performed and element and mineral compositions were determined. Total organic carbon (TOC) values of coals are between 14.6 and 37.7 wt% with average of 28.5 wt%. Samples are composed of quartz, calcite, feldspar, dolomite, mica, gypsum, and salt minerals which are accompanied by illite-, kaolinite-, and smectite-type clay minerals. Comparison of average element contents of world coals and studied samples yields that K > Fe > As > U > Cs > Y > Er > Al > Th > Rb > Yb > W > Tb > Dy > Lu > Ce > Sm > La > Ho > Si > Nd > Gd > Tm > Eu > Nb > Pr > Pb > Sn > Ni > Cu > Ga > Ta > Sb > Zr > Cd > V > Zn > Co > Mo > P > Hf > Ba are found to be enriched, while Mn > Be > Ca > Sr > Bi > Mg are found to be depleted. Statistically elements are correlated with TOC.     

Immobilization Horseradish Peroxidase onto UiO-66-NH2 for Biodegradation of Organic Dyes

Enzymes are extensively used as catalyst in several fields of production such as chemistry, and pharmaceuticals owing to their selectivity, efficiency and environmentally friendliness. However, their applications are often hindered due to their insufficient stability and difficulties in re-use. As a member of porous crystalline materials, metal organic frameworks are a promising enzyme carrier due to their multi-functional pore surfaces and robustness in variety of harsh conditions. In this study, the horseradish peroxidase (HRP) enzyme was immobilized onto UiO-66-NH₂ (Universitetet i Oslo) by a facile incubation method at the room temperature to improve the stability and reusability of enzyme. The prepared HRP@UiO-66-NH₂ bio-composite was characterized by using FT-IR, XRD and SEM. The crystal structure of MOF was well-preserved after enzyme immobilization. A colorimetric assay for enzyme activity after released from UiO-66-NH₂ has been employed based on the catalytic oxidation of phenol coupled with 4-aminoantipyrine. The robustness and activity of immobilized enzyme after released from UiO-66-NH₂ were investigated by biodegradation of methyl orange (MO) and methylene blue (MB) with several parameters such as pH, temperature, the dosage of H₂O₂ and the dye concentration with comparison to its free form. The optimum condition for dye degradation was obtained at basic conditions. The immobilized enzyme maintained its activity at elevated temperature while free enzyme lost its activity at the same conditions, attributed to the armoring effect of UiO-66-NH₂. According to the results of studied various parameters, MO and MB were biodegraded to 60% and 45%, respectively, within 60 min with the optimum conditions at pH 9 and 50 °C at a H₂O₂ dosage of 3%. The superior pH tolerance and stability suggest potential of UiO-66-NH₂ immobilized peroxidase enzyme in industrial applications.

     

A dwell time approach to the stability of switched linear systems based on the distance between eigenvector sets

In this article, a sufficient condition on the minimum dwell time that guarantees the stability of switched linear systems is given. The proposed method interprets the stability of switched linear systems through the distance between the eigenvector sets of subsystem matrices. Thus, an explicit relation in view of stability is obtained between the family of the involved subsytems and the set of admissible switching signals.