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1.
Passive air sampling using semipermeable membrane devices at different wind-speeds in situ calibrated by performance reference compounds 总被引:1,自引:0,他引:1
Semipermeable membrane devices (SPMDs) are passive samplers used to measure the vapor phase of organic pollutants in air. This study tested whether extremely high wind-speeds during a 21-day sampling increased the sampling rates of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), and whether the release of performance reference compounds (PRCs) was related to the uptakes at different wind-speeds. Five samplers were deployed in an indoor, unheated, and dark wind tunnel with different wind-speeds at each site (6-50 m s(-1)). In addition, one sampler was deployed outside the wind tunnel and one outside the building. To test whether a sampler, designed to reduce the wind-speeds, decreased the uptake and release rates, each sampler in the wind tunnel included two SPMDs positioned inside a protective device and one unprotected SPMD outside the device. The highest amounts of PAHs and PCBs were found in the SPMDs exposed to the assumed highest wind-speeds. Thus, the SPMD sampling rates increased with increasing wind-speeds, indicating that the uptake was largely controlled by the boundary layer at the membrane-air interface. The coefficient of variance (introduced by the 21-day sampling and the chemical analysis) for the air concentrations of three PAHs and three PCBs, calculated using the PRC data, was 28-46%. Thus, the PRCs had a high ability to predict site effects of wind and assess the actual sampling situation. Comparison between protected and unprotected SPMDs showed that the sampler design reduced the wind-speed inside the devices and thereby the uptake and release rates. 相似文献
2.
Lijana Augulyte Daina Kliaugaite Viktoras Racys Dalia Jankunaite Audrone Zaliauskiene Per-Anders Bergqvist Patrik L. Andersson 《Journal of hazardous materials》2009,170(1):997
The efficiency of a biologically activated carbon system for treating wastewater polluted with petroleum products was examined and the effects of process parameters on its efficacy were evaluated. In each experiment 17 alkylated and 19 non-alkylated polycyclic aromatic hydrocarbons (PAHs) and total petroleum hydrocarbons (TPHs, C10–C40) were extracted using semipermeable membrane devices from wastewater before and after treatment. The acquired data during experiments were analyzed using principal component analysis (PCA). The treatment system robustly removed dissolved PAHs across the studied ranges of the process parameters, providing overall removal efficiencies of 96.9–99.7% for the sum of 36 PAHs. However, the major contributor to their removal was sorption rather than biodegradation, and despite the general efficiency of the process there was up to a 9-fold range in the sums of quantified PAHs in the effluents between experiments. Combinations of long process contact time (24 h) with high temperature (24 °C) and moderate oxygen concentration (6–7 mg O2 L−1) resulted in good removal of bioavailable PAHs. The removal of TPHs was more dependent on biological activities during the wastewater treatment, and consequently more dependent on the process parameters. In addition, small but significant proportions of PAHs were volatilized and released during the wastewater treatment. 相似文献
3.
Per-Anders Carlsson Magnus Skoglundh Erik Fridell Edward Jobson Bengt Andersson 《Catalysis Today》2002,73(3-4):307-313
The effect of gas composition changes on the low temperature activity for supported platinum model catalysts has been studied. By introducing well-controlled periodic O2 pulses to a simple diluted gas mixture of CO and O2, a substantial improvement of the low temperature oxidation activity was observed. The reason for low activity on noble metals at low temperatures is often attributed to self-poisoning by CO. The improved catalytic performance observed is proposed to origin from the transients causing a surface reactant composition that is favourable for the reaction rate, i.e. lower degree of self-poisoning. This was also confirmed by in situ Fourier transform infrared (FT-IR) spectroscopy in combination with mass spectrometry (MS) measurements, which gave evidence for the existence of a strong interplay between the gas phase concentration and the adsorbate composition for these catalysts. 相似文献
4.
The work reported in the present paper constitutes a part of a project on simulation of springback in sheet metal forming. Previous work in this project has been concentrated on material modeling and characterization with focus on springback applications. It has been demonstrated that, with proper considerations of all aspects of the material model and the material properties, excellent springback results can be obtained for simple problems. At the simulation of real, industrial parts, a number of additional problems are encountered. Many of these problems are associated with deviations from nominal geometries and other properties. These are examples of factors that influence the outcome of the forming process, but are unknown to the analyst, and can therefore not be considered in the simulation of the forming process. Other phenomena are known to exist, but due to their complexity, they are practically impossible to consider in industrial simulations. Examples of such phenomena are the true frictional behavior in contacts between the blank and the tools, and the flexibility of the press and the forming tool. The influence of these kinds of effects is discussed in the present paper. In the current study, a semi-industrial tool, specially designed to catch those springback problems that are encountered in the forming of real industrial, parts, is used. The tool includes several characteristics that can be found in typical forming tools, such as several draw radius steps and change-over in section geometries. Effects like flange/wall angle changes, sidewall curl and twist are obtained at springback. The sensitivity of the predicted springback is evaluated with respect to various numerical factors, such as the friction coefficient, the material model, and the mesh density. Finally, the quality of the predicted springback behavior for four different materials, commonly used in the automotive industry, is evaluated. 相似文献
5.
Carolin Wang-Hansen Per Ericsson Björn Lundberg Magnus Skoglundh Per-Anders Carlsson Bengt Andersson 《Topics in Catalysis》2013,56(1-8):446-451
The reactivity and reaction kinetics of particulate matter (PM) from direct injected gasoline (GDI) engines has been studied by O2 and NO2 based temperature programmed and isothermal step-response experiments, and the PM nano-structure has been characterized using HRTEM. The reactivity of the PM samples collected in filters during on-road driving was found to increase in the following order: Printex U < diesel < gasoline PI ≈ gasoline DI < ethanol for O2 based combustion. The activation energies for O2 and NO2 based oxidation of PM collected from a GDI engine in an engine bench set-up was estimated to 146 and 71 kJ/mol respectively, which is comparable to corresponding values reported for diesel and model soot. Similar nano-structure features (crystallites plane dimensions, curvature and relative orientation) as observed for diesel soot were observed for gasoline PM. 相似文献
6.
Ivar Sagefors Per-Anders Daerga 《Tunnelling and Underground Space Technology incorporating Trenchless Technology Research》1996,11(3):279-285
Construction of underground storage chambers in rock has traditionally adopted a construction-oriented approach; the cavern design and the method of excavation have been governed by the capabilities of the equipment available. One example is oil storage in unlined horizontal caverns. Today, however, equipment is no longer a limiting factor. The time has come to integrate the construction and operational aspects in the design process. This paper presents a construction concept developed for large vertical rock caverns with a circular or elliptical horizontal cross-section. The method of excavation, called PBM (Pillar Blasting Method), is condensed into a few main operations which are geometrically separated but overlapping in time. PBM is characterized by two main working sites per cavern, and by long-hole bench-drilling, massive blasting rounds, continuous loading and easy ventilation. Recent developments in drilling and blasting techniques are incorporated, such as the water-driven in-the-hole hammer and the electronic ignition system. PBM enables a high rate of excavation and provides a satisfactory working environment with respect to labour safety and human health (a limited exposure to large openings, no exposure to oil mist and to combustion and explosive fumes, etc). Considerable construction cost savings and time savings may thus be achieved compared to conventional methods of excavation for vertical and horizontal caverns of equal storage volume. A preliminary PCT patent (application No PCT/SE95/00324) has been granted. Examples of applications are fresh-water reservoirs, natural gas reservoirs, subsurface hydroelectric pump power plants, and similar objects which require a large underground storage space in preferably unlined rock caverns. 相似文献
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8.
Markus Happel Lisa Kylhammar Per-Anders Carlsson Jrg Libuda Henrik Grnbeck Magnus Skoglundh 《Applied catalysis. B, Environmental》2009,91(3-4):679-682
The SOx storage and release kinetics on CeO2 have been studied by lean SOx adsorption and temperature programmed desorption for different pairwise configurations of individual monolith samples, i.e., Pt/CeO2 + SiO2, Pt/SiO2 + CeO2, CeO2 + Pt/SiO2 and CeO2 + SiO2. In the case of sole ceria, SOx adsorption proceeds both via SO2 and SO3 adsorption although the latter channel is kinetically favored. Hence, the rate of SO2 oxidation is crucial for the overall SOx storage kinetics. It is also found that physical contact between Pt and ceria is important for the storage process. This is attributed to efficient transport routes for SOx (surface diffusion and spill-over processes) and/or specific adsorption sites at the platinum–ceria interface. The main route for SOx release is found to be thermal decomposition where the effect of platinum is minor, although an indirect effect cannot be ruled out. Different mechanistic scenarios for SOx adsorption are discussed, which may serve as a guide for future experiments. 相似文献
9.
Zheng F Alayoglu S Guo J Pushkarev V Li Y Glans PA Chen JL Somorjai G 《Nano letters》2011,11(2):847-853
In-situ near edge X-ray absorption fine structure spectroscopy was performed to monitor the oxidation states of Co and CoPt nanoparticles (NPs) of 4 nm size in the presence of H(2) and O(2) in the pressure range of 1 bar and 36 Torr respectively. Platinum helps the rapid reduction of cobalt oxides in hydrogen at a rather low temperature (38 °C). In addition, reversible changes of the oxidation states of cobalt in the Co and CoPt NPs as a function of cycling oxygen pressure (in the range of millitorr to 36 Torr) are quantified and compared. The role of Pt in the process of Co reducing and oxidizing was explored. Our findings permit the prediction of the cobalt oxidation states as the reaction conditions are altered. The experimental results also suggest the presence of tetrahedral structure of Cobalt oxide that differs from the Co(3)O(4) spinel structure. 相似文献
10.
The present work is a study of reentrainment of a tracer gas formaldehyde via six rotary air-to-air heat exchangers (all enthalpy exchangers) in the northern part of Sweden. Five exchangers installed in office buildings and one in a day-care centre were included in the study. Formaldehyde in indoor was used as a monitor pollutant and was determined in air samples collected in the ducts at four positions around the rotor of the exchanger, in the supply-air duct and in the exhaust-air duct. Air sampling of homogeneous duct air was performed simultaneously at the four positions using 2, 4-dinitrophenylhydrazine-impregnated glass fibre filters. The sample analysis of formaldehyde was made by high-performance liquid chromatography. The reentrainment of formaldehyde was calculated and found to be 1-9%. These results show that a rotary heat exchanger can be used in buildings where activities produce low levels of air pollutants, provided that the exchanger is properly installed and maintained. 相似文献