Electronic transport behavior of 4,6-bis(4-nitrophenyl)-2-phenyl-3,5-diaza-bicyclo[3.1.0]hex-2-ene (a bicyclic aziridine) as optical molecular switch: a first-principles approach

Journal of Computational Electronics - In this study, the electronic transport properties of 4,6-bis(4-nitrophenyl)-2-phenyl-3,5-diaza-bicyclo[3.1.0]hex-2-ene (as a bicyclic aziridine) have been...     

Flexible Triboelectric Nanogenerator Based on High Surface Area TiO2 Nanotube Arrays

Triboelectric nanogenerators (TENGs) can harvest mechanical energy through coupling triboelectric effect and electrostatic induction. Typically, TENGs consist of organic materials, however on account of the potentially wide range of applications of TENGs as the self‐powered portable/wearable electronics, biomedical devices, and sensors; semiconductor metal oxide materials can be promising candidates to be incorporating in TENG structure. Here, flexible TENG based on self‐organized TiO₂ nanotube arrays (TNTAs) is fabricated via anodization method. The introduced flexible large area nanotubular electrode is employed as the moving electrode in contact with Kapton film in vertical contact separation mode of TENG. The fabricated TENG can deliver output voltage of 40 V with the current density of 1 μA cm^?2. To evaluate the role of nanostructured interface, its performance has been compared to the thin film flat compact TiO₂ electrode. The results of extracted charge measurements under short circuit condition indicate that larger triboelectric charge density formed in TNTA‐based electrode (about 110 nC per cycle of press and release) is in comparison to 15 nC in flat TiO₂ electrode. Due to the extensive range of applications of TiO₂, the introduced structure can potentially be applicable in various types of self‐powered systems such as photo‐detectors and environmental gas and bio‐sensors.

     

Nano ZrP2O7 Catalyzed Multicomponent Reaction for an Easy Access of 4H-pyrans and 1,4-dihydropyridines

ZrP₂O₇ nanoparticle catalyzed one-pot synthesis of 4H-pyran scaffolds installing a one-pot three-component coupling reaction of an aldehyde, malononitrile, and ethyl acetoacetate. Also the synthesis of 1,4-dihydropyridines was investigated by using aldehydes, ethyl acetoacetate and ammonium acetate as utilizing nano structured ZrP₂O₇ as an efficient catalyst in ethanol. The attractive features of this process are mild reaction conditions, reusability of the catalyst, short reaction times, easy isolation of the products, and excellent yields.     

Interfacial Reactions Between BaAl2Si2O8 and Molten Al Alloy at 850°C

A corrosion cup test was undertaken using BaAl₂Si₂O₈ and Al4.1Zn3.2Mg alloy, heated in air for 150 h at 850°C. Electron probe microanalysis, X‐ray diffraction, and scanning electron microscopy coupled with energy dispersive spectroscopy were used to identify the mineralogical and microstructural changes at the interfaces. The microstructural results revealed three microstructural areas: (1) Spinel layer with large numbers of Al alloy channels; (2) interfacial area with mainly alumina, spinel, and BaAl₂Si₂O₈; and (3) interdiffusion zone chemically close to barium hexaaluminate. The principal observations are:

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The effect of foundation flexibility and structural strength on response reduction factor of RC frame structures

Current force‐based design procedure adopted by most seismic design codes allows the seismic design of building structures to be based on static or dynamic analyses of elastic models of the structure using elastic design spectra. The codes anticipate that structures will undergo inelastic deformations under strong seismic events; therefore, such inelastic behaviour is usually incorporated into the design by dividing the elastic spectra by a factor, R, which reduces the spectrum from its original elastic demand level to a design level. The most important factors determining response reduction factors are the structural ductility and overstrength capacity. For a structure supporting on flexible foundation, as Soil Structure Interaction (SSI) extends the elastic period and increases damping of the structure‐foundation elastic system, the structural ductility could also be affected by frequency‐dependent foundation‐soil compliances. For inelastic systems supporting on flexible foundations, the inelastic spectra ordinates are greater than for elastic systems when presented in terms of flexible‐base structure's period. This implies that the reduction factors, which are currently not affected by the SSI effect, could be altered; therefore, the objective of this research is to evaluate the significance of foundation flexibility on force reduction factors of RC frame structures. In this research, by developing some generic RC frame models supporting on flexible foundations, effects of stiffness and strength of the structure on force reduction factors are evaluated for different relative stiffnesses between the structure and the supporting soil. Using a set of artificial earthquake records, repeated linear and nonlinear analyses were performed by gradually increasing the intensity of acceleration time histories to a level, where first yielding of steel in linear analysis and a level in which collapse of the structure in nonlinear analysis are observed. The difference between inelastic and elastic resistance in terms of displacement ductility factors has been quantified. The results indicated that the foundation flexibility could significantly change the response reduction factors of the system and neglecting this phenomenon may lead to erroneous conclusions in the prediction of seismic performance of flexibly supported RC frame structures. Copyright © 2010 John Wiley & Sons, Ltd.     

Regenerated cellulose nanocomposites reinforced with exfoliated graphite nanosheets using BMIMCL ionic liquid

Green nanocomposites of regenerated cellulose/exfoliated graphite nanosheets films with low nanofiller loadings were prepared using environmentally benign 1-butyl-3-methylimidazolium chloride (BMIMCl) ionic liquid. X-ray diffraction revealed well developed intercalated nanocomposites. The tensile strength and Young's modulus of the prepared nanocomposites were increased by 97.5% and 172% respectively when 0.75 wt.% and 1 wt.% exfoliated graphite nanosheets were added. The results were validated using the Halpin–Tsai model. The exfoliated graphite nanosheets were unidirectionally aligned in the regenerated cellulose parallel to the surface of the nanocomposites as revealed by transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM). Also, the TEM and FESEM revealed uniform dispersion of the exfoliated graphite nanosheets and good interaction between the nanofillers and the matrix. The addition of the exfoliated graphite nanosheets enhanced the thermal stability and reduced the water absorption and diffusivity of the nanocomposites.     

THE EFFICIENCY CHALLENGES OF RESOURCE DISCOVERY IN GRID ENVIRONMENTS

Resource discovery is one of the most important services that significantly affects the efficiency of grid computing systems. The inherent dynamic and large-scale characteristics of grid environments make their resource discovery a challenging task. In recent years, different approaches have been proposed for resource discovery, attempting to tackle the challenges of grid environments and improve the efficiency. Being aware of these challenges and approaches is worthwhile in order to choose an appropriate approach according to the application in different organizations. This study reviews the most important factors that should be considered and challenges to be tackled in order to develop an efficient grid resource discovery system.     

Resolution Improvement of Scanning Acoustic Microscopy Using Sparse Signal Representation

Scanning acoustic microscopy is an imaging method in which the focused high frequency ultrasound is used to visualize the micro structures. The morphology and acoustic properties of the biological tissues can be evaluated using scanning acoustic microscope system. To determine thin tissues having micrometer thickness, the high acoustic frequency is required for conventional SAM. In practice the acoustic frequency is restricted by the penetration depth through the material. Characterization of thin sliced tissue is difficult, as the reflected signals from top and bottom are superimposed. In order to improve the axial resolution of conventional SAM, a technique based on sparse signal representation in overcomplete time–frequency dictionaries is investigated and among the great number of algorithms for finding sparse representation, we first apply matching pursuit (MP) and basis pursuit (BP) and then propose the orthogonal matching pursuit (OMP) and stagewise orthogonal matching pursuit (StOMP) algorithms to decompose the A-scan signal to an overcomplete Gabor dictionary. Different criteria are used for measuring the performance of these algorithms in C-scan imaging. The proposed method can separate closely space overlapping echoes beyond the resolution of conventional SAM systems and also the final results show that StOMP performs best overall in extracting the specific echo, since this algorithm is precise and fast.     

Formation mechanism of porous reaction-bonded silicon nitride with interconnected pores in the presence of MgO

In porous reaction bonded silicon nitride, whiskers normally grow in globular clusters as the dominant morphology and deteriorate the pore interconnectivity. However, the ceramic microstructure was significantly transformed with the addition of MgO; specifically, the morphology was modified to a combination of matte and hexagonal grains. Microstructural observation along with thermodynamic studies suggest that MgO interfered with the presence and nitridation of SiO_(g). Consequently, rather than being involved in the whiskers’ formation, surface silica instead reacted with volatile MgO to form intermediate products. Through these reactions, whisker formation was blocked, and a porous interconnected structure formed which was confirmed by 3D tomography. After heat-treatment at 1700 °C, β-Si₃N₄ crystallized in a glassy matrix containing magnesium. Resulting samples had an open-pore structure with porosity of 74–84 vol. %, and density of 0.48-0.75 g.cm^?3. Combination of high porosity and pore size of <40 μm led to compressive strengths of 1.1–1.6 MPa.