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Maimaitiaili Tayier Yunfeng Zhao Dengle Duan Rongge Zou Yunpu Wang Roger Ruan 《木材化学与工艺学杂志》2020,40(3):190-199
AbstractLignin biochar-catalytic depolymerization using biochar Fe-600, Fe-800, Ni-600, Ni-800 catalysts under microwave-heating (180?°C for 30?min) was explored in an ethanol/formic acid (1:1) media. Non-catalyst depolymerization was also studied and compared with the biochar-catalysts results. Characteristics of the bio-char catalysts were analyze by BET, XRD, and FT-IR. GPC, FT-IR, and MALDI-TOF MS spectrometry were also used to characterize the depolymerization products. The experimental results showed that the SBET, Vt, and Vmec and average pore diameter of the biochars are considerably dependent on the preparation temperature and type of cation (Ni2+ or Fe3+). The maximum yield of bio-oil product was obtained as 85?wt% with the addition of biochar Ni-600 and the total amount of oligomers or monomers with a molecular weight of 164 to 446 reaches 80.4%. 相似文献
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This work examines the correlation between the 1H‐NMR T2 relaxation constant and the mechanical properties of aged crosslinked polyolefin cable insulation. T2 experiments on unswollen samples could not differentiate between unaged and highly aged materials; all exhibited 1H T2 constants of approximately 0.5 ms. To accentuate the effects of aging, samples were swollen in various solvents. Unaged samples had T2 values of approximately 15 ms in good solvents. With thermal aging, T2 values decreased as the ultimate tensile elongation decreased. However, the correlation between T2 and elongation differed for samples irradiated with high‐energy radiation and for materials aged above versus below the crystalline melting temperature. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2578–2582, 2003 相似文献
5.
Marginal costs of electricity vary by time and location. In the past, researchers attributed the variations to factors related to electricity generation and transmission. These authors, however, have not analyzed possible variations in marginal distribution capacity costs (MDCC). The objectives of this paper are:
- 1. (i) to show that large MDCC variations are due to the dispersion in distribution capital expenditures by time and space,
- 2. (ii) to propose a method for quantifying the area- and time-specific MDCC in the presence of lumpy investments, and
- 3. (iii) to compare our MDCC estimates to those commonly used in the electric utility industry.
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Petr A. Nikrityuk Kerstin Eckert Roger Grundmann 《Metallurgical and Materials Transactions B》2006,37(3):349-359
This paper presents a numerical study of the Lorentz force and fluid flow induced by a rotating magnetic field in a medium
with a nonhomogeneous electric conductivity placed in a cylindrical vessel with insulated walls. The nonhomogeneity is modeled
by the presence of a solid and a liquid phase of different electrical conductivity. The solid phase is located orthogonally
to the axis of rotation, which corresponds to the case of unidirectional solidification. The simulations were performed for
different locations of the solid front and different ratios of the electrical conductivity, σ
s
/σ
l
=0.2... 10. Here σ
s
and σ
l
are the electric conductivity of the solid and liquid phases, respectively. The results showed that the difference between
electrical conductivity of solid and liquid phases has a noticeable effect on the mean-time Lorentz force and the velocity:
namely, the presence of the solid phase (σ
s
>σ
l
) leads to an increase of the Lorentz force and fluid flow in the cylinder. 相似文献