Evolution of Local Structural Ordering and Chemical Distribution upon Delithiation of a Rock Salt–Structured Li1.3Ta0.3Mn0.4O2 Cathode

Lithium‐rich disordered rock‐salt oxides have attracted great interest owing to their promising performance as Li‐ion battery cathodes. While experimental and theoretical efforts are critical in advancing this class of materials, a fundamental understanding of key property changes upon Li extraction is largely missing. In the present study, single‐crystal synthesis of a new disordered rock‐salt cathode material, Li_1.3Ta_0.3Mn_0.4O₂ (LTMO), and its use as a model compound to investigate Li concentration–driven evolution of local cationic ordering, charge compensation, and chemical distribution are reported. Through the combined use of 2D and 3D X‐ray nanotomography, it is shown that Li removal accompanied by oxygen oxidation is correlated with the development of morphological defects such as particle cracking. Chemical heterogeneity, quantified by subparticle level distribution of Mn valence state, is minimal during Mn redox, which drastically increases upon the formation of cracks during oxygen redox. Density functional theory and bond valence sum mismatch calculations reveal the presence of local short‐range ordering in the pristine oxide, which gradually disappears along with the extraction of Li. The study suggests that with cycling the transformation into true cation–disordered state can be expected, which likely impacts the voltage profile and obtainable energy density of the oxide cathodes.     

Capture of Organic Vapors Using Adsorption and Electrothermal Regeneration

Activated-carbon-fiber cloth (ACFC) is an alternative adsorbent to granular activated carbon (GAC) for removing and recovering organic vapors from gas streams. Electrothermal desorption (ED) of ACFC provides rapid regeneration while requiring less energy compared to traditional regeneration techniques used with GAC. This paper provides proof-of-concept results from a bench-scale ACFC adsorption system. The automated system captured 1,000 ppmv of hazardous air pollutants/volatile organic compounds (HAPs/VOCs) from air streams and demonstrated the use of ED, using ac voltage, to recover the HAP/VOC as a pure liquid. The desorbed HAP/VOC condensed onto the inner walls of the adsorber and was collected at the bottom of the vessel, without the use of ancillary cooling. Seventy percent of the HAP/VOC was collected per cycle as condensate, with the balance being retained in the regenerated adsorber or recycled to the second adsorber. ED with in-vessel condensation results in minimal N2 consumption and short regeneration cycle times allowing the process to be cost competitive with conventional GAC-based adsorption processes. This technology extends the application of carbon adsorption systems to situations that were previously economically and physically impractical.     

Subreflector shaping to improve multiple-beam performance of a Cassegrain antenna

A method of designing multiple-beam antennas based on shaping the subreflector of an offset Cassegrain antenna is described. It is applied to a compact system having a diameter of 300? that is required to produce beams up to 4-6°either side of boresight. The performance is shown to be only slightly less than that obtainable by also shaping the main reflector, indicating that efficient multiple-satellite-access antennas can be designed without specially shaped main reflectors.     

Methodologies for the optimal design of parallel manipulators

In this paper the problem of determining a manipulator design so that its workspace corresponds to a prescribed workspace is considered. Two different strategies, resulting in two different types of optimization problem are considered. The first strategy attempts to obtain a good overall approximation to the prescribed workspace and results in an unconstrained optimization problem. The second strategy entails designing a manipulator so that its workspace fully encloses the prescribed workspace and results in a constrained optimization problem. Two specific formulations of the constrained problem are proposed. The first constrained problem simply aims to fit the manipulator workspace as exactly as possible to the prescribed workspace, while still ensuring that the prescribed workspace is fully enclosed. The second constrained optimization formulation is used to design a manipulator, the workspace of which fully encloses the prescribed workspace, but which is also well‐conditioned throughout the workspace with respect to some performance measure. The particular manipulator used to illustrate and evaluate these formulations is a simple 2‐dof planar parallel manipulator, and the final formulation is also applied to a 3‐dof planar parallel manipulator. Although the manipulators studied here are simple, the objective of this study is to obtain a robust numerical methodology which can be extended to more practical and complex manipulators. Copyright © 2003 John Wiley & Sons, Ltd.     

Evaluating the solar resource: a review of problems resulting from temporal, spatial and angular variations

Accurate assessment of the availability of solar energy at the Earth's surface is hampered by difficulties associated with the variability of solar radiation in space and time and with the angular position in the sky hemisphere. This paper assesses each of these problem areas by highlighting the difficulties and the attempts to offset them. Major emphasis is placed on extrapolation and interpolation procedures, the sensitivity of inclined surfaces to variations in the solar input, numerical models for calculating the irradiance of inclined surfaces and the time scales for which these computations are valid.Finally, the reader is urged to consider the significance of these difficulties in light of both radiation measurement errors and the sensitivity of the application to imprecise determinations of the radiation environment.     

A recent assessment of cocoa and pesticides in Brazil: an unhealthy blend for plantation workers

Cocoa is the major source of income for the Brazilian state of Bahia and some 2.3 million people rely on the crop for their livelihood. Most cocoa is grown on large plantations where working conditions are often extremely poor. Few workers using pesticides on plantations, or on small-holdings, have had instruction about safe working practices. Protective clothing is rarely available. The result is frequent complaints about health. None of this likely to improve in the short term given Brazil's perilous economic situation.     

Enthalpic relaxation in semi-crystalline PEEK

The effect of crystallisation on the glass transition temperature and enthalpic relaxation in poly(ether ether ketone) (PEEK) has been investigated. The increase in glass transition temperature and the activation enthalpy of ageing is explained in terms of the amorphous phase being constrained by the crystallites. The extent of enthalpic relaxation with time has been analysed in terms of the Cowie-Ferguson model and the β value was found to be dependent on both temperature and the crystalline morphology, changes in the co-operativity of the relaxations are used to explain this observation.     

The effect of alumina particulate morphology on the properties of reinforced poly(propylene) and poly(ethylene-co-vinyl acetate) composites

The effect of alumina particulates on a thermoplastic matrix is investigated, in particular the effect altering the alumina particle size and morphology has on the mechanical properties. Different grades of alumina are used and two thermoplastic matrices; namely poly(propylene) and poly(ethylene-co-vinyl acetate). Investigations showed that optimum properties were achieved with the alumina of smallest particle size and lowest aspect ratio. Preliminary work has also been performed on the use of silane coupling agents and they have proved effective in increasing the tensile properties of the composites.     

Quantitative studies on the movement of fluid and lymphocytes through periodontal tissue and into the draining lymph.

Chronic lymph drainage techniques in sheep have been used to map the pathways and to quantify the fluid and cell traffic through periodontal tissues. The continuous collection of cervical and prescapular lymph has demonstrated that 65% of labelled protein tracer injected into the periodontal tissues could be found in lymph over a period of 7.5 hours. Nearly 90% of the total radioactivity could be accounted for between the lymph and the tissue site. When silk was impregnated with radiolabelled albumin and a tooth ligated, the kinetics of the subsequent appearance of the tracer in lymph emphasized the ease with which macromolecules surrounding the teeth gain access to the lymphatics, regional lymph nodes, and immune apparatus. Animals were primed with BCG and then tuberculin (delayed hypersensitivity) lesions were simultaneously induced in the skin, bowel, and periodontium. When T cells were labelled with radioisotopes and their migration from blood to lymph measured, the periodontal tissue traffic pattern was distinct from the traffic pattern through DTH in the skin and also distinct from the pattern through the small intestine. This indicates that the lymphocyte traffic through the inflamed periodontium has unique features. This tissue specificity was not apparent when lesions were induced with TNFalpha. The static assessment of lymphocyte subsets within the tissues was also assessed with immunohistochemistry.