A single phase photovoltaic inverter control for grid connected system

This paper presents a control scheme for single phase grid connected photovoltaic (PV) system operating under both grid connected and isolated grid mode. The control techniques include voltage and current control of grid-tie PV inverter. During grid connected mode, grid controls the amplitude and frequency of the PV inverter output voltage, and the inverter operates in a current controlled mode. The current controller for grid connected mode fulfills two requirements – namely, (i) during light load condition the excess energy generated from the PV inverter is fed to the grid and (ii) during an overload condition or in case of unfavorable atmospheric conditions the load demand is met by both PV inverter and the grid. In order to synchronize the PV inverter with the grid a dual transport delay based phase locked loop (PLL) is used. On the other hand, during isolated grid operation the PV inverter operates in voltage-controlled mode to maintain a constant amplitude and frequency of the voltage across the load. For the optimum use of the PV module, a modified P&O based maximum power point tracking (MPPT) controller is used which enables the maximum power extraction under varying irradiation and temperature conditions. The validity of the proposed system is verified through simulation as well as hardware implementation.     

Extraction of aluminium as aluminium sulphate from thermal power plant fly ashes

Valuable metal extraction technology from thermal power plant fly ash is limited. In the present study, aluminium is extracted from fly ash as highly pure aluminium sulphate (>99.0%) by leaching with sulphuric acid, followed by pre-concentration and successive crystallization. Two types of fly ashes from different sources, i.e., Talcher Thermal Power Station (TTPS) and Vedanta Aluminium Company Limited (VAL) were chosen for comparative study on the extraction of aluminium as aluminium sulphate. The product is characterized by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). Purity of aluminium sulphate was also investigated by inductively coupled plasma–optical emission spectrometry (ICP–OES). The extraction efficiency of aluminium depends on the varied solid-to-liquid ratio (fly ash : 18 mol/L H₂SO₄, g/mL) and particle size of fly ashes. Physico-chemical analysis indicates that the obtained product is Al₂(SO₄)₃·18H₂O, having low iron content (0.08%).     

Variability of waste copper slag concrete and its effect on the seismic safety of reinforced concrete building: A case study

Proven research output on the behavior of structures made of waste copper slag concrete can improve its utilization in the construction industry and thereby help to develop a sustainable built environment. Although numerous studies on waste copper slag concrete can be found in the published literature, no research has focused on the structural application of this type of concrete. In particular, the variability in the strength properties of waste copper slag concrete, which is required for various structural applications, such as limit state design formulation, reliability-based structural analysis, etc., has so far not attracted the attention of researchers. This paper quantifies the uncertainty associated with the compressive-, flexural- and split tensile strength of hardened concrete with different dosages of waste copper slag as fine aggregate. Best-fit probability distribution models are proposed based on statistical analyses of strength data generated from laboratory experiments. In addition, the paper presents a reliability-based seismic risk assessment of a typical waste copper slag incorporated reinforced concrete framed building, considering the proposed distribution model. The results show that waste copper slag can be safely used for seismic resistant structures as it results in an identical probability of failure and dispersion in the drift demand when compared with a conventional concrete building made of natural sand.     

LACTIC ACID FERMENTATION OF SWEET POTATO (IPOMOEA BATATAS L.) INTO PICKLES

Lactic acid (LA) fermentation has many benefits. It is feasible in small scale, inexpensive, and does not require additives and confers organoleptic characteristics to the foodstuff according to the habits and requirement of the consumers. Sweet potato roots were pickled by lactic fermentation by brining the cut and blanched roots in common salt (NaCl, 2–10%) solution and subsequently inoculated with a strain of Lactobacillus plantarum (MTCC 1407) for 28 days. The treatment with 8–10% brine solution was found to be the most acceptable organoleptically. The final product with 8 and 10% brine solutions had a pH of 2.9–3.0, titratable acidity of 2.9–3.7 g/kg, LA of 2.6–3.2 g/kg and starch of 58–68 g/kg on fresh weight basis. Sensory evaluation rated the sweet potato lacto‐pickle acceptable based on texture, taste, aroma, flavor and aftertaste. Principal component analyses reduced the six original analytical variables to two independent components (factors), which accounted for 92% of the total variations.     

Kinetics of Precipitation of α-Al2O3 in Polycrystalline Supersaturated MgO - 2Al2O3 Spinel Solid Solution

Supersaturated polycrystals of solid-solution spinel were heat-treated below the solvus temperature. Precipitation of α-alumina was examined by X-ray diffraction, microprobe, and scanning transmission electron microscopy. Precipitation kinetics followed classical time-temperature-transformation behavior: the precipitation rate was growth controlled at large undercoolings and nucleation controlled at low undercoolings. Scanning transmission electron microscopy and microprobe analysis revealed that the growth of precipitates was limited by interface reaction. Nucleation occurred throughout the polycrystal and was probably promoted by the grain boundaries. Precipitation was accompanied by the growth of pores at interfaces, presumably to accommodate the change in volume required by the phase transformation. Our observations in polycrystals contrast sharply with single-crystal work, where it has been reported that nucleation occurs at the free surface and that the formation of α-alumina is preceded by metastable phases.     

Influence of vitamin E supplementation on spontaneous oxidized flavour of milk in dairy buffaloes

Twenty-four Murrah buffaloes (60 days pre-partum) were divided into four equal groups (T ₁ , T ₂ , T ₃ and T ₄ ) and were supplemented with 0, 1000, 1500 and 2000 IU α-tocopheryl acetate per day up to 30 days of lactation, and half of these doses from 30 to 60 days of lactation. Milk samples collected fortnightly were analysed for vitamin E, fat, and development of oxidized flavour, with and without copper addition by a panel of judges, and chemically by the thiobarbituric acid test. Scores for oxidized flavour ranged from 0 to 10 with 0–4 as definite, 5–7 as light and 8–10 having no defect. The α-tocopherol content in milk fat (µg/g) averaged 20.55, 25.56, 29.98 and 31.38 in T ₁ , T ₂ , T ₃ and T ₄ groups, respectively. The addition of Cu in the milk significantly increased milk fat oxidation. Better stability of milk in T ₃ and T ₄ groups was observed, which might be due to a higher level of milk α-tocopherol. Addition of 1500 IU α-tocopheryl acetate in the diet of buffaloes helped in improving the oxidative stability of milk.     

Mechanical and morphological investigation of virgin polyethylene and silver nanoparticle-loaded nanocomposites film: comprehensive analysis of kinetic models for non-isothermal crystallization

This research was accomplished to examine the mechanical, morphological and crystallization kinetics study of polyethylene/silver nanoparticles (Ag-NPs) nanocomposite films. In this research, low-density polyethylene (LDPE) nanocomposite films were prepared containing Ag-NPs using maleic-anhydride-grafted low-density polyethylene (LDPE-g-MAH) as a compatibilizer by the melt mixing process. From mechanical property evaluation, it is revealed that the LDPE/LDPE-g-MAH/Ag-NPs nanocomposite films showed decreased tensile strength as compared with virgin LDPE matrix. Thermal characteristics of the prepared virgin LDPE and its nanocomposite films were studied by differential scanning calorimetry (DSC). Comprehensive analysis of different kinetic models such as the Avrami and Mo model on non-isothermal crystallization kinetics was performed in order to correlate the rate of crystallization and its various kinetic parameters. Further, the macrokinetic equation as proposed by Malkin has been applied to describe the kinetics of crystallization in the light of the Avrami equation. Concerning virgin LDPE and Ag-NP-reinforced LDPE, the former shows primary crystallization, whereas the later exhibits both primary and secondary crystallization with varying Avrami exponents. Kinetic parameters are recognized, and confirm the influence of Ag-NPs on crystallization kinetics. X-ray diffraction spectroscopy and transmission electron microscopic analysis of the nanocomposite films were conducted to verify the dispersion of inorganic filler particles in the resulting hybrids.