Hydrogel photocatalysts for efficient energy conversion and environmental treatment

Photocatalysts have attracted great research interest owing to their excellent properties and potential for simultaneously addressing challenges related to energy needs and environmental pollution. Photocatalytic particles need to be in contact with their respective media to exhibit efficient photocatalytic performances. However, it is difficult to separate nanometer-sized photocatalytic materials from reaction media later, which may lead to secondary pollution and a poor recycling performance. Hydrogel photocatalysts with a three-dimensional (3D) network structures are promising support materials for photocatalysts based on features such as high specific surface areas and adsorption capacities and good environmental compatibility. In this review, hydrogel photocatalysts are classified into two different categories depending on their elemental composition and recent progresses in the methods for preparing hydrogel photocatalysts are summarized. Moreover, current applications of hydrogel photocatalysts in energy conversion and environmental remediation are reviewed. Furthermore, a comprehensive outlook and highlight future challenges in the development of hydrogel photocatalysts are presented.     

Design for Consecutive Testability of System-on-a-Chip with Built-In Self Testable Cores

This paper introduces a new concept of testability called consecutive testability and proposes a design-for-testability method for making a given SoC consecutively testable based on integer linear programming problem. For a consecutively testable SoC, testing can be performed as follows. Test patterns of a core are propagated to the core inputs from test pattern sources (implemented either off-chip or on-chip) consecutively at the speed of system clock. Similarly the test responses are propagated to test response sinks (implemented either off-chip or on-chip) from the core outputs consecutively at the speed of system clock. The propagation of test patterns and responses is achieved by using interconnects and consecutive transparency properties of surrounding cores. All interconnects can be tested in a similar fashion. Therefore, it is possible to test not only logic faults but also timing faults that require consecutive application of test patterns at the speed of system clock since the consecutively testable SoC can achieve consecutive application of any test sequence at the speed of system clock.     

Effects of Oxygen Absorber and Temperature on ω3 Polyunsaturated Fatty Acids of Sardine Oil during Storage

To prevent loss of w3 polyunsaturated fatty acids over long-term preservation, the effects of temperature and oxygen absorber on the fatty acids of sardine oil stored in air-tight film were studied. The fatty acids of sardine oil and lipids in the diet of experimental animals rapidly decreased over 1 month at 22°C. The amounts in the diet decreased slowly at 2°C; however, no alterations in the oil samples were observed for 6 months. Also, the amounts did not change at -30°C. Significant changes in samples treated with oxygen absorber were not observed under all temperatures during 6 months storage (P > 0.05). These results indicate that treatment with an oxygen absorber and/or freezing can prevent ω3 polyunsaturated fatty acids of fish oil from decreasing during storage.     

氧浓度对近临界水中纤维素分解的影响

研究了不同初始氧浓度对纤维素在近临界水中分解的影响，实验结果表明，氧浓度显著地影响产物总碳收支平衡，液相不同组分的收率、气体的产量以及气相产物的组成，微量氧对产物总碳收支平衡影响不大，而对液相不同组分的收率有一定的影响。从实验结果可以看出，离子型反应机理在纤维素水解的第一步中起主导作用。而单糖的进一步分解是一个以自由基反应机理为主的过程。     

Synthesis of poly(α-thiophenediyl)benzylidene with high molecular weight and its thermal stability

Summary The synthesis of poly(-thiophenediyl)benzylidene (PTB) with high molecular weight is described. Number-average degrees of polymerization reached about 74. The characterizations of the polymer was investigated by ¹H-NMR, ¹³C-NMR, IR, and UV-VIS spectra. The polymer with well-defined structure and high molecular weight was obtained by polymerization at low temperature and in polar solvent. This polymer was thermally stable and a thermal decomposition took place at 391°C under nitrogen and at 370°C under air. The glass transformation temperature was 117°C and this PTB was nonfusible.     

脉冲放电高能转化制备纳米粉体

综合介绍了脉冲电流通过细金属丝放电(pulsed wire discharge,PWD)制备纳米粉体的方法.讨论了影响纳米粉体,特别是晶粒尺寸的因素,以防止形成亚微米颗粒.因为达到电压峰值的丝的沉积能相当于丝的汽化能,因此,能夠计算出沉积能.随着所施加的能量增加,气体压力降低,介质气体的热扩散率增大,晶粒尺寸变小.在惰性气氛中,采用PWD工艺,由金属蒸气急冷可制备金属粉体.如果介质气体变为氧气或者氨气,就能制备氧化物、氮化物纳米粒子.要制备双金属合金、双氧化物或氮化物纳米粒子就必需采用双金属丝和不同的介质气体.采用PWD工艺,在有机气体或烟气中,能制备电磁屏蔽和导电浆料和其它用途的钝化纳米粒子.采用丝输送器而实现大量生产纳米粉体的PWD工艺一个实例证明了PWD工艺生产纳米粉体的可行性.     

MHz-driven snubberless zero-current soft-switching high step-up DC-DC converter with a multi-resonant tank

A novel high step-up DC-DC converter suitable for the power interface of fuel cells (FC) is presented in this paper. The proposed converter features a multi-resonant tank for achieving high-step up ratio under zero current soft switching (ZCS) without any snubber circuits. The simple and minimized-component topology is beneficial for megahertz driving of gallium nitride (GaN) power transistors with effective reductions of switching loss, electromagnetic emission interference (EMI) noise, and ripple-free DC input current. Mode-transitional power stages are described in detail, following that the high step-up principle is revealed by means of frequency-domain analysis. The essential performances of the proposed circuit topology are demonstrated by simulation and experiment of 1.8 MHz-120W prototype whereby effectiveness of the snubberless and multi-resonant topology are verified from the practical point of view.     

A Hilbert warping method for handwriting gesture recognition

We propose a novel sequence alignment algorithm for recognizing handwriting gestures by a camera. In the proposed method, an input image sequence is aligned to the reference sequences by phase-synchronization of analytic signals which are transformed from original feature values. A cumulative distance is calculated simultaneously with the alignment process, and then used for the classification. A major benefit of this method is that over-fitting to sequences of incorrect categories is restricted. The proposed method exhibited higher recognition accuracy in handwriting gesture recognition, compared with the conventional dynamic time warping method which explores optimal alignment results for all categories.     

Time‐averaged spatial profile of Xe excitation efficiency in PDPs

Abstract— The Xe excitation efficiency for various Xe content was analyzed by monitoring the panel luminance and IR emission intensity. It was found that dependences of the Xe excitation efficiency and luminous efficacy on the sustain voltage show almost the same tendency. A decrease for increasing sustaining voltage was found in a low‐Xe‐content panel and an increase was found in a high‐Xe‐content panel. A reduction in the effective electron temperature and a reduction in plasma saturation contribute to the efficacy improvement. The time‐averaged spatial profile of the Xe excitation efficiency in PDPs was investigated by measuring the distribution of IR and blue‐phosphor emissions. The results show that the Xe excitation efficiency is similar in the cathode and anode regions even though the spatial and time development of the discharge in these regions is very different. An extended theory that takes into account not only the radiative transition process but also the collisional de‐excitation process from Xe** to Xe* is proposed for investigating the pressure dependence of the Xe excitation efficiency. By using the proposed theory, it was found that Xe excitation efficiency increases, attains a maximum value at 30% Xe, then decreases as the Xe content is increased, when the rate coefficient of the collisional de‐excitation process is less than 1.0 × 10^?10 cm³/sec.     

Power savings and enhancement of gray‐scale capability of LCD TVs with an adaptive dimming technique

Abstract— The luminance of a backlight unit for an LCD TV is adaptively and locally dimmed along with the input video signal in order to reduce the power consumption and also to improve the picture quality. By adopting the zero‐dimensional (0D), 1D, and 2D adaptive dimming techniques, a sample movie having 8.0% post‐gamma average picture levels (APL) could be displayed using 83%, 71%, and 50% of the original backlight power, respectively. For an adoption of the 2D dimming, an LED backlight is preferable. The adaptive‐dimming technique also allows the differential aging characteristics between the LED components and temperature dependence of color and luminance to be overcome. From simulations of a reduction in power consumption, it was found that 40 × 40 pixels is a unit of the local dimming, 30 frames for the sampling period, 24 dimming steps, and an equal‐signal‐step method for determining the dimming factor have been found to be appropriate. The gray‐scale capability of low‐luminance images can also be improved by dimming the backlight luminance and expanding the input signal. By using an LCD TV having an 8‐bit capability, an 11‐bit‐equivalent gray‐scale expression was experimentally proven.