The oxidation properties of fourth generation single-crystal nickel-based superalloys

The fourth-generation nickel-based single-crystal superalloys, which contain large amounts of refractory metals for strengthening and platinum group metals for topologically close-packed phase prevention, show excellent high-temperature strength. However, these alloying elements seem to decrease high-temperature oxidation resistance. In this study, nickel-based superalloys with various amounts of tantalum, rhenium, and ruthenium were examined in isothermal and cyclic exposures at 1,100°C to investigate the effect on the oxide growth rate and resistance to scale spallation. Ruthenium and rhenium were found to degrade the oxidation resistance by the vaporization of their oxide. Tantalum-rich oxide in the spinel layer acts to stabilize ruthenium and rhenium oxide in the scale. The addition of hafnium and yttrium is effective in improving the oxidation resistance of ruthenium-containing nickel-based superalloys.     

Ergonomics solution for crossing collisions based on field assessment of visual environment at urban intersections in Japan

This paper aims to assess quantitatively the actual visual environment of uncontrolled urban downtown intersections in Japan in relation to frequently occurring crossing collisions and to discuss the safety countermeasures for them. In Field Study 1 dealing with direct visibility, our ultra-wide-angle photograph analysis revealed that most of the right/left-ward visible range at 11 intersections were insufficient to check safety, and the quality of direct visibility was closely associated with causing crossing collisions. The countermeasures to reduce a blind area were determined to be a top priority. In Field Study 2 dealing with indirect visibility, more than half of the 25 traffic convex mirrors had marked shortcomings for preventive safety, and ergonomics guidelines ensuring indirect visibility were proposed for installing traffic convex mirrors. Low-cost/low-technology-oriented countermeasures are highly recommended to obtain clear/sufficient images of crucial information satisfying drivers' requirements on traffic convex mirrors in accordance with those ergonomics guidelines was highly recommended. Crossing collisions could be prevented by improvement of poor direct and indirect visibility.     

Analysis and discussion on conduction current based on simultaneousmeasurement of TSC and space charge distribution

A new analysis of conduction current distributed in dielectrics based on simultaneous measurements of thermally stimulated current (TSC) and time dependent space charge distribution is proposed. A new system pulsed electro-acoustic (PEA) method has been developed to enable simultaneous measurement of the TSC and the dynamic space charge and electric field distributions as a function of temperature within insulators. With the new system, the relationship between the TSC and the time dependent electric field distribution in electron beam (e-beam) irradiated PMMA has been investigated. From the time dependent electric field, the displacement current in dielectrics is obtained. The TSC is a typical external current which is represented as an addition of the displacement current and a conduction current in dielectrics. This paper makes it clear that the conduction current as a function of position is determined by the simultaneous measurement of the external current and the dynamic space charge distribution     

Evaluation of absorption of micro-droplets on paper for creation of paper-based microstructures

This study clarifies the absorption behavior of micro-droplets of water on treated paper to support the design of functional microstructures, such as electronics and micro-fluid channels, on paper. The period of time between when a micro-droplet of water ejected from an ink-jet head lands on the paper’s surface and its complete disappearance by absorption was defined as the micro-sizing degree (MSD), and an MSD measurement method was established. The MSD was evaluated using microscopic high-speed video images of the side view recorded every millisecond. Several grades of commercially available ink-jet paper media and laboratory sheets having different levels of water repellency prepared from a pulp and a sizing agent were examined. The MSD of commercial ink-jet papers, which are known to absorb water very quickly, was 3–6 ms. Weakly sized laboratory sheets exhibited a lower MSD of 2–3 ms. The absorption behavior was analyzed in terms of the capillary pressure with and without the Laplace pressure; the theoretical and experimental results agreed moderately well. The results indicated that the Laplace pressure cannot be neglected in the analysis. The MSD of a wet surface where a preceding micro-droplet had already landed was higher than that on a dry or partially wet surface, presumably because water remains inside pores for an unexpectedly long time.     

Research and Development of the Coprecipitation Process for Lanthanum Germanate Oxyapatite

Although lanthanum germanate oxyapatite (La–Ge–O) has shown good potential for use as a solid electrolyte in energy storage applications, its synthesis has been challenging by either solid‐ or solution‐state methods. In this study, a new synthesis of La–Ge–O was developed through a coprecipitation technique, in which a highly concentrated homogeneous aqueous solution of La and Ge was prepared from aqueous ammonium germanate and lanthanum nitrate solutions with the addition of dilute nitric acid. Several precipitates were formed by pH manipulation, including an amorphous material obtained at pH > 3. Compared to the individual precipitation behaviors of the parent compounds, the amorphous precipitate was formed only from the aqueous two‐component mixture, and appeared to contain both metals. This material was transformed into crystalline mixtures upon heating at 1273 K. The crystalline phases were La₂Ge₃O₉ and hexagonal‐type GeO₂ when the precipitate was formed below pH 8, and the La–Ge–O and La₂Ge₂O₇ phases when the precipitate was formed around pH 8. Product formation from the coprecipitate was discussed based on X‐ray diffraction and thermal analyses. The improved availability of La–Ge–O will allow more extensive investigations of its useful properties.     

Solubility of NiO in Al2O3

Solubility of NiO in Al₂O₃ was determined by electron probe microanalysisy A diffusion couple method was used by coupling an NiO-doped Al₂O₃ polycrystal to a pure single crystal of Al₂O₃. The solubility of NiO in Al₂O₃ in air was 230 wt ppm (157 at. ppm of cations) and 170 wt ppm (116 at. ppm) at 2073 and 1973 K, respectively. The solubility of NiO in Al₂O₃ obtained in this work was compared with our previous work of the solubility of MgO in Al₂o₃.     

Neuromelanin in Parkinson’s Disease: Tyrosine Hydroxylase and Tyrosinase

Parkinson’s disease (PD) is an aging-related disease and the second most common neurodegenerative disease after Alzheimer’s disease. The main symptoms of PD are movement disorders accompanied with deficiency of neurotransmitter dopamine (DA) in the striatum due to cell death of the nigrostriatal DA neurons. Two main histopathological hallmarks exist in PD: cytosolic inclusion bodies termed Lewy bodies that mainly consist of α-synuclein protein, the oligomers of which produced by misfolding are regarded to be neurotoxic, causing DA cell death; and black pigments termed neuromelanin (NM) that are contained in DA neurons and markedly decrease in PD. The synthesis of human NM is regarded to be similar to that of melanin in melanocytes; melanin synthesis in skin is via DOPAquinone (DQ) by tyrosinase, whereas NM synthesis in DA neurons is via DAquinone (DAQ) by tyrosine hydroxylase (TH) and aromatic L-amino acid decarboxylase (AADC). DA in cytoplasm is highly reactive and is assumed to be oxidized spontaneously or by an unidentified tyrosinase to DAQ and then, synthesized to NM. Intracellular NM accumulation above a specific threshold has been reported to be associated with DA neuron death and PD phenotypes. This review reports recent progress in the biosynthesis and pathophysiology of NM in PD.     

Protective layer for high‐efficiency PDPs driven at low voltage

Abstract— The sustain pulse voltage of a panel for 66‐kPa Ne + Xe (5–30%) with an (SrCa)O protective layer is 20–40% lower than that with an MgO protective layer. The luminous efficiency of the panel with a Ne + Xe (30%) (SrCa)O protective layer is 1.5 times that of the conventional panel with a Ne + Xe (10%) MgO protective layer; the sustain pulse voltages of these panels are almost the same. The power loss caused by panel capacitance is proportional to the second power of the sustain pulse voltage. Using the (SrCa)O protective layer for Xe (5–30%), the power loss is reduced by 35–60% compared with the MgO protective layer. It follows that, using the (SrCa)O protective layer, we can increase the Xe content with little power loss and thus achieve high‐efficiency PDPs. As for MgO and CaO with Xe ions, electrons are probably ejected from only the defect states. On the other hand, as for the SrO with Xe ions, it is likely that electrons can be ejected from not only defect states but also the valance band. This seems to be the reason why the driving voltage is lower with the (SrCa)O protective layer than with the MgO protective layer.     

Loss factors of mirrors for a gravitational wave antenna

Low-loss mirrors fabricated by ion-beam-sputtering machines for possible application in an interferometric gravitational wave antenna were evaluated by use of Nd:YAG laser light (lambda = 1064 nm) with two distinct measurements: a tabletop experiment that used a short cavity with a small beam with a beam waist of approximately 2w(0) = 0.82 mm, and an optical test that used a 20-m prototypical gravitational-wave detector with a large beam with a beam waist of approximately 2w(0) = 4.4 mm. A multilayer coating comprised 29 layers of SiO(2)/Ta(2)O(5) and one protective coating of SiO(2). The best values obtained as a result of these measurements were 16 ppm (parts in 10(6)) and 30 ppm in total loss, respectively. Also, a two-dimensional loss map generated by use of a small beam successfully revealed the existence of a loss structure within the coating surface. These results imply that a high-reflectance multilayer coating has some inhomogeneities and a loss distribution with a typical scale of a few millimeters and that the total measured losses depend on the beam spot size.