The peak shear strength of discontinuities between two different rock types is essential to evaluate the stability of a rock slope with interlayered rocks. However, current research has paid little attention to shear strength parameters of discontinuities with different joint wall compressive strength (DDJCS). In this paper, a neural network methodology was used to predict the peak shear strength of DDJCS considering the effect of joint wall strength combination, normal stress and joint roughness. The database was developed by laboratory direct shear tests on artificial joint specimens with seven different joint wall strength combinations, four designed joint surface topographies and six types of normal stresses. A part of the experimental data was used to train a back-propagation neural network model with a single-hidden layer. The remaining experimental data was used to validate the trained neural network model. The best geometry of the neural network model was determined by the trial-and-error method. For the same data, multivariate regression analysis was also conducted to predict the peak shear strength of DDJCS. Prediction precision of the neural network model and multivariate regression model was evaluated by comparing the predicted peak shear strength of DDJCS with experimental data. The results showed that the capability of the developed neural network model was strong and better than the multivariate regression model. Finally, the established neural network model was applied in the stability evaluation of a typical rock slope with DDJCS as the critical surface in the Badong formation of China.
Reaction of a rigid conjugated clamp-like ligand N,N′-bis(pyridin-3-yl)-2,6-pyridinedicarboxamide (bppdca) with ZnSO4·7H2O or CoSO4·7H2O resulted in the formation of two new polymers, namely, {[Zn2(bppdca)(SO4)2(DMF)2]·(DMF)}n (1) and {[Co(bppdca)(SO4)(CH3OH)(DMF)]·H2O}n (2). Both 1 and 2 feature one-dimensional double-chain structures with macrocyclic subunits, and the chains further self-assemble into a higher-dimensional framework via the hydrogen-bonding and π–π stacking interactions. Fluorescence studies show that the free ligand displays a strong fluorescence emission in solid state at room temperature, but in 1 and 2, the complexation of the ligand with metal ions and weak intermolecular interactions make the fluorescence emission partial quenching. 相似文献