连续鼓气对舰船冷却海水真空膜蒸馏强化效果的研究

通过连续运行试验考察舰船冷却海水膜蒸馏系统不鼓气时膜通量变化及膜污染情况,应用气液两相流试验考察连续鼓气流量与膜通量之间的关系,探讨不同温度下连续鼓气的强化效果.结果 表明,舰船冷却海水真空膜蒸馏系统不鼓气时,海水温度升高膜通量衰减加快,会在膜面形成碳酸钙等盐类结晶;0～30 L/min连续鼓气时膜通量随鼓气流量上升而增加,30～40 L/min连续鼓气时膜通量随鼓气流量上升而减小;连续鼓气能提高真空膜蒸馏通量,鼓气流量宜控制在30 L/min.     

浅谈几种钢丝编织机的结构原理及性能特点

介绍了国产GBG，美国RB-2、TMW225-11，德国MR-11，意大利DAK，韩国BW等型号的钢丝编织机的编织机构的结构特点，分析了各种编织机梭子的传递过程。随后总结了各种编织机的性能特点并进行了分析讨论，认为至今没有先进的国产编织机研发成功的主要原因在于成本价格过高及制造技术水平达不到。     

Preparation of superparamagnetic immunomicrospheres and application for antibody purification

A novel and effective protocol for the preparation of superparamagnetic immunomicrospheres has been developed. First, micro‐size magnetic poly (methacrylate‐divinylbenzene) (PMA‐DVB) spheres were prepared by a modified suspension polymerization method. The oleic acid coated magnetite (Fe₃O₄) nanoparticles made by coprecipitation were mixed with monomers of MA, DVB, and initiator benzoyl peroxide (BPO) to form oil in water emulsion droplets with the presence of poly (vinyl alcohol) (PVA‐1788) as a stabilizer. The polymerization reaction was carried out in a 2‐L beaker equipped with four vertical stainless steel baffleplates by increasing the temperature of the mixture at a controlled rate. The resulting magnetic microspheres are micro‐sized (less than 8μm in diameter) and 80 percent of them are in the size ranging from 1 to 5 μm. Then, they were highly functionalized via ammonolysis reaction with ethylenediamine, and the surface amino‐modified magnetic microspheres were obtained. The morphology and properties of these magnetic microspheres were examined by SEM, TEM, VSM, and FT‐IR. Affinity ligand protein A (ProtA) was covalently immobilized to the amino‐modified magnetic microspheres by the glutaraldehyde method. These ProtA‐immobilized magnetic immunomicrospheres were effective for affinity bioseparation processes, as was demonstrated by the efficient immunoaffinity purification of antibodies IgG2a (22mg per gram of microspheres) from mouse ascites. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2205–2211, 2004     

模拟水中硫离子对不锈钢钝化膜破坏作用的光电化学研究

采用光电化学方法研究了模拟冷却水中硫离子对不锈钢钝化膜的破坏作用.结果表明,不锈钢钝化膜显示n-型光响应,最大吸收峰出现在310 nm处.不锈钢钝化膜在电位约-0.35 V开始出现光电流,随电位升高,光电流增大.钝化膜禁带宽度Eg随电位的升高而减小,并逐渐向铁氧化物的Eg靠近.模拟冷却水中加入硫离子使不锈钢钝化膜的光电流增大,Eg减小.硫离子的浓度越大,测得的光电流越大,而Eg越小,这可归因于钝化膜膜电阻的降低及钝化膜中氧化铬含量的减少.     

浅议各类数据的备份与归档管理

本文从各类数据在计算机中存在的状态以及在存储过程中的安全问题,对数据的安全性和保护性进行了论证。     

1，4，5，8-四硝基-1，4，5，8-四氮杂双环[4.4.0]癸烷合成工艺的改进?

为了改进1,4,5,8-四硝基-1,4,5,8-四氮杂双环[4.4.0]癸烷(TNAD)的合成方法,以1,4,5,8-四氮杂双环[4.4.0]癸烷(THAD)为原料,经成盐、硝化两步反应合成出了TNAD,反应总收率为90%,纯度为98.7%。采用红外光谱、核磁共振氢谱及元素分析对产品结构进行了表征。考察了硝化体系、物料比、反应温度、反应时间对硝化反应的影响,确定了最佳的反应条件:n(THAD.4HNO_3):n(98%HNO_3):n(AC_2O)=1:24:15,反应温度为25℃,反应时间为2 h。     

1，3-双（叠氮乙酰氧基）-2-乙基-2-硝基丙烷的合成与性能

以2-乙基-2-硝基-1,3-丙二醇为原料,经酯化、叠氮化两步反应,合成出了1,3-二(叠氮乙酰氧基)-2-乙基-2-硝基丙烷(ENPEA),总收率为83%。利用红外光谱、核磁共振、元素分析对ENPEA的结构进行了表征。探讨了叠氮化反应的影响因素,确定其最佳反应条件为:n(Na N3)n(ENPE)为2.21.0,混合溶剂中水占总体积的13%~20%,反应时间2 h;性能测试得到ENPEA的玻璃化转变温度为-43.4℃,热分解峰温为252.4℃,密度为1.34 g/cm3,特性落高为120.2 cm(落锤2 kg),爆炸概率为4%(摆角66°)。     

一类具功能反应函数生物系统的定性分析

研究了一类具功能反应函数的食饵-捕食两种群生物系统的定性性质。利用Dulac判别定理,Poincare-Bendixson环域定理等,得到了该系统解的有界性,正平衡点的稳定性和至少存在一个极限环的充分条件。所得结果推广了已有文献的结论。