某高磷鲕状赤铁矿焙烧—磁选—酸浸脱磷试验

针对湖南某高磷鲕状赤铁矿采用磁化焙烧—磁选—酸浸工艺流程进行试验研究,并在硫酸浸出脱磷过程中对试验工艺条件进行了优化。研究结果表明:经还原焙烧—磁选得到的粗精矿,在硫酸浓度为0.2 mol/L、反应时间为10 min、液固比为3∶1、温度常温、搅拌速率为300 r/min的条件下,可使磷含量降低到0.2%,最终全流程获得了产率为62.47%、铁品位为59.52%、铁回收率为90.53%、磷含量为0.2%、除磷率为80.39%的铁精矿。     

某高磷鲕状赤铁矿焙烧—磁选—酸浸脱磷试验

针对湖南某高磷鲕状赤铁矿采用磁化焙烧—磁选—酸浸工艺流程进行试验研究,并在硫酸浸出脱磷过程中对试验工艺条件进行了优化。研究结果表明：经还原焙烧—磁选得到的粗精矿,在硫酸浓度为0.2 mol/L、反应时间为10 min、液固比为3∶1、温度常温、搅拌速率为300 r/min的条件下,可使磷含量降低到0.2%,最终全流程获得了产率为62.47%、铁品位为59.52%、铁回收率为90.53%、磷含量为0.2%、除磷率为80.39%的铁精矿。     

Research on preparation optimization of nano CeB6 powder and its high temperature stability

High temperature self-propagating synthesis (SHS) process is very rapid, the reaction process becomes un-controlled after the SHS reaction is ignited. So the initial reaction conditions will have great effects on phase compositions and microstructures of reaction products. In this paper, the effects of the proportioning amount of Mg on the yield ratio and particle sizes of CeB6 were studied. The SHS reaction products and leached products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the SHS products consisted of MgO, CeB6 and little Mg3B2O6. The single CeB6 phase was contained after the SHS reaction products were leached. The purity of CeB6 was higher than 99.0 mass%, and the minimum particle sizes of CeB6 were within 30-70 nm. When the proportioning amount of Mg was 25% more than the theoretic amount, the yield of CeB?6 was 68.68%. The antioxidant ability of CeB6 was rather stronger, which was oxidized step by step, and the initial oxidation temperature was 750 oC, which indicated that it had good high temperature stability. The apparent activation energies of oxidation reactions of CeB6 were 200.09 and 312.10 kJ/mol, respectively, and reaction orders were 0.69 and 0.40, respectively.     

菱褐铁矿回转窑磁化焙烧技术研究现状

介绍了回转窑磁化焙烧工艺技术的实验室试验、半工业试验、工业试验研究过程以及取得的成果.长沙矿冶研究院开发的大型回转窑磁化焙烧技术与成套装备在处理中低品位菱、褐铁矿的工业试验中取得了圆满成功,同时在此过程中应用了多项先进技术,生产顺畅,产品品质高,获得了较好的经济效益和社会效益,为综合回收处理中低品位菱、褐铁矿提供了良好的途径.     

Preparation of CeB6 nano-powders by self-propagating high-temperature synthesis （SHS）

CeB6 powders were prepared by high-temperature self-propagating synthesis(SHS) in which CeO2,B2O3 and Mg were taken asreactants.The adiabatic temperature and dynamics of SHS reactions were investigated.The SHS reaction products and leached products werecharacterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM).The results indicated that the adiabatic temperature ofMg-B2O3-CeO2 reaction system was rather higher than 1800 K to make the reaction propagate by itself,and the apparent activation energy(Ea)and reaction order(n) of exothermic peak on Mg-B2O3-CeO2 differential scanning calorimetry(DSC) curve were 23.03 kJ/mol and 1.31,respectively.The apparent activation energy was lower,so the reaction occurred easily.The SHS products consisted of MgO,CeB6 and littleMg3B2O6.The leached products consisted of single CeB6 phase and its purity was higher than 99.0%,and the average particle sizes of CeB6were smaller than 150 nm.     

利用高压DSC研究一水铝石在碱液中的溶出动力学

研究一水铝石(包括一水软铝石和一水硬铝石)在氢氧化钠溶液中溶出过程的机理函数并确定相应的动力学参数.将一水铝石矿和氢氧化钠溶液在高压DSC设备中以10 ℃/min的速度加热,用微分方程法分析得到DSC曲线,同时借助Matlab程序利用迭代法和线性最小二乘法计算微分方程,从30种机理函数的微分形式中分别逻辑地选择了两种一...     

回转窑处理中低品位锰矿试验研究

针对含铁的中低品位锰矿石进行了实验室静态及回转窑动态连续试验, 采用还原焙烧-酸浸工艺有效回收金属锰。在回转窑温度750 ℃, 转速2.2 r/min时, 配入10%还原剂进行焙烧; 取焙烧矿280 g, 当浓硫酸用量95 mL, 液固比6∶1, 浸出时间40 min, 搅拌速度300 r/min时, 可获得Mn回收率大于90%的良好指标。进行了除铁探索试验, 可有效降低浸出液中铁含量。该研究为利用回转窑回收中低品位锰矿资源提供了新思路。     

某含铜菱铁矿磁化焙烧选矿试验研究

对某含铜菱铁矿进行了磁化焙烧-磁选回收铁以及磁选尾矿浮选回收铜的试验研究.在焙烧温度800℃、焙烧时间60min、磁选场强96 kA/m以及浮选采用丁黄药+丁胺黑药各100 g/t等工艺条件下,分别获得了产率为61.85％、品位为64.64％、铁回收率为97.88％的铁精矿和产率为0.25％、品位为19.54％、铜回收率为29.37％的铜精矿.