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排序方式: 共有404条查询结果,搜索用时 15 毫秒
1.
Jiri Patocka Ran Wu Eugenie Nepovimova Martin Valis Wenda Wu Kamil Kuca 《International journal of molecular sciences》2021,22(4)
Mushroom poisoning has always been a threat to human health. There are a large number of reports about ingestion of poisonous mushrooms every year around the world. It attracts the attention of researchers, especially in the aspects of toxin composition, toxic mechanism and toxin application in poisonous mushroom. Inocybe is a large genus of mushrooms and contains toxic substances including muscarine, psilocybin, psilocin, aeruginascin, lectins and baeocystin. In order to prevent and remedy mushroom poisoning, it is significant to clarify the toxic effects and mechanisms of these bioactive substances. In this review article, we summarize the chemistry, most known toxic effects and mechanisms of major toxic substances in Inocybe mushrooms, especially muscarine, psilocybin and psilocin. Their available toxicity data (different species, different administration routes) published formerly are also summarized. In addition, the treatment and medical application of these toxic substances in Inocybe mushrooms are also discussed. We hope that this review will help understanding of the chemistry and toxicology of Inocybe mushrooms as well as the potential clinical application of its bioactive substances to benefit human beings. 相似文献
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The effect of alumina particulates on a thermoplastic matrix is investigated, in particular the effect altering the alumina particle size and morphology has on the mechanical properties. Different grades of alumina are used and two thermoplastic matrices; namely poly(propylene) and poly(ethylene-co-vinyl acetate). Investigations showed that optimum properties were achieved with the alumina of smallest particle size and lowest aspect ratio. Preliminary work has also been performed on the use of silane coupling agents and they have proved effective in increasing the tensile properties of the composites. 相似文献
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Cynthia Bruckner-Lea Ryan J. Kimmel Jiri Janata John F. T. Conroy Karin Caldwell 《Electrochimica acta》1995,40(18):2897-2904
Octadecanethiol (ODT) and octanethiol (OT) films at the mercury-electrolyte interface are examined using cyclic voltammetry and differential capacitance measurements at a single frequency. A mercury flow-system is used to alter the volume, and therefore, the surface area and surface pressure of the mercury electrode. Manipulation of the mercury electrode's volume enables the introduction and removal of defects in the insulating thiol films. OT and ODT film behavior are contrasted under conditions of expansion and contraction. ODT forms extremely impermeable layers that allow 1000 time less redox probe current than seen on uncoated drops. Expansion of the mercury electrode to increase the electrode surface area produces defects and pinholes in the thiol film. These defects are almost completely removed when the drop is compressed back to its initial surface area. OT also forms insulating films on mercury sessile drops, however these films contain more defects than ODT films. While expansion of an OT-coated mercury drop increases redox probe current, recompression of the drop does not return the film to its initial condition. Pinholes and defects in the OT and ODT films can also be produced by cycling to negative potentials, which produce abrupt stripping peaks. 相似文献
6.
Fuchs E Gruber T Nitschke J Sick B 《IEEE transactions on pattern analysis and machine intelligence》2010,32(12):2232-2245
The paper presents SwiftSeg, a novel technique for online time series segmentation and piecewise polynomial representation. The segmentation approach is based on a least-squares approximation of time series in sliding and/or growing time windows utilizing a basis of orthogonal polynomials. This allows the definition of fast update steps for the approximating polynomial, where the computational effort depends only on the degree of the approximating polynomial and not on the length of the time window. The coefficients of the orthogonal expansion of the approximating polynomial-obtained by means of the update steps-can be interpreted as optimal (in the least-squares sense) estimators for average, slope, curvature, change of curvature, etc., of the signal in the time window considered. These coefficients, as well as the approximation error, may be used in a very intuitive way to define segmentation criteria. The properties of SwiftSeg are evaluated by means of some artificial and real benchmark time series. It is compared to three different offline and online techniques to assess its accuracy and runtime. It is shown that SwiftSeg-which is suitable for many data streaming applications-offers high accuracy at very low computational costs. 相似文献
7.
The different steps of the dehalogenation reaction carried out by LinB on three different substrates have been characterized using a combination of quantum mechanical calculations and molecular dynamics simulations. This has allowed us to obtain information in atomic detail about each step of the reaction mechanism, that is, substrate entrance and achievement of the near-attack conformation, transition state stabilization within the active site, halide stabilization, water molecule activation and subsequent hydrolytic attack on the ester intermediate with formation of alcohol, and finally product release. Importantly, no bias or external forces were applied during the whole procedure so that both intermediates and products were completely free to sample configuration space in order to adapt to the plasticity of the active site and/or search for an exit. Differences in substrate reactivity were found to be correlated with the ease of adopting the near-attack conformation and two different exit pathways were found for product release that do not interfere with substrate entrance. Additional support for the different entry and exit pathways was independently obtained from an examination of the enzyme's normal modes. 相似文献
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9.
Variable narrowband transmission filters with a wide rejection band for spectrometry 总被引:2,自引:0,他引:2
Variable narrowband transmission filters are useful for the development of compact spectrometers. For this purpose the filter should be directly coupled to the detector and the wavelength of the transmission peak should move in one surface direction over a length of a few millimeters. To obtain both a wide measurement spectrum and high accuracy, the ratio of extreme operating wavelengths is required to be greater than 2:1 and the width of the transmission band narrower than 10 nm. A metal-dielectric variable transmission filter, with an operating range of 400-1000 nm, is proposed. The method for obtaining variable transmission filters, with dimensions of a few millimeters, is described. 相似文献
10.
On the existence of chaos in the electronically adjustable structures of the state variable filters
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Jiri Petrzela 《International Journal of Circuit Theory and Applications》2016,44(10):1779-1797
As demonstrated in the paper, chaotic motion can appear in state variable filters, that is, common network structures dedicated for analog signal processing. In particular, two Kerwin–Huelsman–Newcomb biquadratic filtering sections are considered for theoretical, numerical and experimental analysis. Mathematical models are designed, and conditions for evolution of typical strange attractors are provided. The corresponding largest Lyapunov exponent is calculated and visualized as a function of internal system parameters and the shape of input harmonic waveform. Mutual connection between the mathematical model and the real lumped electronic circuit is discussed in detail. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献