Optical and electrical properties of porous silicon layer formed on the textured surface by electrochemical etching

Porous silicon(PS) layers were formed on textured crystalline silicon by electrochemical etching in HF-based electrolyte.Optical and electrical properties of the TMAH textured surfaces with PS formation are studied. Moreover,the influences of the initial structures and the anodizing time on the optical and electrical properties of the surfaces after PS formation are investigated.The results show that the TMAH textured surfaces with PS formation present a dramatic decrease in reflectance.The longer the anodizing time is,the lower the reflectance.Moreover,an initial surface with bigger pyramids achieved lower reflectance in a short wavelength range.A minimum reflectance of 3.86%at 460 nm is achieved for a short anodizing time of 2 min.Furthermore,the reflectance spectrum of the sample,which was etched in 3 vol.%TMAH for 25 min and then anodized for 20 min,is extremely flat and lies between 3.67%and 6.15%in the wavelength range from 400 to 1040 nm.In addition,for a short anodizing time,a slight increase in the effective carrier lifetime is observed.Our results indicate that PS layers formed on a TMAH textured surface for a short anodization treatment can be used as both broadband antireflection coatings and passivation layers for the application in solar cells.     

X射线弯晶谱仪的几何因数对色散角的影响

在假设谱线的固有宽度可以忽略的情况下 ,本文成功地应用了柱坐标系统来进行定量的分析在弯晶谱仪中由于晶体的几何结构和光源的大小对色散角的影响。为了更具普适性 ,分析了Johann晶体谱仪和点光源 ,同时还有球面晶体谱仪和Johanson晶体谱仪。最后与其他方法所得出的结论做了比较并且给出各种因素对色散角的影响的数据分析     

Texturization of mono-crystalline silicon solar cells in TMAH without the addition of surfactant

Etching was performed on(100) silicon wafers using silicon-dissolved tetramethylammonium hydroxide (TMAH) solutions without the addition of surfactant.Experiments were carried out in different TMAH concentrations at different temperatures for different etching times.The surface phenomena,etching rates,surface morphology and surface reflectance were analyzed.Experimental results show that the resulting surface covered with uniform pyramids can be realized with a small change in etching rates during the et...     

合肥地区户用光储直柔系统设计

为了解决农村户用光伏发电与农户用电不匹配的问题,采用户用光伏和光储直柔的方案,对合肥地区的地理气候、户用能耗进行调研,利用PVsyst软件设计出户用光伏发电系统,并将其与光储直柔系统的设计依据相结合,初步设计了户用光储直柔系统。通过SAM软件进行模拟,从技术经济的角度确定了系统内储能电池的类型和容量,并对系统进行了经济分析,验证了在合肥农村使用户用光储直柔系统的可行性。     

Optical and electrical properties of porous silicon layer formed on the textured surface by electrochemical etching

Porous silicon (PS) layers were formed on textured crystalline silicon by electrochemical etching in HF-based electrolyte. Optical and electrical properties of the TMAH textured surfaces with PS formation are studied. Moreover, the influences of the initial structures and the anodizing time on the optical and electrical properties of the surfaces after PS formation are investigated. The results show that the TMAH textured surfaces with PS formation present a dramatic decrease of reflectance. The longer is the anodizing time, the lower is the reflectance. Moreover, an initial surface with bigger pyramids achieved lower reflectance in short wavelength range. A minimum reflectance of 3.86 % at 460 nm is achieved for a short anodizing time of 2 min. Furthermore, the reflectance spectrum of the sample, which was etched in 3 vol.% TMAH for 25 min and then anodized for 20 min, is extremely flat and lies between 3.67% and 6.15% in the wavelength range from 400 to 1040 nm. In addition, for a short anodizing time, a slight increase in the effective carrier lifetime is observed. Our results indicate that PS layers formed on a TMAH textured surface for a short anodization treatment can be used as both broadband antireflection coatings and passivation layers for the application in solar cells.     

光子晶体绿光滤波器的研究

利用传输矩阵法设计了一种适用于绿光波段的光子晶体窄带滤波器,并研究了影响滤 波器特性的多种因素。结果表明:适当选取光子晶体结构参数,可将滤波器的中心波长移到绿光波段的532nm处,谱线线宽可达0. 0131nm。此外,随着光子晶体周期层数的增加,线宽进一步变窄;当缺陷层厚度减小时,滤波器的中心波长向短波段移动而谱线宽度几乎保持不变;当入射角增大时,滤波器的谱线宽度变窄但变化幅度不大且在小角度范围( 0～3°)内宽度几乎保持不变。这种绿光窄带滤光器有望在蓝绿光通信中得到应用。     

基于光电联合傅立叶变换相关识别的增强技术研究

根据联合傅立叶变换相关识别理论,首先计算模拟其识别过程,然后结合光学傅立叶变换相关识别系统的特点,应用数字图像处理的方法对光学联合傅立叶变换相关识别系统进行改进。实验表明:改进后的光电联合傅立叶变换相关识别系统不仅对相关输出结果有一定增强作用,而且还能够识别出传统光学傅立叶变换相关识别系统所不能识别的对象。     

智慧新能源城乡建设模式应用研究

该文提出智慧新能源城乡建设的新理念.通过对盘锦大洼区城乡村地区的取暖现状、生物质资源现状、红村矿区多能互补取暖项目等进行实地调研,给出了大洼区适宜在既有清洁能源取暖的基础上增加户用光伏取暖、小型生物质发电,形成以电网为基础,综合多种清洁能源输入的区域分布式综合能源系统的新能源建设方案,并针对方案提出了相应技术模式和商业...     

Texturization of mono-crystalline silicon solar cells in TMAH without the addition of surfactant

Texturization of mono-crystalline silicon solar cell by chemical anisotropic etching is still a key issue due to metal ions contamination and consumption of large amount of isopropyl alcohol (IPA) in a conventional mixture of potassium hydroxide (KOH) or sodium hydroxide (NaOH) and IPA. In this study, etching was performed on (100) silicon wafers using silicon-dissolved tetramethylammonium hydroxide (TMAH) solutions without addition of surfactant. Experiments were carried out in different TMAH concentration solutions at different temperatures for different etching time. The surface phenomena, etching rates, surface morphology and surface reflectance have been analyzed. Experimental results show that the resulted surface covered with uniform pyramids can be realized due to small changes of etching rates during the etching process. The etching mechanism has been explained basing on the experimental results and the theoretical considerations. It was suggested that all the components in the TMAH solutions play important roles in the etching process. Moreover, TMA+ ions may increase the wettability of the textured surface. A good textured surface can be obtained on conditions that the absorption of OH- /H2O is equilibrium with that of TMA+/SiO2(OH)22-.