Random poly(ε‐caprolactone‐L‐alanine) by direct melt copolymerization

A series of random polyesteramides (PEAs) with a range of molar composition from 90/10 to 50/50 were synthesized by direct melt polycondensation of ε‐caprolactone and l ‐alanine. Their structure was fully characterized by Fourier transform IR and NMR spectroscopy. The resulting copolymers are completely amorphous with the exception of PEA‐90/10 which possesses a semicrystalline structure. These PEAs present increasing glass transition temperatures at increasing l ‐alanine contents and exhibit fairly good thermal stability with 10% mass loss temperatures reaching 315 °C. © 2020 Society of Industrial Chemistry     

A comparative study of the electrochemical behaviour of Algerian zinc and a zinc from a commercial sacrificial anode

Zinc is used in the oil industry as a sacrificial anode for protecting steel storage tanks from corrosion. The behaviour of a sample of zinc from the Algerian metallurgy industry (zinc A) and a commercially available zinc (zinc B) was compared in an electrolyte from storage tank drainage water. The corrosion potential measurements for zinc A confirmed that this material could be used as a sacrificial anode. The polarization curves of the two materials (zinc A and zinc B) were different, zinc A being the least polarized. Thus, the same corrosion protection could be obtained with a lower surface ratio (S _Zn/S _Fe) for Zinc A. Cyclic voltammetry curves provided evidence of a surface layer formed by dissolution products. To provide protection over extended periods of time, the zinc anode must be oversized. The two types of zinc tested were comparable.The results of the impedance spectroscopy study confirmed the previous results. The corrosion layer formed on zinc A was not prejudicial to dissolution. Hence, the properties of this zinc were found to be satisfactory for its use as a sacrificial anode.     

The vehicle routing problem with restricted mixing of deliveries and pickups

The vehicle routing problem with deliveries and pickups is one of the main problems within reverse logistics. This paper focuses on an important assumption that divides the literature on the topic, namely the restriction that all deliveries must be completed before pickups can be made. A generalised model is presented, together with a mathematical formulation and its resolution. The latter is carried out by adopting a suitable implementation of the reactive tabu search metaheuristic. Results show that significant savings can be achieved by allowing a mixture of delivery and pickup loads on-board and yet not incurring delays and driver inconvenience.     

Lateral Magnetically Modulated Multilayers by Combining Ion Implantation and Lithography

The combination of lithography and ion implantation is demonstrated to be a suitable method to prepare lateral multilayers. A laterally, compositionally, and magnetically modulated microscale pattern consisting of alternating Co (1.6 µm wide) and Co‐CoO (2.4 µm wide) lines has been obtained by oxygen ion implantation into a lithographically masked Au‐sandwiched Co thin film. Magnetoresistance along the lines (i.e., current and applied magnetic field are parallel to the lines) reveals an effective positive giant magnetoresistance (GMR) behavior at room temperature. Conversely, anisotropic magnetoresistance and GMR contributions are distinguished at low temperature (i.e., 10 K) since the O‐implanted areas become exchange coupled. This planar GMR is principally ascribed to the spatial modulation of coercivity in a spring‐magnet‐type configuration, which results in 180° Néel extrinsic domain walls at the Co/Co‐CoO interfaces. The versatility, in terms of pattern size, morphology, and composition adjustment, of this method offers a unique route to fabricate planar systems for, among others, spintronic research and applications.     

Artificial intelligence implementation in the APS process diagnostic

Thermal spray process is a technique of coating manufacturing implementing a wide variety of materials and processes. This technique is characterized by up to 150 processing parameters influencing the coating properties. The control of the coating quality is needed through the consideration of a robust methodology that takes into account the parameter interdependencies, the process variability and offers the ability to quantify the processing parameter-process response relationships. The aim of this work is to introduce a new approach based on artificial intelligence responding to these requirements. A detailed procedure is presented considering an artificial neural network (ANN) structure which encodes implicitly the physical phenomena governing the process. The implementation of such a structure was coupled to experimental results of an optic sensor controlling the powder particle fusion state before the coating formation. The optimization steps were discussed and the predicted results were compared to the experimental ones allowing the identification of the control factors.     

Mesoscopic approach for steady‐state free convection in a diamond array

The purpose of the present paper is testing an in‐house efficiency algorithm based on lattice Boltzmann method (LBM) and using it to resolve the obtained coupled nondimensional governing equations to analyze two‐dimensional free convection inside a cold outer cavity subjected to a heated cylindrical diamond array. Steady state or oscillatory results are obtained using the Bhatnagar‐Gross‐Krook collision model associated to the thermal LBM. Both the velocity and temperature fields are solved using the D2Q9 models. With different Rayleigh numbers (Ra), the tested free convection can either achieve to steady state or oscillatory. We extended our in house Fortran 90 code using curved boundary conditions and implemented them into a cavity with a diamond array. The numerical simulations were done using distinct Ra (10⁶ and 10 ⁷) and distances between the four neighboring circular cylinders aligned in a diamond array. The effects of several physical parameters, including Ra and position of the hot body array on flow and heat transfer characteristics are investigated. The obtained results are highlighted in the form of streamlines, isotherms, and velocities plots. We show in this paper the stability and the efficiency of the LBM to deal with a complex geometry and its ability to reach suitable convergence criteria for high Ra (10 ⁶ and 10 ⁷). The numerical results indicate that LBM can simulate numerical problems with a high Ra reaching a steady state where we can depict the change of the flow pattern and enhancement of the heat transfer in the presence of heated diamond array.     

Provably safe navigation for mobile robots with limited field-of-views in dynamic environments

This paper addresses the problem of navigating in a provably safe manner a mobile robot with a limited field-of-view placed in a unknown dynamic environment. In such a situation, absolute motion safety (in the sense that no collision will ever take place whatever happens in the environment) is impossible to guarantee in general. It is therefore settled for a weaker level of motion safety dubbed passive motion safety: it guarantees that, if a collision takes place, the robot will be at rest.     

Abundant non-toxic materials for thin film solar cells: Alternative to conventional materials

Presented are the results of a comparative analysis to identify abundant, non-toxic binary materials with potential applicability for photovoltaics. Materials other than the conventional Si, CdTe, and Cu(In,Ga)Se₂ (CIGS) are examined. The screening is based on the materials’ bulk properties and a set of environmental, physical, and chemical criteria. The screening process is detailed and the properties and applicability of the screened materials are discussed.