On the development, optical properties and thermal performance of cool colored coatings for the urban environment

This paper reports the measured solar spectral properties and the thermal performance of 10 prototype cool colored coatings, developed at the National and Kapodistrian University of Athens, using near-infrared reflective color pigments in comparison to color-matched, conventionally pigmented coatings. These coatings are developed to be used in the urban environment to fight the heat island effect. The spectral reflectance and the infrared emittance were measured and the solar reflectance of the samples was calculated. The surface temperature of the coatings when applied to concrete tiles was monitored, using surface temperature sensors and a data logging system, on 24 h basis from August to December 2005 in an effort to investigate the ability of the cool colored coatings to maintain lower surface temperatures than conventionally pigmented color-matched coatings. The data obtained has been extensively analysed and indicate significant success in the development of these cool colored coatings. It was found that all the coatings containing infrared reflective pigments have solar reflectance values higher than those of standard coatings. Furthermore, it was demonstrated that cool colored coatings maintain lower surface temperatures than color-matched conventionally pigmented coatings. This temperature difference is mainly due to differences in solar reflectance. These cool colored coatings can be used on buildings (roofs and walls) and other surfaces in the urban environment. Thus, at building scale, the use of cool colored coatings with increased solar reflectance can improve building comfort and reduce cooling energy use, and at city city-scale it can contribute to the reduction of the air temperature due to the heat-transfer phenomena and therefore improve outdoor thermal comfort and reduce the heat-island effect.     

A study of the thermal performance of reflective coatings for the urban environment

This paper presents the results of a comparative study aiming to investigate the effect of reflective coatings on lowering surface temperatures of buildings and other surfaces of the urban environment, and thus test their suitability to lower ambient temperatures and fight the heat island effect. In total, 14 types of reflective coatings, selected from the international market were studied, from August to October 2004, on a 24 h basis. These coatings are used in buildings and some of them are used or could be used in the future in other surfaces of the urban environment (sidewalks, parking lots, etc.). In order to investigate the thermal performance of the reflective coatings, surface temperature sensors and a data logging system as well as infrared thermography procedures were used. The spectral reflectance and the infrared emittance of the samples were also measured. The collected data have been extensively analyzed. It was demonstrated that the use of reflective coatings can reduce a white concrete tile’s surface temperature under hot summer conditions by 4 °C and during the night by 2 °C. It can be warmer, than the ambient air by only 2 °C during the day and cooler than the ambient air by 5.9 °C during the night. “Cool” coatings present superior thermal performance even compared to other “cool” materials. This study can assist in choosing more appropriate coatings for building envelopes and other surfaces of the urban environment, and thus contribute to the mitigation of the heat island effect as well as the reduction of cooling loads and electricity consumption of buildings.     

Biosynthesis of lipids and organic acids by Yarrowia lipolytica strains cultivated on glucose

The biochemical behavior of wild‐type or genetically modified (presenting decreased expression of intracellular acyl‐CoA oxidases) Yarrowia lipolytica strains cultivated on commercial glucose was studied. Flask nitrogen‐limited cultures were performed favoring the production of organic acids (and potentially the accumulation of lipid). Nitrogen depletion induced secretion of citric acid, while intracellular lipid was not produced in high quantities. Maximum total citric acid up to 49 g/L (yield 0.85 g/g glucose) was produced. In some of the wild‐type strains, an increase of glucose in the medium also induced noticeable production of acetic acid. Increasing the amount of added glucose led to an increase in the total lipid quantity (%) produced, although in the stationary growth phase the concentration of lipid declined, indicating lipid degradation even for the genetically modified strains. Total lipid amount did not exceed the value of 14%, while neutral fractions increased with increase in glucose concentration. In all cases, the total microbial lipids and major lipid fractions were composed of C₁₆ and C₁₈ (principally unsaturated) fatty acids. Finally, in several of the strains cultured in media containing a low glucose concentration, unicellular morphology was observed, while at high glucose concentrations mycelia were predominant.     

ApoA1 Deficiency Reshapes the Phenotypic and Molecular Characteristics of Bone Marrow Adipocytes in Mice

In the present study, we studied the effect of apolipoprotein A-1 (APOA1) on the spatial and molecular characteristics of bone marrow adipocytes, using well-characterized ApoA1 knockout mice. APOA1 is a central regulator of high-density lipoprotein cholesterol (HDL-C) metabolism, and thus HDL; our recent work showed that deficiency of APOA1 increases bone marrow adiposity in mice. We found that ApoA1 deficient mice have greatly elevated adipocytes within their bone marrow compared to wild type counterparts. Morphologically, the increased adipocytes were similar to white adipocytes, and displayed proximal tibial-end localization. Marrow adipocytes from wild type mice were significantly fewer and did not display a bone-end distribution pattern. The mRNA levels of the brown/beige adipocyte-specific markers Ucp1, Dio2, Pat2, and Pgc1a; and the expression of leptin were greatly reduced in the ApoA1 knock-out in comparison to the wild-type mice. In the knock-out mice, adiponectin was remarkably elevated. In keeping with the close ties of hematopoietic stem cells and marrow adipocytes, using flow cytometry we found that the elevated adiposity in the ApoA1 knockout mice is associated with a significant reduction in the compartments of hematopoietic stem cells and common myeloid, but not of the common lymphoid, progenitors. Moreover, the ‘beiging’-related marker osteopontin and the angiogenic factor VEGF were also reduced in the ApoA1 knock-out mice, further supporting the notion that APOA1—and most probably HDL-C—regulate bone marrow microenvironment, favoring beige/brown adipocyte characteristics.     

Antibacterial Activity of Copper Nanoparticles against Xanthomonas campestris pv. vesicatoria in Tomato Plants

Copper-based bactericides have appeared as a new tool in crop protection and offer an effective solution to combat bacterial resistance. In this work, two copper nanoparticle products that were previously synthesized and evaluated against major bacterial and fungal pathogens were tested on their ability to control the bacterial spot disease of tomato. Growth of Xanthomonas campestris pv. vesicatoria, the causal agent of the disease, was significantly suppressed by both nanoparticles, which had superior function compared to conventional commercial formulations of copper. X-ray fluorescence spectrometry measurements in tomato leaves revealed that bioavailability of copper is superior in the case of nanoparticles compared to conventional formulations and is dependent on synthesis rather than size. This is the first report correlating bioavailability of copper to nanoparticle efficacy.     

Effect of dehydration on phenolic compounds and antioxidant activity of blackcurrant (Ribes nigrum L.) pomace

This study examined the effect of dehydration on the phenolic compounds and antioxidant activity of blackcurrant (Ribes nigrum L.) pomaces (DBP) subjected to hot air oven drying (HOD), industrial rotary drying (IRD) and freeze drying (FD). Temperature and residence time were evaluated for HOD, whereas air-on and air-off temperature, ratio of drum rotor speed to air speed and particle size were evaluated for IRD. The highest total anthocyanins (ATC) and flavonols (FLV) were obtained in particle size of> 5.0 mm using IRD at 475°C/97°C (air-on/air-off) and higher ratio of drum rotor speed to air speed. Smaller size particles were found susceptible to degradation due to high temperature and retention time applied in IRD, resulting in loss of phenolic compounds in DBP, and thus, HOD was deemed more suitable. Overall, drying method selection and parameters of operation are key in preserving the concentrations of individual HCA and FLV in DBP.     

Experimental testing of cool colored thin layer asphalt and estimation of its potential to improve the urban microclimate

Urban Heat Island refers to the temperature increase in urban areas compared to rural settings, exacerbating the energy consumption of buildings for cooling. The use of highly reflective materials in buildings and urban structures reduces the absorbed solar radiation and contributes to mitigate heat island. This paper presents the results of a study aiming to measure and analyze the solar spectral properties and the thermal performance of 5 color thin layer asphalt samples in comparison to a sample of conventional black asphalt. Computational fluid dynamics (CFD) simulation is used for evaluating the thermal and energy impact of applying the samples in outdoor spaces (roads). The spectrophotometric measurements showed that the colored thin layer asphalt samples are characterized by higher values of solar reflectance compared to the conventional asphalt, which is mainly due to their high near infrared solar reflectance. From the statistical analysis of the surface temperatures it was found that all the colored thin layer asphalt samples demonstrate lower surface temperatures compared to conventional asphalt. The maximum temperature difference recorded was for the off-white sample and was equal to 12 °C. The CFD simulation results show that surface and air temperatures are decreased when applying the color thin layer sample.     

Development and testing of thermochromic coatings for buildings and urban structures

The present study reports the development and comparative testing of thermochromic coating to be used in buildings and urban structures. Experimental results from an extensive comparative analysis of the thermal and physical behaviour of thermochromic, highly reflective (cool), and common coatings are reported and analyzed. The surface temperature was monitored on 24 h basis from August to mid-September 2007. It was revealing that the temperature of thermochromic coatings was lower than cool and common coatings. Measurements of spectral reflectance indicated that the thermochromic coatings at the colored phase (below the transition temperature of 30 °C) are energy-absorbing while at the colorless phase (above the transition temperature of 30 °C) are energy-reflecting. The data obtained was used for the calculation of solar reflectance. The results showed that the solar reflectance of the thermochromic samples was significally higher compared to the cool and common ones. A 10-day period test was also performed showing the impact of solar radiation on thermochromism.The comparative results demonstrate that the use of thermochromic coatings can both contribute to energy savings in buildings, providing a thermally comfortable indoor environment, while can contribute highly to improve the urban microclimate.     

Recent progress on passive cooling techniques: Advanced technological developments to improve survivability levels in low-income households

Low-income households in developed and less developed countries suffer from serious indoor environmental problems such as heat stress, lack of comfort and poor indoor air quality. Passive cooling of buildings and in particular solar and heat protection techniques, heat dissipation and heat amortisation techniques have reached a very high degree of maturity. New technological developments have proven extremely efficient in decreasing the need for cooling and improving indoor environmental conditions. Developments on the field of solar and heat protection, such as highly reflective coatings for the urban environment and the building envelope and new knowledge and developments on the field of ground and convective cooling and ventilation, may help low-income citizens to considerably improve their quality of life during the overheating period. These new developments are characterised by low cost and are easy to apply.     

Estimating the effect of using cool coatings on energy loads and thermal comfort in residential buildings in various climatic conditions

The impact from using cool roof coatings on the cooling and heating loads and the indoor thermal comfort conditions of residential buildings for various climatic conditions is estimated. The energy cooling loads and peak cooling demands are estimated for different values of roof solar reflectance and roof U-value. The results show that increasing the roof solar reflectance reduces cooling loads by 18–93% and peak cooling demand in air-conditioned buildings by 11–27%. The indoor thermal comfort conditions were improved by decreasing the hours of discomfort by 9–100% and the maximum temperatures in non air-conditioned residential buildings by 1.2–3.3 °C. These reductions were found to be more important for poorly or non-insulated buildings. For the locations studied, the heating penalty (0.2–17 kWh/m² year) was less important than the cooling load reduction (9–48 kWh/m² year). The application of cool roof coatings is an effective, minimal cost and easy to use technique that contributes to the energy efficiency and the thermal comfort of buildings.