Recent research progress on bio-oil conversion into bio-fuels and raw chemicals: a review

Recent advances in lignocellulosic biomass valorization for producing fuels and commodities (olefins and BTX aromatics) are gathered in this paper, with a focus on the conversion of bio-oil (produced by fast pyrolysis of biomass). The main valorization routes are: (i) conditioning of bio-oil (by esterification, aldol condensation, ketonization, in situ cracking, and mild hydrodeoxygenation) for its use as a fuel or stable raw material for further catalytic processing; (ii) production of fuels by deep hydrodeoxygenation; (iii) ex situ catalytic cracking (in line) of the volatiles produced in biomass pyrolysis, aimed at the selective production of olefins and aromatics; (iv) cracking of raw bio-oil in units designed with specific objectives concerning selectivity; and (v) processing in fluidized bed catalytic cracking (FCC) units. This review deals with the technological evolution of these routes, in terms of catalysts, reaction conditions, reactors, and product yields. A study has been carried out on the current state-of-knowledge of the technological capacity, advantages and disadvantages of the different routes, as well as on the prospects for the implementation of each route within the scope of the Sustainable Refinery. © 2018 Society of Chemical Industry     

Catalysts of Ni/α-Al2O3 and Ni/La2O3-αAl2O3 for hydrogen production by steam reforming of bio-oil aqueous fraction with pyrolytic lignin retention

This paper reports on the steam reforming, in continuous regime, of the aqueous fraction of bio-oil obtained by flash pyrolysis of lignocellulosic biomass (sawdust). The reaction system is provided with two steps in series: i) thermal step at 200 °C, for the pyrolytic lignin retention, and ii) reforming in-line of the treated bio-oil in a fluidized bed reactor, in the range 600–800 °C, with space-time between 0.10 and 0.45 g_catalyst h (g_bio-oil)⁻¹. The benefits of incorporating La₂O₃ to the Ni/α-Al₂O₃ catalyst on the kinetic behavior (bio-oil conversion, yield and selectivity of hydrogen) and deactivation were determined. The significant role of temperature in gasifying coke precursors was also analyzed. Complete conversion of bio-oil is achieved with the Ni/La₂O₃-αAl₂O₃ catalyst, at 700 °C and space-time of 0.22 g_catalyst h (g_bio-oil)⁻¹. The catalyst deactivation is low and the hydrogen yield and selectivity achieved are 96% and 70%, respectively.     

Hydrogen production by steam reforming of bio-oil/bio-ethanol mixtures in a continuous thermal-catalytic process

The feasibility of the steam reforming of bio-oil aqueous fraction and bio-ethanol mixtures has been studied in a continuous process with two in-line steps: thermal step at 300 °C (for the controlled deposition of pyrolytic lignin during the heating of the bio-oil/bio-ethanol feed) followed by steam reforming in a fluidized bed reactor on a Ni/α-Al₂O₃ catalyst. The effect of bio-ethanol content in the feed has been analyzed in both the thermal and reforming steps, and the suitable range of operating conditions (temperature and space-time) has been determined for obtaining a high and steady hydrogen yield. Higher ethanol content in the mixture feed improves the reaction indices and reduces coke deposition. Operating conditions of 700 °C and space-times higher than 0.23 g_catalyst h (g_bio-oil+EtOH)⁻¹ are suitable for attaining almost fully conversion of oxygenates (bio-oil and ethanol) and hydrogen yields above 93%, with low catalyst deactivation.     

Wear Evolution in a Stranded Rope Subjected to Cyclic Bending

Wire ropes, due to their construction, combine two very interesting properties: high axial strength and flexibility in bending. However, the assemblage of wires to form flexible ropes results in the sliding of contacting wires and the creation of wear scars, which can act as stress risers and reduce the fatigue life of ropes. Therefore, in order to understand the fatigue behavior of wire ropes, the degradation that occurs between the wires and the strands has to be studied first. In this study, after identifying the main wear patterns for a polymer-covered stranded rope, the wear evolution along the number of cycles and the effect of the sheave diameter in the preferential wear sites were analyzed. The tests were carried out in a custom-made Bending over Sheave (BoS) fatigue test bench and short segments of the rope were analyzed by Scanning Electron Microscope (SEM) and confocal imaging profilometry in order to characterize the wear scars. The worn volume and the wear scar depth were selected as the most suitable parameters to characterize the wear behavior of wires. In addition, the importance of the polymeric cover and sheave diameter was proved: a reduction of the sheave diameter results in a bigger wear rate (μm³/cycle).     

Matxin, an open-source rule-based machine translation system for Basque

We present the first publicly available machine translation (MT) system for Basque. The fact that Basque is both a morphologically rich and less-resourced language makes the use of statistical approaches difficult, and raises the need to develop a rule-based architecture which can be combined in the future with statistical techniques. The MT architecture proposed reuses several open-source tools and is based on a unique XML format to facilitate the flow between the different modules, which eases the interaction among different developers of tools and resources. The result is the rule-based Matxin MT system, an open-source toolkit, whose first implementation translates from Spanish to Basque. We have performed innovative work on the following tasks: construction of a dependency analyser for Spanish, use of rich linguistic information to translate prepositions and syntactic functions (such as subject and object markers), construction of an efficient module for verbal chunk transfer, and design and implementation of modules for ordering words and phrases, independently of the source language.