An analytical model to determine the ultimate load on masonry arch bridges.

This paper proposes an analytical elasto–plastic model to describe the behavior of arches. The modeling is carried out using the equations of (i) horizontal equilibrium, (ii) vertical equilibrium and (iii) equilibrium of moments. The latter equations of equilibrium are ordinary differential equations which can easily be solved by adding boundary conditions, imposing restrictions on the horizontal and vertical movement and on the rotation in the abutments of the arch. For masonry arches, including material properties allowing the occurrence of cracks and the subsequent formation of hinges is required. The latter theory has been implemented in a computer program (Matlab), offering numerical simulations. The software was used to illustrate two case-studies, i.e., the assessment of an arch loaded with a vertical point load and one with a horizontal point load.     

Global optimization method for combined spherical-cylindrical wrapping in musculoskeletal upper limb modelling

In musculoskeletal modelling, many muscles cannot be represented as straight lines from origin to insertion because the bony and musculotendinous morphology of neighboring structures causes them to wrap. The majority of these passive structures can be adequately described as simple geometric shapes such as spheres and cylinders. Techniques for describing smooth muscle paths around multiple obstacles have been developed for modelling use. Until now obstacle-set methods have combined the path of single structures. This does not analytically define the shortest smooth path around multiple objects. When a sphere is included in a multiple-object wrapping algorithm, muscle paths around that sphere are restricted to a bundle of planes containing the sphere center. This assumed restriction can compromise the iterative process for finding the true shortest muscle path that satisfies all restrictions of a smooth path. This can cause model instability. The new method involves the determination of the shortest smooth muscle path in a spherical and cylindrical wrapping algorithm. A typical example is musculoskeletal modelling of the upper limb, where the muscle fibers have to wrap over this combination of obstacles.     

Fault tolerant network design inspired by Physarum polycephalum

Physarum polycephalum, a true slime mould, is a primitive, unicellular organism that creates networks to transport nutrients while foraging. The design of these natural networks proved to be advanced, e.g. the slime mould was able to find the shortest path through a maze. The underlying principles of this design have been mathematically modelled in literature. As in real life the slime mould can design fault tolerant networks, its principles can be applied to the design of man-made networks. In this paper, an existing model and algorithm are adapted and extended with stimulation and migration mechanisms which encourage formation of alternative paths, optimize edge positioning and allow for automated design. The extended model can then be used to better design fault tolerant networks. The extended algorithm is applied to several national and international network configurations. Results show that the extensions allow the model to capture the fault tolerance requirements more accurately. The resulting extended algorithm overcomes weaknesses in geometric graph design and can be used to design fault tolerant networks such as telecommunication networks with varying fault tolerance requirements.     

Virtual agent multimodal mimicry of humans

This work is about multimodal and expressive synthesis on virtual agents, based on the analysis of actions performed by human users. As input we consider the image sequence of the recorded human behavior. Computer vision and image processing techniques are incorporated in order to detect cues needed for expressivity features extraction. The multimodality of the approach lies in the fact that both facial and gestural aspects of the user’s behavior are analyzed and processed. The mimicry consists of perception, interpretation, planning and animation of the expressions shown by the human, resulting not in an exact duplicate rather than an expressive model of the user’s original behavior.     

Chloride binding of cement-based materials subjected to external chloride environment – A review

This paper reviews the chloride binding of cement-based materials subjected to external chloride environments. Chloride ion exist either in the pore solution, chemically bound to the hydration products, or physically held to the surface of the hydration products. Chloride binding of cement-based material is very complicated and influenced by many factors, such as chloride concentration, cement composition, hydroxyl concentration, cation of chloride salt, temperature, supplementary cementing materials, carbonation, sulfate ions and electrical field etc. Four different types of binding isotherms, namely linear, Langmuir, Freundlich and BET binding isotherm have been proposed to describe the relationship between free and bound chloride, none of which can accurately express the relationships between free and bound chloride within the whole concentration range. Freundlich binding isotherm seems to be the most approximate one. However, some field data fit linear isotherm well. This may be ascribed to the leakage of hydroxyl ion. Many service life prediction models based on diffusion mechanism alone have been proposed during the past two decades. If chloride ion binding is not considered in the models, it underestimates the predicated service life.     

Management of evacuation in case of fire accidents in chemical industrial areas

Trade-offs between economic and safety arguments exist in the operation of chemical installations, should knock-on calamities induced by fire accidents occur: a sudden installation shutdown might result in substantial economic losses, but may be needed to ensure safety. Due to the very rare nature of domino effect risks induced decision problems an adequate evacuation decision aid model to be used by plant safety management does, to the best of the authors' knowledge, not exist. This paper develops a tentative approach to calculate the economic gains and/or losses linked to the decision problem whether or not, and when, to evacuate chemical installation(s) threatened by possible domino effect risks. The proposed model is illustrated by a case-study based on empirical data.     

Occurrence,prevention and remediation of toxigenic fungi and mycotoxins in silage: a review

Ruminants are considered to be less sensitive towards mycotoxins than monogastric animals because rumen microbiota have mycotoxin‐detoxifying capacities. Therefore the effect of mycotoxins towards ruminants has been studied to a lesser extent compared with monogastric animals. Worldwide, a high proportion of the ruminant diet consists of silages made of forage crops (i.e. all parts of the crop above the stubble are harvested). In practice, silages are often contaminated with multiple mycotoxins. Exposure to a cocktail of mycotoxins can hamper animal production and have severe health consequences. In this article the different aspects associated with mycotoxin contamination of silage are reviewed ‘from seed to feed’. An overview is given on the occurrence of toxigenic fungal species and their concomitant mycotoxins in forage crops before and after ensiling. The mycotoxin load of visually non‐mouldy samples and mouldy hot spots within the same silo is also compared. Subsequently, this review delves into different problem‐solving strategies. A logical first step is prevention of mould growth and mycotoxin production in the field, during harvest and during ensiling. If prevention should fail, several remediation strategies are available. These are listed, mainly focusing on the possibilities of microbial degradation of mycotoxins in vivo in silage. © 2015 Society of Chemical Industry     

Development and validation of an LC-MS/MS method for the simultaneous determination of deoxynivalenol, zearalenone, T-2-toxin and some masked metabolites in different cereals and cereal-derived food

An LC-MS/MS method was developed and validated for the simultaneous determination of deoxynivalenol, zearalenone, T-2-toxin, HT-2-toxin and metabolites, including 3-acetyldeoxynivalenol, 15-acetyldeoxynivalenol, deoxynivalenol-3-glucoside, α-zearalenol, β-zearalenol, zearalenone-4-glucoside, α-zearalenol-4-glucoside, β-zearalenol-4-glucoside and zearalenone-4-sulfate in maize, wheat, oats, cornflakes and bread. Extraction was performed with acetonitrile/water/acetic acid (79/20/1, v/v/v) followed by a hexane defatting step. After filtration, the extract was evaporated and the residue was redissolved in mobile phase for injection. The mobile phase, which consisted of a mixture of methanol and water with 10?mM ammonium acetate, was adjusted to pH 3 with glacial acetic acid. A sample clean-up procedure was not included because of the low recoveries of free and masked mycotoxins and their differences in polarity. The method allowed the simultaneous determination of 13 Fusarium mycotoxins in a one-step chromatographic run using a Waters Acquity UPLC system coupled to a Quattro Premier XE mass spectrometer. The method was validated for several parameters such as linearity, apparent recovery, limit of detection, limit of quantification, precision, expanded measurement uncertainty and specificity. The limits of detection varied from 5 to 13?ng?g?1; those for the limit of quantification from 10 to 26?ng?g?1. The results of the performance characteristics of the developed LC-MS/MS method were in good agreement with the criteria mentioned in Commission Regulation (EC) No. 401/2006. Thirty samples of a variety of food and feed matrices were sampled and analysed between July 2010 and January 2011.     

Making evacuation decisions by using a discrete-time approximation methodology

This article further elaborates the findings by Reniers et al. in 2007 and 2008. A discrete-time approximation is presented to determine the severity of a major accident threat triggering immediate evacuation and its expected resulting costs. By implementing the proposed mathematical model, precautionary evacuation decision problems can be tackled in a realistic way, i.e., allowing for major accident threats with limited duration. Furthermore, the model is moulded into a working procedure which was used to develop software to solve the suggested algorithms. A case-study is provided and the results obtained by application of the methodology are discussed. Using a (realistic) discrete-time approximation computer simulation, we found that ignoring option characteristics may produce suboptimal intervention decisions in shutdown settings.     

Mirror-aided non-LOS VLC channel characterizations with a time-efficient simulation model

Photonic Network Communications - The emerging cost-efficient visible light communication (VLC)-based indoor wireless network requires an economical solution for backhaul transmission....