The Radical Versus Non-radical Reactive Intermediates in the Iron(III) Porphyrin Catalyzed Oxidation Reactions by Hydroperoxides, Hydrogen Peroxide and Iodosylarene

In the catalytic reaction of an iron(III) porphyrin with t-BuOOH, CumOOH, H₂O₂ and C₆F₅IO, cyclohexene was used as a probe substrate. The selective hydroxylation of cyclohexene by hydroperoxides proceeds through radical path and this has been utilized for successful dioxygen activation/autooxidation. For other oxidants epoxide was the major product and the reactions proceed through non-radical path.     

A design advisor for the optimal inspection of circularity tolerance

In the wake of growing importance for quality and the need to reduce inspection costs simultaneously, the need for a scientific method of selecting an optimum inspection strategy for coordinate measuring machine (CMM) based inspection has become very important. The inspection error resulting from CMM inspection is greatly affected by the profile irregularities and the sampling strategy, which includes sample size, sampling methods, and algorithms used for form evaluation. This paper describes a system that can recommend an optimal inspection plan based on the needs of the user. A design of experiments (DOE) based approach is used to relate the inspection error with sampling strategies. Surface irregularities are included in the form of lobes formed on the profile. A new two-way model is proposed that works in both directions between the sampling strategy and the performance metrics. The results indicate that the number of lobes and the sampling method used have little impact on the inspection error, while the sample size and form evaluation algorithms have a significant influence. An inspection plan advisor is presented, which provides an inspection plan based on the estimated shape and acceptable measurement error.     

A meta-analytic review of the relationship between absence and turnover.

A meta-analysis that combined 33 correlations from 17 studies found a corrected average correlation of .330 between absence and turnover. The type of absence measure did not moderate the covariation between absence and turnover, but industry type and study duration did act as moderators. The results are discussed in the context of the "withdrawal" approach to understanding employee behaviors. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Mössbauer Study of the Influence of Fe-Si-N Liquid in the Synthesis of β-Si3N4 from Silica

Mössbauer spectra of the products obtained by carbothermal reduction and distribution of silica in the presence of iron in the temperatures range 1200^o to 1540^o were studied. The preponderance of β- Si₃N₄ over the α form at a higher reaction temperature were assumed to be related to the formation of an Fe-Si-N liquid. The liquid did not alter its composition with the variation of reduction-temprature, Iron had no effect on the reaction mechanism below 1300^oC.     

Favorable influence of ssDNA-functionalized SWCNT on the navigation pattern of C. elegans

Microsystem Technologies - Single-Walled Carbon Nanotubes (SWCNTs) are widely used as potential carriers in drug delivery systems. The objective of this work was to observe the effects of pristine,...     

An investigation of grain boundary sliding in superplasticity at high elongations

Experiments were performed on the superplastic Zn-22% Al eutectoid alloy to determine the contribution of grain boundary sliding at both low (35%) and high (235%) elongations. The tests were conducted at two different strain rates in the superplastic Region II, and the results show that, within the accuracy of the measurements, there is a large sliding contribution at both elongations. By taking detailed measurements of both the magnitude of the sliding offset and the type of interface, it is shown that the average offsets are generally a maximum at the Zn-Zn boundaries, there is less sliding at the Zn-Al interfaces, and the offsets are a minimum at the Al-Al boundaries. In addition, the distributions of the magnitudes of the sliding offsets are similar at both the low and high elongations. It is concluded that grain boundary sliding is an important deformation process in the superplastic Region II and that it remains important even when the elongation is very high. The nature of the results indicates also that experimental observations of the deformation behaviour in superplastic materials at low elongations (up to 50%) provide meaningful information on the behaviour at much higher (superplastic) elongations.On leave from Mechanical Engineering Department, Nanjing Aeronautical Institute, Nanjing, Jiang-su 210002, People's Republic of China.