Spectroscopic Multicomponent Analysis Using Multi-objective Optimization for Variable Selection

The multiple determination tasks of chemical properties are a classical problem in analytical chemistry. The major problem is concerned in to find the best subset of variables that better represents the compounds. These variables are obtained by a spectrophotometer device. This device measures hundreds of correlated variables related with physicocbemical properties and that can be used to estimate the component of interest. The problem is the selection of a subset of informative and uncorrelated variables that help the minimization of prediction error. Classical algorithms select a subset of variables for each compound considered. In this work we propose the use of the SPEA-II （strength Pareto evolutionary algorithm II）. We would like to show that the variable selection algorithm can selected just one subset used for multiple determinations using multiple linear regressions. For the case study is used wheat data obtained by NIR （near-infrared spectroscopy） spectrometry where the objective is the determination of a variable subgroup with information about E protein content （%）, test weight （Kg/HI）, WKT （wheat kernel texture） （%） and farinograph water absorption （%）. The results of traditional techniques of multivariate calibration as the SPA （successive projections algorithm）, PLS （partial least square） and mono-objective genetic algorithm are presents for comparisons. For NIR spectral analysis of protein concentration on wheat, the number of variables selected from 775 spectral variables was reduced for just 10 in the SPEA-II algorithm. The prediction error decreased from 0.2 in the classical methods to 0.09 in proposed approach, a reduction of 37%. The model using variables selected by SPEA-II had better prediction performance than classical algorithms and full-spectrum partial least-squares.     

Water soluble trehalose-derived oligoamides

A new family of oligotrehaluronamides was synthesized through the polycondensation of α,α-trehaluronic acid dimethyl ester and different diamines or polyamines. In particular, diamines with different molecular structure (1,n-alkylene diamines, aromatic diamine, and alkyleneoxydiamine) were used in order to modulate the molecular weights and the physical characteristics of the products, such as T_g, hydrophilic or hydrophobic properties, and solubility. α,α-Trehaluronic acid was obtained from a renewable source as α,α-trehalose. The syntheses of oligotrehaluronamides were carried out in different solvents such as ethanol, methanol, THF and DMSO, using triethylamine as catalyst. All the compounds obtained in this study were characterized through FT-IR and NMR spectroscopy. The molecular weights were evaluated by ¹H-NMR and in some cases compared with those obtained from ESI-MS spectrometry. Glass transition temperatures and melting points were detected by differential scanning calorimetry. Low molecular weight oligoamides, containing several hydroxyl groups, are water-soluble and could be used in water-based formulations.     

Use of Digital Terrestrial Photogrammetry in rocky slope stability analysis by Distinct Elements Numerical Methods

Current approaches to rocky slope stability analysis require knowledge of the geometrical–structural setting, as well as the physical–mechanical properties of the intact material and its discontinuities. The physical–mechanical properties are derived from in situ and laboratory tests, whereas the geometrical characteristics come from field attitude measurements. Frequently, the inaccessibility of walls does not allow direct measurement of discontinuity surfaces by traditional geological methods. In such cases, data can only be obtained by statistical methods. Although this approach is significant and provides spatial meaning, it is ineffective for deterministic analysis.This paper provides a solution to this problem by applying digital terrestrial photogrammetric techniques employing a reamed bar, an aerostatic balloon and a helicopter. Results demonstrate that the accuracy and the quantity of geometrical and engineering–geological data coming from the photogrammetric survey, allow for numerical simulation of the relationship between rock elements as a function of their physical–mechanical properties and load conditions. The 3DEC code was chosen among the different methods available to model the discontinuous media through distinct elements.The proposed methodology was applied to a quarry located in the Carrara Marble District (the Apuan Alps, Italy), the largest and most exploited mining region in Europe. The economic value of the area required a detailed study of the presence of instability phenomena so that marble extraction could continue in safe conditions.     

Assessment of Forchheimer's Equation to Predict the Permeability of Ceramic Foams

Correct estimation of the pressure drop in filtration processes that involve fluid velocity variations is of major importance, because it allows the filtration rate and/or the energy consumed on fluid flow to be more accurately controlled. Permeability of porous filters has been often described by Forchheimer's equation, which establishes a nonlinear dependence between pressure drop and fluid velocity. Two constants, k ₁ and k ₂, dependent only on the medium, quantify the viscous and inertial effects on the pressure drop curve. In this work, experimental data of airflow through 10 pores per linear inch ceramic foam filters are used to show that a single sample may have completely distinct permeability constants depending on the data range chosen for analysis. The Darcian permeability constant k ₁ displays higher variation than the non-Darcian permeability constant k ₂. The conclusion is that special attention must be taken to represent permeability of highly porous structures in a large velocity range. The predictability of Forchheimer's equation generally worsens when less data are included in the curve fitting, particularly at low velocities. Careful consideration should be made if constants k ₁ and k ₂ are intended to be used for permeability estimation beyond the fitting range.     

Stability analysis of “Grotta delle Felci” Cliff (Capri Island,Italy): structural,engineering–geological,photogrammetric surveys and laser scanning

A study of rock slope stability was performed using geological surveys and Digital Terrestrial Photogrammetry (DTP) integrated by Laser Scanning (LS) and topographic measurements. The use of DTP is useful especially in inaccessible sites such as natural cliffs. By obtaining oriented stereo images, accurate digital surface models and orthophotos, useful data can be produced showing geometrical characteristics of joints, blocks and slopes such as planes, attitude, spacing, persistence and rock mass volumes. In order to accomplish the analysis, DTP was combined with LS in order to build the Digital Dense Surface Model (DDSM) of the slope. The conventional method of limit equilibrium was applied to study the slope stability using a deterministic approach and to suggest activities of geo-monitoring and engineering solutions for risk mitigation with respect to the environment.     

A PROCEDURE FOR FATIGUE LIFE PREDICTION OF SPOT WELDED JOINTS

Abstract— The problem of predicting the fatigue life of spot welded joints has not yet been satisfactorily resolved. Several approaches exist, but many of them are difficult to apply to general structures, which are widely different from simple laboratory specimens. A general criterion is proposed in this paper, based on a theoretical extrapolation of the radial stress. The criterion must be used together with a Finite Element model of the joint and so this paper presents the steps required to get the necessary FE data; steps that are also applicable to the case of complex joints. The advantage of the proposed method is its independence of notch effects near the spot-weld edge. The suggested procedure is applied to several specimens of different materials and the results obtained are successfully compared with experimental data.     

The laparoscopic treatment of splenic rupture, a case report

This retrospective study presents data from 26 women who underwent a reversal of female sterilization. The intrauterine pregnancy rate and ectopic pregnancy rate were 38.5% and 7.7% respectively. The most successful site of tubal anastomosis was isthmic-isthmic anastomosis. The importance of proper patient selection and factors that affect the success rate in attempted reversals are emphasised. The importance of microsurgical approach is highlighted.