Proficiency on underlying mechanism of rubber-metal adhesion has been increased significantly in the last few decades. Researchers have investigated the effect of various ingredients, such as hexamethoxymethyl melamine, resorcinol, cobalt stearate, and silica, on rubber-metal interface. The role of each ingredient on rubber-metal interfacial adhesion is still a subject of scrutiny. In this article, a typical belt skim compound of truck radial tire is selected and the effect of each adhesive ingredient on adhesion strength is explored. Out of these ingredients, the effect of cobalt stearate is found noteworthy. It has improved adhesion strength by 12% (without aging) and by 11% (humid-aged), respectively, over control compound. For detailed understanding of the effect of cobalt stearate on adhesion, scanning electron microscopy and energy dispersive spectroscopy are utilized to ascertain the rubber coverage and distribution of elements. X-ray photoelectron spectroscopy results helped us to understand the impact of CuXS layer depth on rubber-metal adhesion. The depth profile of the CuXS layer was found to be one of the dominant factors of rubber-metal adhesion retention. Thus, this study has made an attempt to find the impact of different adhesive ingredients on the formation of CuXS layer depth at rubber-metal interface and establish a correlation with adhesion strength simultaneously. 相似文献
The article investigates the finite sample properties of estimators for spatial autoregressive models where the disturbance
terms may follow a spatial autoregressive process. In particular we investigate the finite sample behavior of the feasible
generalized spatial two-stage least squares (FGS2SLS) estimator introduced by Kelejian and Prucha (1998), the maximum likelihood
(ML) estimator, as well as that of several other estimators. We find that the FGS2SLS estimator is virtually as efficient
as the ML estimator. This is important because the ML estimator is computationally burdensome, and may even be forbidding
in large samples, while the FGS2SLS estimator remains computationally feasible in large samples.
Received: 20 January 2001 / Accepted: 31 August 2001 相似文献
A tricyclazole selective chitosan/Fe3O4 magnetic molecularly imprinted polymer (MMIP) was synthesized using non-covalent binding polymerization involving methacrylic acid (MAA) as functional monomer, divinylbenzene (DVB-80) as crosslinker, 2,2'-azobisisobutyronitrile as initiator, acetonitrile/toluene (75:25, v/v) as porogenic solvent and tricyclazole as template. Surface morphology and magnetic characterization of the prepared imprinted and non-imprinted polymers were done using scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectrometry and vibrating sample magnetometry, respectively. The adsorption kinetic data fitted best in pseudo-second-order model. The adsorption equilibrium was achieved in 30 min and the maximum binding capacity was 4579.9 µg/g. The Freundlich isotherm model was found suitable for explaining the binding isotherm data (R2 > 0.99). Negative values of thermodynamic parameters ∆G (Gibb’s free energy), ∆H (enthalpy), and ∆S (entropy) revealed exothermic and spontaneous nature of adsorption processes. It also revealed decreased randomness at the solid–liquid interface during sorption. The scatchard plot analysis suggested heterogeneity of binding sites on MMIPs. The molecular recognition selectivity of MMIPs towards tricyclazole was much higher, as compared to its structural analogues, tebuconazole (α = 28.58) and hexaconazole (α = 37.16). The MMIPs were successfully applied to separate and enrich tricyclazole from fortified samples of rice and water, with a recovery percentage of 89.4% and 90.9%, respectively. These reusable imprinted polymers possessing high selectivity and specificity can be utilized as an adsorbent for solid-phase extraction in sample preparation for tricyclazole residue analysis in complex environmental matrices.
Silicon - In this article, the electrical behavior of short channel SiGe Heterostructure Junction-Less DG-MOSFET have been studied by incorporating the quantum mechanical effect and short channel... 相似文献
In an attempt to toughen the epoxy resin matrix for fiber-reinforced composite applications, a chemical modification procedure of a commercially available bisphenol-A-based epoxy resin using reactive liquid rubber HTBN [hydroxy-terminated poly(butadiene-co-acrylonitrile)] and TDI (tolylene diisocyanate) is described. The progress of the reaction and the structural changes during modification process are studied using IR spectroscopy, viscosity data, and chemical analysis (epoxy value determination). The studies support the proposition that TDI acts as a coupling agent between the epoxy and HTBN, forming a urethane linkage with the former and an oxazolidone ring with the latter. The chemical reactions that possibly take place during the modification are discussed. 相似文献
Finite depth-of-field poses a problem in light optical imaging systems since the objects present outside the range of depth-of-field appear blurry in the recorded image. Effective depth-of-field of a sensor can be enhanced considerably without compromising the quality of the image by combining multi-focus images of a scene. This paper presents a block-based algorithm for multi-focus image fusion. In general, finding a suitable block-size is a problem in block-based methods. A large block is more likely to contain portions from both focused and defocused regions. This may lead to selection of considerable amount of defocused regions. On the other hand, small blocks do not vary much in relative contrast and hence difficult to choose from. Moreover, small blocks are more affected by mis-registration problems. In this work, we present a block-based algorithm which do not use a fixed block-size and rather makes use of a quad-tree structure to obtain an optimal subdivision of blocks. Though the algorithm starts with blocks, it ultimately identifies sharply focused regions in input images. The algorithm is simple, computationally efficient and gives good results. A new focus-measure called energy of morphologic gradients is introduced and is used in the algorithm. It is comparable with other focus measures viz.energy of gradients, variance, Tenengrad, energy of Laplacian and sum modified Laplacian. The algorithm is robust since it works with any of the above focus measures. It is also robust against pixel mis-registration. Performance of the algorithm has been evaluated by using two different quantitative measures. 相似文献
Purpose: To develop and optimize nanoemulsion (NE)-based emulgel (EG) formulation as a potential vehicle for topical delivery of tea tree oil (TTO).Methodology: Central composite design was adopted for optimizing the processing conditions for NE preparation by high energy emulsification method viz. surfactant concentration, co-surfactant concentration, and stirring speed. The optimized NE was developed into emulgel (EG) using pH sensitive polymer Carbopol 940 and triethanolamine as alkalizer. The prepared EG was evaluated for its pH, viscosity, and texture parameters, ex vivo permeation at 37?°C and stability. Antimicrobial evaluation of EG in comparison to conventional gel and pure TTO was also carried out against selected microbial strains.Results and discussion: Optimized NE had particle size and zeta potential of 16.23?±?0.411?nm and 36.11?±?1.234?mV, respectively. TEM analysis revealed the spherical shape of droplets. The pH of EG (5.57?±?0.05?) was found to be in accordance with the range of human skin pH. EG also illustrated efficient permeation (79.58?μL/cm2) and flux value (JSS) of 7.96?μL cm2/h through skin in 10?h. Viscosity and texture parameters, firmness (9.3?±?0.08?g), spreadability (2.26?±?0.06?mJ), extrudability (61.6?±?0.05?mJ), and adhesiveness (8.66?±?0.08?g) depict its suitability for topical application. Antimicrobial evaluation of EG with same amount of TTO as conventional gel revealed broader zones of growth inhibitions against all the selected microbial strains. Moreover, EG was also found to be nonirritant (PII 0.0833). These parameters were consistent over 90 d.Conclusion: TTO EG turned out to be a promising vehicle for the topical delivery of TTO with enhanced therapeutic efficacy. 相似文献
Researchers have identified network effects as one of the major drivers for the adoption and diffusion of household technologies. However, the mechanisms and social contexts through which network effects induce technology adoption are unclear. In this paper, we investigate the adoption of household computers using the dataset from the 1989-2003 Computer and Internet Supplement to the Current Population Surveys (CPS). We argue that social influence and learning play a dominant role in inducing the adoption of home computers, and workplaces and schools are important channels through which network effects take place. We find that recent adopters have a stronger impact than distant adopters on future computer adoptions. When the adoption rate is low, channels play a more important role, but their effects diminish as the adoption rate grows. We also find that diffusion channels are more effective for first-time adoption than for repeat purchases. Overall, our study provides important theoretical, policy, and managerial implications. 相似文献