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1.
2.
Flame structure and NO emission characteristics in counterflow diffusion flame of blended fuel of H2/CO2/Ar have been numerically simulated with detailed chemistry. The combination of H2, CO2 and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of CO2. A radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. The detailed chemistry adopts the reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions. All mechanisms including thermal, NO2, N2O and Fenimore are taken into account to separately evaluate the effects of CO2 addition on NO emission characteristics. The increase of added CO2 quantity causes flame temperature to fall since at high strain rates a diluent effect is prevailing and at low strain rates the breakdown of CO2 produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the contribution of NO production by N2O and NO2 mechanisms are negligible and that thermal mechanism is concentrated on only the reaction zone. As strain rate and CO2 quantity increase, NO production is remarkably augmented. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
3.
Nanocomposites based on poly(butylene terephthalate) (PBT) and an organoclay (Cloisite 30B) were prepared by melt blending using a twin‐screw extruder. Two kinds of PBTs, ie PBT‐A and PBT‐B, with different inherent viscosities (ηinh), were used for this study (ηinh of PBT‐A and PBT‐B were 0.74 and 1.48, respectively). Dispersion of the clay layers in the PBT nanocomposites was characterized by using X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Tensile and dynamic mechanical properties and non‐isothermal crystallization temperatures of the nanocomposites were also examined. Nanocomposites based on the higher‐viscosity PBT (PBT‐B) showed a higher degree of exfoliation of the clay and a higher reinforcing effect when compared to the composites based on the lower‐viscosity PBT (PBT‐A). The clay nanolayers dispersed in PBT matrices lead to increases in the non‐isothermal crystallization temperatures of the PBTs, with such increases being more significant for the PBT‐B nanocomposites than for the PBT‐A nanoocomposites. Copyright © 2004 Society of Chemical Industry 相似文献
4.
Du Young Choi Long Mei Jin Dexian Wang Kyung Ho Row 《Korean Journal of Chemical Engineering》2005,22(3):465-469
High-performance frontal analysis (HPFA) was used for a protein binding study of isoflavones (daidzein, genistin, and genistein),
enantiomers of perillyl alcohol and S-ibuprofen to human serum albumin (HSA). The analyses were performed on a Develosil and
Inertsil 100-Diol-5 column (10 cm×4.6mm). Sodium phosphate solution (pH 7.4, ionic strength 0.17) was used as the mobile phase
at a flow rate of 1 ml/min. To ensure the drug to be eluted as a trapezoidal peak with a plateau, injection volumes were each
fixed up the zonal profile with an evident plateau appears. The unbound drug concentration was determined from a plateau height
of the plateau region after that experimental data were fitted by Scatchard equation. The binding constants (K) and total
binding affinities (nK) of drugs to HSA were calculated, respectively. 相似文献
5.
Zhihui Zhang Bing Q. Han Kyung H. Chung Enrique J. Lavernia 《Metallurgical and Materials Transactions A》2006,37(7):2265-2273
The current study aims to provide fundamental insight into the behavior of microstructures containing grain sizes that span
multiple length scales. A commercial 5083 Al alloy was selected as the material of interest to facilitate comparison with
recently published data. The materials studied here were prepared via the thermal consolidation of powders that were cryomilled
for different times (i.e., 0, 2, 4, and 8 hours). Following consolidation, the resultant microstructure was characterized by an equiaxed grain morphology
with a size distribution centered around 200∼300 nm. Dispersed among the 200- to 300-nm grains were coarse-grained regions
or ligaments with a grain size ranging from 600 nm to 2 μm. The occurrence of coarse-grained regions is rationalized on the
basis of recrystallization or subgrain coarsening, whereas the occurrence of equiaxed fine regions is proposed to be a result
of continuous grain growth. Two types of microstructures were selected for study, containing coarse-grained volumes of approximately
28 pct and 43 pct that corresponded to an ultimate tensile strength (UTS) of 566 MPa and 535 MPa, and a fracture strain of
3.2 pct and 3.5 pct, respectively. The observed ductility and the relevant toughening mechanisms were discussed in light of
the presence of multiple length scales. 相似文献
6.
Sang-Hoon Lee Dae Hwan Kim Kyung Rok Kim Jong Duk Lee Byung-Gook Park Young-Jin Gu Gi-Young Yang Jeong-Taek Kong 《Nanotechnology, IEEE Transactions on》2002,1(4):226-232
A practical model for a single-electron transistor (SET) was developed based on the physical phenomena in realistic Si SETs, and implemented into a conventional circuit simulator. In the proposed model, the SET current calculated by the analytic model is combined with the parasitic MOSFET characteristics, which have been observed in many recently reported SETs formed on Si nanostructures. The SPICE simulation results were compared with the measured characteristics of the Si SETs. In terms of the bias, temperature, and size dependence of the realistic SET characteristics, an extensive comparison leads to good agreement within a reasonable level of accuracy. This result is noticeable in that a single set of model parameters was used, while considering divergent physical phenomena such as the parasitic MOSFET, the Coulomb oscillation phase shift, and the tunneling resistance modulated by the gate bias. When compared to the measured data, the accuracy of the voltage transfer characteristics of a single-electron inverter obtained from the SPICE simulation was within 15%. This new SPICE model can be applied to estimating the realistic performance of a CMOS/SET hybrid circuit or various SET logic architectures. 相似文献
7.
An efficient way to implement the surface impedance boundary conditions (SIBC) for the finite-difference time-domain (FDTD) method is presented in this paper. Surface impedance boundary conditions are first formulated for a lossy dielectric half-space in the frequency domain. The impedance function of a lossy medium is approximated with a series of first-order rational functions. Then, the resulting time-domain convolution integrals are computed using recursive formulas which are obtained by assuming that the fields are piecewise linear in time. Thus, the recursive formulas derived here are second-order accurate. Unlike a previously published method [7] which requires preprocessing to compute the exponential approximation prior to the FDTD simulation, the preprocessing time is eliminated by performing a rational approximation on the normalized frequency-domain impedance. This approximation is independent of material properties, and the results are tabulated for reference. The implementation of the SIBC for a PEC-backed lossy dielectric shell is also introduced 相似文献
8.
On the influence of N on residual microstrain in cryomilled Ni 总被引:1,自引:0,他引:1
Kyung H. Chung Entrique J. Lavernia 《Metallurgical and Materials Transactions A》2002,33(12):3795-3801
The factors that influence the development of residual microstrain during milling in a liquid nitrogen atmosphere, defined
hereafter as cryomilling, are investigated. The residual microstrains in cryomilled Ni, processed under various cryomilling
conditions, were examined by X-ray diffraction (XRD) and analyzed through the single line approximation (SLA) method. The
average residual microstrains are determined to be in the range of 2×10−3 to 6×10−3. The residual microstrain on the (200) plane is higher than those on the other planes by 33 pct. The residual microstrain
and its anisotropy in Ni are reduced after heat treatment at 800 °C for 1 hour. The measured microstrain is proposed to evolve
from the presence of N and O as impurity atoms in the Ni lattice. Both N and O are introduced from the environment and then
their solubility in Ni is enriched via the generation of defects that occurs during cryomilling. The stable site for N and O atoms in Ni is the octahedral site,
and the sizes of N and O atoms exceed those of the octahedral site of Ni by 48 and 16 pct respectively. Accordingly, a lattice
strain field is expected around interstitial N atoms that are located at octahedral sites. By comparing the crystal structure
around the octahedral site, the stable site for impurity N atoms, in the Ni lattice with that of Ni3N structure, the lattice strains are estimated to be in the range of 5 to 15 pct. The result shows that the (200) plane has
strains that are 2 times higher than those in other planes, and this is argued to be the reason for the measured anisotropy
of residual strain in Ni after cryomilling. 相似文献
9.
The flow behavior in an open two-phase natural circulation loop was studied experimentally using Freon-113. The heat flux, inlet- and exit-restrictions, liquid charging level and inlet subcooling were taken as parameters. As a result, three basic circulation modes were observed with variation of the heat flux: periodic circulation (A), continuous circulation, and periodic circulation (B). Of these modes, only the continuous circulation mode was stable and the maximum circulation rate appeared with this mode. An increase in the inlet-restriction and/or decrease in the exit-restriction broadened the range of the continuous circulation mode and stabilized the system. When the liquid charging level was lowered or the inlet subcooling was decreased, the continuous circulation mode started at a lower heat flux and the system became stable. The results are summarized on instability maps in the plane of heat flux vs. inlet subcooling. 相似文献
10.
Suk Lee Kyung Chang Lee Man Hyung Lee Harashima F. 《Industrial Electronics, IEEE Transactions on》2002,49(3):693-701
This paper focuses on a method to integrate mobile devices such as a mobile robot, automated guided vehicle, and unmanned container transporter to form an automated material handling system. In this paper, the stationary devices are connected via a Profibus network while the mobile devices are communicating via an IEEE 802.11 wireless LAN. In order to integrate these two networks, a protocol converter is developed on a PC platform that runs two interacting processes with shared internal buffers. The protocol converter performs a role of translator between two different protocols by converting the format of a data frame. In addition to this basic conversion function, the protocol converter has a virtual polling algorithm to reduce the uncertainty involved in accessing the wireless network. Finally, the integrated network. of Profibus and IEEE 802.11 is experimentally evaluated for its data latency and throughput, which shows the feasibility of the Profibus-IEEE 802.11 network for industrial applications involving mobile devices 相似文献