Synthesis,characterization and ion exchange properties of zirconium(IV) tungstoiodophosphate,a new cation exchanger

Zirconium(IV) tungstoiodophosphate has been synthesized under a variety of conditions. The most chemically and thermally stable sample is prepared by adding a mixture of aqueous solutions of 0·5 mol L⁻¹ sodium tungstate, potassium iodate and 1 mol L⁻¹ orthophosphoric acid to aqueous solution of 0·1 mol L⁻¹ zirconium(IV) oxychloride. Its ion exchange capacity for Na⁺ and K⁺ was found to be 2·20 and 2·35 meq g⁻¹ dry exchanger, respectively. The material has been characterized on the basis of chemical composition, pH titration, Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis. The effect on the exchange capacity of drying the exchanger at different temperatures has been studied. The analytical importance of the material has been established by quantitative separation of Pb²⁺ from other metal ions.     

Method to Characterize the Air Flow and Water Removal Characteristics During Vacuum Dewatering. Part II—Analysis and Characterization

This is part II of a study reported earlier on a method to characterize the air flow and water removal characteristics during vacuum dewatering. This article presents experimental data and analysis of results from the use of a cyclically actuated vacuum dewatering device for removing moisture from wetted porous materials such as paper with the intermittent application of vacuum and accompanying air flow though the material. Results presented include sheet moisture content as a function of residence time and hence water removal rate under a variety of process conditions. Also, experimental results on air flow through the wet porous structure and hence the role and importance of air flow during vacuum dewatering are presented. Vacuum dewatering process conditions include exit solids content between 11 and 20% solid under applied vacuum conditions of 13.5 to 67.7 kPa (4 to 20 in. Hg). Regression analysis indicated that the exit sheet moisture content exhibited a nonlinear relationship with residence time with exit solids reaching a plateau after a certain residence time. Final moisture content correlated linearly with the average overall flow rate of air through the paper sample and the basis weight of the material.     

A finite range failure model

In the present article the characterstics of a finite range failure time distribution, that includes the rectangular distribution as a particular case, are studied. When shape parameter surpass unity then the distribution is IFR otherwise it always remains IFRA. A graphic shape of the distribution is also formed for certain admissible values of the constants.     

Potent and selective bicyclic lactam inhibitors of thrombin: Part 2: P1 modifications

The synthesis and antithrombotic activity of a series of nonpeptide bicyclic thrombin inhibitors is described. We have explored the SAR with modifications to the P1 site. The introduction of arginine mimetics at the P1 site led to potent and selective thrombin inhibitors.     

Random-effects regression analysis of correlated grouped-time survival data

Random-effects regression modelling is proposed for analysis of correlated grouped-time survival data. Two analysis approaches are considered. The first treats survival time as an ordinal outcome, which is either right-censored or not. The second approach treats survival time as a set of dichotomous indicators of whether the event occurred for time periods up to the period of the event or censor. For either approach both proportional hazards and proportional odds versions of the random-effects model are developed, while partial proportional hazards and odds generalizations are described for the latter approach. For estimation, a full-information maximum marginal likelihood solution is implemented using numerical quadrature to integrate over the distribution of multiple random effects. The quadrature solution allows some flexibility in the choice of distributions for the random effects; both normal and rectangular distributions are considered in this article. An analysis of a dataset where students are clustered within schools is used to illustrate features of random-effects analysis of clustered grouped-time survival data.     

Infrared spectroscopic investigation of tannins

Infrared spectroscopy is suggested as a diagnostic method for the characterisation and qualitative estimation of the two classes of tannins. Gallic acid, tannic acid and chebulinic acid have been taken as model compounds for the hydrolysable and catechin for the condensed tannins. The former class is marked by the presence of strong absorption maxima at 1710 – 35 cm^?1. The two classes have characteristic pattern of absorption, from which it is possible to characterise the particular type of tannin.     

Parameter estimation for five- and seven-parameter photovoltaic electrical models using evolutionary algorithms

Equivalent electric circuit modeling of PV devices is widely used to predict PV electrical performance. The first task in using the model to calculate the electrical characteristics of a PV device is to find the model parameters which represent the PV device. In the present work, parameter estimation for the model parameter using various evolutionary algorithms is presented and compared. The constraint set on the estimation process is that only the data directly available in module datasheets can be used for estimating the parameters. The electrical model accuracy using the estimated parameters is then compared to several electrical models reported in literature for various PV cell technologies.     

A formal mapping-based approach for distributed schedule coordination on projects

Construction projects involve a large number of participants with overlapping scope of work. Coordination of their activities is usually an iterative manual task undertaken by a general contractor that is often unaware of the detailed constraints of other participants. Project schedules play a key role in this coordination and form the backbone of almost all current approaches to process coordination. However, no single schedule represents the perspective of all participants involved in a project. Rather, each participant keeps in some manner a schedule for its own activities, resulting in multiple schedules that need to be coordinated. The current literature does not support simultaneous reasoning across multiple distributed, overlapping schedules. This paper introduces constructs to formalize the integration of participants’ overlapping schedules that represent the same project tasks, but use a different set breakdown structures and level of detail. Implementation of these constructs allows linking of the master schedule to the other participants’ schedules thereby representing the perspectives of all project participants. This integrated perspective facilitates initial schedule coordination and allows rapid identification of schedule conflicts in response to any schedule changes.     

Infrared Spectroscopy-Based Chemometric Analysis for Lard Differentiation in Meat Samples

One of the most pressing concerns for the consumer market is the detection of adulteration in meat products due to their preciousness. The rapid and accurate identification mechanism for lard adulteration in meat products is highly necessary, for developing a mechanism trusted by consumers and that can be used to make a definitive diagnosis. Fourier Transform Infrared Spectroscopy (FTIR) is used in this work to identify lard adulteration in cow, lamb, and chicken samples. A simplified extraction method was implied to obtain the lipids from pure and adulterated meat. Adulterated samples were obtained by mixing lard with chicken, lamb, and beef with different concentrations (10%–50% v/v). Principal component analysis (PCA) and partial least square (PLS) were used to develop a calibration model at 800–3500 cm⁻¹. Three-dimension PCA was successfully used by dividing the spectrum in three regions to classify lard meat adulteration in chicken, lamb, and beef samples. The corresponding FTIR peaks for the lard have been observed at 1159.6, 1743.4, 2853.1, and 2922.5 cm⁻¹, which differentiate chicken, lamb, and beef samples. The wavenumbers offer the highest determination coefficient R² value of 0.846 and lowest root mean square error of calibration (RMSEC) and root mean square error prediction (RMSEP) with an accuracy of 84.6%. Even the tiniest fat adulteration up to 10% can be reliably discovered using this methodology.     

The optimal solution for the flow of a fourth-grade fluid with partial slip

The steady flow of a non-Newtonian fluid when slippage between the plate and the fluid occurs is considered. The constitutive equations of the fluid are modeled for a fourth-grade non-Newtonian fluid with partial slip; they give rise to nonlinear boundary value problems. Analytical solutions are obtained using powerful analytic techniques for solving nonlinear problems, homotopy perturbation and optimal homotopy asymptotic methods. The results obtained are compared with the numerical results and it is shown that solutions exist for all values of the non-Newtonian parameters. The solutions valid for the no-slip condition for all values of the non-Newtonian parameters can be derived as special cases of the present analysis. Finally the solutions are discussed using a graphical approach.