Determination of the vapor pressures of select polychlorinated dibenzo-p-dioxins and dibenzofurans at 75-275 °C

Vapor pressures were determined for several polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) at 75-275 °C, extending the available literature data to more relevant temperature regions and providing the first experimental data for 2,3,7-trichlorodibenzo-p-dioxin (2,3,7-TriCD). A modification of the effusion technique, based upon controlling the diffusion of the target compound and subsequent high resolution gas chromatography/low resolution mass spectrometry (HRGC/LRMS) analysis, was proven comparable to other accepted methods for determining the vapor pressures of semi-volatile organic compounds (SVOCs). Vapor pressures for octachlorodibenzo-p-dioxin (OCDD) and octachlorodibenzofuran (OCDF) were in excellent agreement with those reported in literature. The application of the current method for the vapor pressure determinations of eight polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) in the extended temperature range (up to 275 °C) is reported. The extension of the vapor pressures to such temperatures, unprecedented for the PCDDs/Fs, is important for vapor-particle partitioning modeling in regions relevant to PCDD/F formation and control. Estimates for the melting temperatures and enthalpies of sublimation and vaporization are also reported, the latter for which no experimentally determined values have been found in the literature. The use of the method to deliver reproducible, trace concentrations (ppt-ppb) of targets was applied to the calibration of the jet-REMPI/TOFMS as an online detector for low chlorinated PCDDs/Fs.     

Corrosion-resistant lightweight metallic bipolar plates for PEM fuel cells

Corrosion resistant treated metal bipolar plates with higher rigidity and electrical conductivity than graphite were developed and tested for PEM fuel cell applications. Six replicas of single cells were used three of which were made of graphite composites bipolar plates and the other three of the treated metallic plates. A Membrane Electrode Assembly (MEA) with 5.55 cm² active electrode areas, 0.3 mg cm^–2 Pt loading and Nafion membrane 115 was fitted to each cell and operated under identical conditions. The experimental testing was conducted at room temperature (20 °C). The average value of the data obtained for the three graphite cells was plotted. Similarly, the average value of the data obtained for the three treated metal cells was plotted on the same graph for comparison. Generally, the treated metal bipolar plate provided at least 12% saving in hydrogen consumption in comparison to graphite. This is attributed to the lower bulk and surface contact resistance of the metal used in this study in relation to graphite. The results of lifetime testing, conducted at room temperature under variable loading showed no indication of power degradation due to metal corrosion for at least 1500 hours.     

A Measurement‐Based Approach for Designing Fixed‐Order Controllers for Unknown Closed‐Loop Architecture

This paper presents a new technique to design fixed‐structure controllers for linear unknown systems using a set of measurements. In model‐based approaches, the measured data are used to identify a model of the plant for which a suitable controller can be designed. Due to the fact that real processes cannot be described perfectly by mathematical models, designing controllers using such models to guarantee some desired closed‐loop performance is a challenging task. Hence, a possible alternative to model‐based methods is to directly utilize the measured data in the design process. We propose an approach to designing structured controllers using a set of closed‐loop frequency‐domain data. The principle of such an approach is based on computing the parameters of a fixed‐order controller for which the closed‐loop frequency response fits a desired frequency response that describes some desired performance indices. This problem is formulated as an error minimization problem, which can be solved to find suitable values of the controller parameters. The main feature of the proposed control methodology is that it can be applied to stable and unstable plants. Additionally, the design process depends on a pre‐selected controller structure, which allows for the selection of low‐order controllers. An application of the proposed method to a DC servomotor system is presented to experimentally validate and demonstrate its efficacy.     

Reference Range Estimation: Accounting for Measurement System Errors

Reference range is a statistic that is used in health related fields to represent the range of the most likely values for a variable of interest. Based on this range, individuals are classified as being healthy or unhealthy. In biostatistics, the reference range is calculated as the (1 ? α)% prediction interval, where this prediction interval is based on the estimated population variance from the data. Such estimation of population variance is not precise, because obtained test results do usually have errors associated with them. These errors are due to the imprecise test procedure or gauge used. In this paper, the total variability in the data is decomposed into two categories. The first is the patient‐to‐patient variability and the other is the variability due to the measurement system used. Estimation of the two kinds is performed through a gauge repeatability and reproducibility study, then the reference range is calculated, taking into account only the patient‐to‐patient variability. The revised reference range procedure is illustrated through a case study of vitamin B12 test results. A closed form formula is given to calculate the probability of a given test result being within the revised reference range. Copyright © 2015 John Wiley & Sons, Ltd.     

CNLs for the semantic web: a state of the art

One of the core challenges for building the semantic web is the creation of ontologies, a process known as ontology authoring. Controlled natural languages (CNLs) propose different frameworks for interfacing and creating ontologies in semantic web systems using restricted natural language. However, in order to engage non-expert users with no background in knowledge engineering, these language interfacing must be reliable, easy to understand and accepted by users. This paper includes the state-of-the-art for CNLs in terms of ontology authoring and the semantic web. In addition, it includes a detailed analysis of user evaluations with respect to each CNL and offers analytic conclusions with respect to the field.     

A recursive algorithm for generating the equations of motion of spatial mechanical systems with application to the five-point suspension

In this paper, a recursive formulation for generating the equations of motion of spatial mechanical systems is presented. The rigid bodies are replaced by a dynamically equivalent constrained system of particles which avoids introducing any rotational coordinates. For the open-chain system, the equations of motion are generated recursively along the serial chains using the concepts of linear and angular momenta. Closed-chain systems are transformed to open-chain systems by cutting suitable kinematic joints and introducing cut-joint constraints. The formulation is used to carry out the dynamic analysis of multi-link five-point suspension. The results of the simulation demonstrate the generality and simplicity of the proposed dynamic formulation.     

An efficient multi-predictor reversible data hiding algorithm based on performance evaluation of different prediction schemes

Multimedia Tools and Applications - With the broad development and evolution of digital data exchange, security has become an important issue in data storage and transmission since digital data can...     

Image watermarking based on inter-tree coefficients differencing in paired wavelet-packets tree constructions

Multimedia Tools and Applications - Recently, image watermarking has been used as a tremendous mean for copyright protection of images and multimedia as well. This work presents an image...