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1.
M. Ganschow C. Hellriegel E. Kneuper M. Wark C. Thiel G. Schulz‐Ekloff C. Bruchle D. Whrle 《Advanced functional materials》2004,14(3):269-276
Dye‐loaded AlPO4‐5 single crystals were prepared by microwave‐assisted hydrothermal synthesis from a batch, containing a mixture of three chromophores (Coumarin 40, Rhodamine BE50, and Oxazine 1) differing in their absorption range, molecular dimensions, and solubilities. Confocal fluorescence images reveal a spatial separation effect of the dye molecules, where the slimmer, more‐soluble dye molecule (Coumarin 40) is uniformly distributed in the body of the single crystal, and the bulky and/or less‐soluble ones (Rhodamine BE50, Oxazine 1) are situated in distinct domains. Visible spectra show good panchromatic absorption of visible light. Fluorescence lifetime measurements indicate the presence of an energy transfer cascade of the entirely fixed dye molecules from Coumarin 40 to Oxazine 1. The transfer mechanism is predominantly radiative. 相似文献
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Measuring knowledge transfer between fields of science 总被引:4,自引:2,他引:2
Rinia Ed J. van Leeuwen Thed N. Bruins Eppo E. W. van Vuren Hendrik G. van Raan Anthony F. J. 《Scientometrics》2002,54(3):347-362
In this paper we report on the results of an exploratory study of knowledge exchange between disciplines and subfields of
science, based on bibliometric methods. The goal of this analysis is twofold. Firstly, we consider knowledge exchange between
disciplines at a global level, by analysing cross-disciplinary citations in journal articles, based on the world publication
output in 1999. Among others a central position of the Basic Life Sciences within the Life Sciences and of Physics within
the Exact Sciences is shown. Limitations of analyses of interdisciplinary impact at the journal level are discussed. A second
topic is a discussion of measures which may be used to quantify the rate of knowledge transfer between fields and the importance
of work in a given field or for other disciplines. Two measures are applied, which appear to be proper indicators of impact
of research on other fields. These indicators of interdisciplinary impact may be applied at other institutional levels as
well.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
4.
J. C. Schulz 《International journal for numerical methods in engineering》1985,21(6):1039-1048
A new hourglassing control technique for quadrilateral and hexahedral elements used in dynamic finite element codes is presented. Based on expansion of the strees in a Taylor series and retention of additional terms beyond the usual constant stress term, this technique has the advantage that actual rather than artificial material properties are used. Simplifications that render this technique competitive with artificial viscosity and stiffness procedures in terms of additional storage and computation requirements are described. 相似文献
5.
RM Bionta G Blewitt CB Bratton D Casper A Ciocio R Claus M Crouch ST Dye S Errede GW Foster W Gajewski KS Ganezer M Goldhaber TJ Haines TW Jones D Kielczewska WR Kropp JG Learned JM LoSecco J Matthews HS Park LR Price F Reines J Schulz S Seidel E Shumard D Sinclair HW Sobel JL Stone L Sulak R Svoboda G Thornton van der Velde JC C Wuest 《Canadian Metallurgical Quarterly》1987,36(1):30-36
6.
Nascent high-molecular-weight (UHMW) polyethylene (PE) samples of different origins show a rather high crystallinity of about 70–75% and contain both a major portion of orthorhombic extended chain crystallites and a minor portion of triclinic crystallites. The triclinic content is greater the higher the molecular weight of the sample and the higher the activity of the used catalyser. A melting / recooling treatment results in a reduction of crystallinity by about 15–25% and disappearance of the triclinic phase. Further, an irreversible conversion of nascent orthorhombic extended chain crystallites to orthorhombic folded chain crystallites of increased lateral dimensions and crystalline perfections takes place during the melting / recooling treatment. The results are compared to those obtained for lower-molecular-weight PE samples and for high-strength / modulus PE fibers of different origins. 相似文献
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MC Dalsing DF Cikrit SG Lalka AP Sawchuk C Schulz 《Canadian Metallurgical Quarterly》1995,21(1):127-134
PURPOSE: This retrospective review of femorodistal vein grafts was analyzed to determine the usefulness of various graft surveillance criteria. METHOD: The surveillance schedule involved evaluations at 1 month, every 3 months the first year, and then every 6 months. Salvage intervention or graft occlusion occurring within the next follow-up interval defined surveillance end points. One hundred two grafts (329 surveillance visits) had an ankle/brachial index (ABI). A duplex scanning-determined midgraft peak systolic flow velocity (PSFV) was available for 81 grafts (262 visits). Forty-eight grafts (137 visits) had both a PSFV and entire graft duplex scanning (EGDS) to determine stenosis greater than 50%, whereas 40 grafts (91 visits) had simultaneous ABI and EGDS. RESULTS: When a greater than 15% decrease in ABI denoted an abnormal surveillance study result, a positive predictive value (PPV) of 24.3% and negative predictive value of 94.5% were noted. Similarly, a PSFV cutoff of less than 35 cm/sec demonstrated values of 26.3% and 94.2%, respectively. When an EGDS of greater than 50% stenosis or a PSFV of less than 35 cm/sec were the cutoff criteria, the PPV was 36.7% and negative predictive value 99.1%, whereas characterizing abnormal results further with ABI (> 15% decreases) increased the PPV to 83.3%. CONCLUSION: The combination of an EGDS, midgraft PSFV, and ABI provides optimal follow-up for our patients with a femorodistal vein graft. 相似文献
9.
10.
The syntheses of polyenynes as model compounds for poly(diacetylene)s (PDAs) are described. Variation of properties (UV–VIS, Raman, NMR and bond geometries) as a function of the chain length was investigated. After extrapolation to infinite chain length these data were compared to those for PDAs. From UV–VIS spectra a value of λ = 551 nm (2.25 eV) was calculated corresponding to the electronic transition of a single polyenyne chain. This energy is located at the low energy end of a yellow PDA solution spectrum. From Raman scattering v(C?C) = 2108–2128 cm?1 and v(C?C) = 1505–1532 cm?1 were calculated after extrapolation. Similarly sp-C13C NMR data yielded a shift of δ = 100 ppm. These data are almost identical to data known for yellow PDA solutions. Bond geometries are almost identical to those of poly(diacetylene)s and theoretical data. 相似文献