The polymerisation of 2-furyl vinyl ketone

Summary 2-Furyl vinyl ketone was polymerised using anionic, cationic and free-radical initiators. Yields and molecular weights varied with the type of activation. Whereas radical polymerisation gave a product possessing a regular vinylic structure, other kinds of units were detected in the polymers prepared with anionic and cationic catalysts.     

Discrete Time Sliding Mode Controller Using a Disturbance Compensator for Nonlinear Uncertain Systems

International Journal of Control, Automation and Systems - In this paper, we propose a new sliding mode control for discrete time nonlinear uncertain systems. The uncertainties include both...     

Numerical simulation of viscous fingering of shear‐thinning fluids

The viscous fingering instability of miscible shear‐thinning fluids has been examined using a pseudo‐spectral numerical technique based on the Hartley transform. The instability was studied for a flow in a rectilinear Hele‐Shaw cell, and the shear‐thinning character of the fluids has been modelied using the Carreau equation. New mechanisms of viscous fingering not previously observed in the case of similar Newtonian flow displacements have been identified. These mechanisms, which are reminiscent of the fractal patterns observed in experimental studies, were interpreted in terms of the velocity‐dependent mobility of the flow.     

First principles calculations of structural,electronic, optical and thermodynamic properties of PbS,SrS and their ternary alloys Pb1−xSrxS

Using first-principle method, we investigate the structural, electronic, optical and thermodynamic properties of the strontium semiconductors Pb_1?xSr_xS with 25%, 50% and 75% of Sr. The calculations are performed by using the full-potential linearized augmented plane wave (FP-LAPW) method. As exchange–correlation potential we used the generalized gradient approximation (GGA) of Perdew et al. The variation of the calculated equilibrium lattice constant versus concentration shows that a small deviation from Vegard’s law is clearly visible with downward bowing parameter equal to 0.009 Å. The bulk modulus as a function of x for Pb_1?xSr_xS alloy shows a significant deviation from the linear concentration dependence (LCD) with downward bowing equal to 6.62 GPa. The different roles of structural and chemical effects on the gap bowing and its variation with composition are identified and discussed. In addition, density of states and optical properties were calculated and compared to the available experimental data and previous theoretical works. On the other hand, the thermodynamic stability of these alloys was investigated by calculating the excess enthalpy of mixing ΔH_m as well as the phase diagram.     

Rheology of fiber filled polymer melts: Role of fiber‐fiber interactions and polymer‐fiber coupling

An experimental study and a numerical modeling analysis are carried out to examine the effects of fiber‐fiber interactions and coupling between fiber orientation and polymer chains conformation on the rheological properties of fiber suspensions. The experimental study allowed examination of large fiber volume fractions up to 35% over a range of shear rates that spans eight decades. This study confirmed already known results and led to new ones. In particular, a peak in the steady shear viscosity at the low shear rate region is observed at large volume fractions. Furthermore, new results regarding the applicability of the Cox‐Merz rule, the behavior of the damping factor, and the end pressure drops are reported, and physical interpretations are proposed. The results of the numerical modeling showed that it is necessary to account for the polymer‐fiber coupling factor to obtain a good fit between the model predictions and the experimental measurements. Comparisons between the model predictions and the experimental measurements allowed study of the variation of the parameters that govern the fiber‐fiber interactions and the polymer‐fiber coupling with the properties of the suspension and the flow. POLYM. ENG. SCI., 45:385–399, 2005. © 2005 Society of Plastics Engineers     

Coalitional game‐based behavior analysis for spectrum access in cognitive radios

The core of cognitive radio paradigm is to introduce cognitive devices able to opportunistically access the licensed radio bands. The coexistence of licensed and unlicensed users prescribes an effective spectrum hole‐detection and a non‐interfering sharing of those frequencies. Collaborative resource allocation and spectrum information exchange are required but often costly in terms of energy and delay. In this paper, each secondary user (SU) can achieve spectrum sensing and data transmission through a coalitional game‐based mechanism. SUs are called upon to report their sensing results to the elected coalition head, which properly decides on the channel state and the transmitter in each time slot according to a proposed algorithm. The goal of this paper is to provide a more holistic view on the spectrum and enhance the cognitive system performance through SUs behavior analysis. We formulate the problem as a coalitional game in partition form with non‐transferable utility, and we investigate on the impact of both coalition formation and the combining reports costs. We discuss the Nash Equilibrium solution for our coalitional game and propose a distributed strategic learning algorithm to illustrate a concrete case of coalition formation and the SUs competitive and cooperative behaviors inter‐coalitions and intra‐coalitions. We show through simulations that cognitive network performances, the energy consumption and transmission delay, improve evidently with the proposed scheme. Copyright © 2016 John Wiley & Sons, Ltd.     

Energy and economic assessment of soda and organosolv biorefinery processes

Lignocellulosic biomass, particularly agricultural and forestry residues, is becoming a potential renewable energy and products source. Lignocellulosic biomass processing technologies include a primary separation of its main constituents, cellulose, hemicelluloses and lignin, as well as further treatment and processing to obtain different platform chemicals to design consistently structured compounds as chemical building blocks. The economic competitiveness of the obtained products is highly dependent on the separation and purification technologies used and the process energetic efficiency. For this proposal, process simulation tools are very useful to design a competitive and effective biorefinery scheme. In the present work, the energetic and economical efficiencies of two biorefinery processes, soda and organosolv-ethanol systems, were analyzed using the simulation software Aspen Plus^®. The process design consisted of several units (reaction, solid fraction washing, products recovery and liquid fraction processing). Mass and energy balances were established and both systems were compared in terms of yield, solvents/reactants recovery and energy consumption. Aspen HX-Net software was used to analyze the process heat exchange network in order to improve energy consumptions. The development of rigorous simulations allowed to determine the economical feasibility of both biorefinery schemes, and to establish the most appropriate operation conditions for both processes.     

Two‐sided matching framework for optimal user association in 5G multi‐RAT UDNs

Recently, academic and industrial research communities are paying more explicit attention to the 5G multiple radio access technology ultra‐dense networks (5G multi‐RAT UDNs) for boosting network capacity, especially in UD urban zones. To this aim, in this paper, we intend to tackle the user association problem in 5G multi‐RAT UDNs. By considering the decoupled uplink/downlink access (DUDA), we divide our user association problem into two distinct subproblems representing, respectively, the uplink and the downlink channels. Next, we formulated each one as a nonlinear optimization problem with binary variables. Then, to solve them, we were restricted by the hard complexity, as well as the hard feasibility of centralized user association schemes. Thus, to resolve our user association problem in a reasonable time and distributed manner, we formulated each subproblem as a many‐to‐one matching game based on matching theory. Next, we provide two fully distributed association algorithms to compute the uplink and downlink stable matching among user equipments (UEs) and base stations (BSs). Simulation results corroborate our theoretical model and show the effectiveness and improvement of our achieved results in terms of the overall network performance, quality of service (QoS), and energy efficiency (EE) of UEs.     

The KNNs Safe Region Pruning Based Method: An Efficient Approach for Continuously Determining the k Nearest Ambulances in Emergency

Wireless Personal Communications - A lot of research has been done on the problem of finding the k nearest neighbor to a query point. Existing studies are usually intended to work on static data....     

Physical investigations on Ni doping ZnO thin films along with ethanol response

Journal of Materials Science: Materials in Electronics - Undoped and Ni-doped ZnO thin films were grown on glass substrates at 460 °C using the spray pyrolysis method. All samples...