Structural evolution of poly(lactic acid)/poly(ethylene oxide)/unmodified clay upon ambient ageing

Poly(lactic acid) (PLA) and poly(ethylene oxide) (PEO)/unmodified clay masterbatches are compounded together in order to investigate the ambient ageing of the resulting PLA/PEO/clay ternary blends. Binary blends are miscible up to 20 wt PEO% and in ternary counterparts, clay is intercalated at a nanometric scale, similarly to the clay dispersion state in masterbatches. PEO/clay interactions are strong, as confirmed by the lower plasticization of ternary blends. Furthermore, structural modifications occurring over time are evidenced for all blends through the observation of changes in thermal responses. Over the 220‐day observation period, lower plasticized samples undergo physical ageing only whereas blends close to the miscibility limit know a rapid PLA/PEO phase separation without physical ageing. For blends with intermediate PEO concentrations, both phenomena are observed with slower PLA chain mobility transition. Remarkably clay appears to affect both phenomena, ternary blends having limited physical ageing and slower PLA/PEO segregation. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40426.     

Modelling mechanical properties of spruce and Douglas fir timber by means of X-ray and grain angle measurements for strength grading purpose

This study proposes a model using data from a scanner (X-ray and grain angle measurements) to perform strength grading. The research also includes global measurements of modulus of elasticity (obtained by vibrations and ultrasound methods), static bending stiffness and bending strength of 805 boards of Douglas fir and 437 boards of spruce. This model can be used in an industrial context since it requires low computational time. The results of this study show that the developed model gives better results than the global non-destructive measurements of the elastic modulus commonly used in the industry. It also shows that this improvement is particularly higher in the case of Douglas fir than for spruce. The comparison has been made on both the quality of the mechanical properties assessment and on the improvement of the grading process according to the European standards by using different index.     

Embedded holonic fault diagnosis of complex transportation systems

The use of electronic equipment and embedded computing technologies in modern complex transportation systems continues to grow in a highly competitive market, in which product maintainability and availability is vital. These technological advances also make fault diagnosis and maintenance interventions much more challenging, since these operations require a deep understanding of the entire system. This paper proposes a holonic cooperative fault diagnosis approach, along with a generic architecture, to increase the embedded diagnosis capabilities of complex transportation systems. This concept is applied to the fault diagnosis of door systems of a railway transportation system.     

Experimental and modeling study of lean premixed atmospheric-pressure propane/O2/N2 flames

A better knowledge of the combustion chemistry in very lean flames is required to improve flame stability and control the presence of oxygenated species as final products. In this work, the chemical structure of lean premixed propane-oxygen-nitrogen flames stabilized on a flat flame burner at atmospheric pressure was determined experimentally. The species mole fraction profiles were also computed by the Premix code (Chemkin II version) and three recently proposed mechanisms. Globally, the agreement between measured and computed mole fractions profiles is similar, despite large differences in the number of reactions in each mechanism. Pathways analyses show that only weak variations are observed in the relative importance of the main oxidation routes when the equivalence ratio is decreased from 0.9 to 0.5.     

Modeling of the oxidation of methyl esters—Validation for methyl hexanoate, methyl heptanoate, and methyl decanoate in a jet-stirred reactor

The modeling of the oxidation of methyl esters was investigated and the specific chemistry, which is due to the presence of the ester group in this class of molecules, is described. New reactions and rate parameters were defined and included in the software EXGAS for the automatic generation of kinetic mechanisms. Models generated with EXGAS were successfully validated against data from the literature (oxidation of methyl hexanoate and methyl heptanoate in a jet-stirred reactor) and a new set of experimental results for methyl decanoate. The oxidation of this last species was investigated in a jet-stirred reactor at temperatures from 500 to 1100 K, including the negative temperature coefficient region, under stoichiometric conditions, at a pressure of 1.06 bar and for a residence time of 1.5 s: more than 30 reaction products, including olefins, unsaturated esters, and cyclic ethers, were quantified and successfully simulated. Flow rate analysis showed that reactions pathways for the oxidation of methyl esters in the low-temperature range are similar to that of alkanes.     

Squeeze film effect for the design of an ultrasonic tactile plate

Most tactile displays currently built rely on pin-based arrays. However, this kind of tactile device is not always appropriate when we need to give the illusion of finely textured surfaces. In this paper, we describe the squeeze film effect between a plate and a finger, and we use this effect to design an ultrasonic tactile plate. The plate is actuated by piezoelectric ceramics. Ultrasonic vibrations are thus produced and are capable of generating the squeeze film effect. This enables us to simulate variable friction on the surface of the plate. In order to identify the squeeze film phenomenon, this study considers the case where a finger, with a planar bottom surface and with epidermal ridges, is placed on a rapidly vibrating plate. The overpressure is calculated and the result enables us to assess the relative coefficient of friction as a function of the vibration amplitude of the plate. Based on this principle, and using both analytic and FE method studies, and given ergonomic and stimulation (squeeze film) requirements, we show that it is possible to design a tactile plate which is capable of giving programmable tactile sensations. We conclude by comparing the results obtained from our simulations with experimental results.     

Conserved sequence preference in DNA binding among recombination proteins: an effect of ssDNA secondary structure

Repetitive sequences have been proposed to be recombinogenic elements in eukaryotic chromosomes. We tested whether dinucleotide repeats sequences are preferential sites for recombination because of their high affinity for recombination enzymes. We compared the kinetics of the binding of the scRad51, hsRad51 and ecRecA proteins to oligonucleotides with repeats of dinucleotides GT, CA, CT, GA, GC or AT. Since secondary structures in single-stranded DNA (ssDNA) act as a barrier to complete binding we measured whether these oligonucleotides are able to form stable secondary structures. We show that the preferential binding of recombination proteins is conserved among the three proteins and is influenced mainly by secondary structures in ssDNA.     

Lathe check development and properties: effect of log soaking temperature,compression rate,cutting radius and cutting speed during peeling process of European beech (<Emphasis Type="Italic">Fagus sylvatica</Emphasis> L.) veneer

The depth of lathe checks and integrity of veneer have been shown to be critical factors affecting the bonding process but also affecting the mechanical properties of veneer-based products. This study shows how beech (Fagus sylvatica L.) veneer lathe checks interval and depths are affected by soaking temperature, compression rate, cutting radius and cutting speed during the peeling process in well-controlled conditions. Freshly felled European beech logs were soaked in a water tank at 50, 60, 70 or 80 °C. Following soaking, the logs were immediately peeled with laboratory scale lathe (SEM S500) to 3.5 mm thick veneer at a cutting speed of 1, 2 or 3 m s^?1 and pressure rates of 0, 5, 10 or 15%. The correlation between lathe check depth and frequency was validated using “Système de Mesure d’Ouverture des Fissures” (SMOF) device, which enables to measure check properties reliably on veneer ribbons. In a well-controlled peeling process, the strong correlation between check depth and interval was shown. At higher temperature, shallower and more frequent checks are created compared to lower temperature. However, the effect of soaking temperature (between 50 and 80 °C) on veneer checking is much smaller than the effect of compression rate during peeling process, where the higher compression rate produced veneer with shallower and more frequent checks. The results of the study also show that the direction of lathe check propagation could be affected by the rays in beech veneer. Rays resist crack growth in tangential direction, but act as weak planes in radial direction.