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1.
A high-performance liquid chromatographic (HPLC) separation of diacylglycerol acetates to quantitatite disaturated species
of lung phosphatidylcholine (PC) was studied. The diacylglycerol acetates were applied on a reversed phase column, eluted
by an isocratic solvent, acetonitrile/isopropanol/water (35:15:1, v/v/v) at a flow rate of 1 ml/min, and detected by differential
refractometry (RI). This isocratic HPLC method was useful to separate disaturated species from the others of lung PC.
The quantitative analysis of the molecular species separated by HPLC was studied by RI detection. Chroamtograms obtained by
RI detection and radioactivity determination of diacylglycerol [3H]acetates prepared by [3H]acetic anhydride were almost identical. The RI detector responsed in the same degree for different, authentic standards
of diacylglycerol acetates. The detection limit with RI detection was about 30 nmoles. Molecular species of PCs from human
lung and carcinoma tissues were analyzed by this HPLC method. The contents of disaturated species were very similar to those
reported previously. These results indicate that RI detection is very useful in the nmole range for the quantitative analysis
among the molecular species containing disaturated species. 相似文献
2.
Masahiro Tatsumisago Tsutomu Minami Masami Tanaka 《Journal of the American Ceramic Society》1981,64(7):97-C-
A new technique combining a thermal-image furnace and a twin roller is described for quenching the melt to form glass. The technique was applied to the simple system Li2 O-SiO2 , since its fundamental parameters in the estimation of critical cooling rate are available. Glass flakes were obtained in the composition Li4 SiO4 , for which a very large critical cooling rate (∼109 K·s−1 ) was needed for glass formation. 相似文献
3.
Koichi Hasegawa Hideki Nishimori Masahiro Tatsumisago Tsutomu Minami 《Journal of Materials Science》1998,33(4):1095-1098
Thick silica films were prepared by the electrophoretic sol–gel deposition technique in the presence of poly(acrylic acid) (PAA) using monodispersed silica particles; the particles were prepared by the sol–gel method, pre-heat treated and then re-dispersed in the mixture of H2O and ethanol. The weight of deposited silica films was maximized when 0.2 mass % of PAA against the whole amount of sol was added. The particles constructing the thick silica films were packed densely when the amount of added PAA was less than 0.2 mass%. The weight of the film increased with decrease in the content of H2O in the sol when a fixed amount of PAA was added. After the heat treatment of deposited films at 800 °C, crack-free silica films of about 30 m thickness were prepared. © 1998 Chapman & Hall 相似文献
4.
N. Umesaki M. Takahashi M. Tatsumisago T. Minami 《Journal of Materials Science》1993,28(13):3473-3481
Raman spectra of glasses in the Li2O-SiO2 system (41.3 Li2O 61.3 mol%), prepared by rapid quenching, were measured. The proportions of SiO4 units with 1–4 non-bridging oxygens per silicon (NBO/Si) and the fractions of bridging oxygen, non-bridging oxygen and free or full-active oxygen were determined for these glasses from quantitative analysis of the Raman spectra obtained. X-ray structural analysis of Li2O-SiO2 showed an increasing elongation of the average atomic distance of the Si-O pair with increase in Li2O content due to weakening of the Si-O bond. 相似文献
5.
Atsunori Matsuda Yugo Higashi Kiyoharu Tadanaga Masahiro Tatsumisago 《Journal of Materials Science》2006,41(24):8101-8108
SiO2–TiO2 spherical microparticles of about 0.7 μm in diameter were prepared by the sol–gel method. Anatase nanocrystals were formed in the microparticles and their specific surface area was increased after a hot-water treatment at 90 °C. From the changes in the concentration of I2 photocatalytically generated from KI aqueous solution, the activity of the SiO2–TiO2 microparticles was found to increase with increasing the hot-water treatment time. Particulate, thick films were electrophoretically deposited on indium tin oxide (ITO)-coated glass substrates using the anatase nanocrystal-precipitated SiO2–TiO2 microparticles. The thickness of the electrophoretically deposited particulate film increased to be approximately 10 μm with an increase in applied voltage. The resultant thick film showed a high photocatalytic activity. 相似文献
6.
René Marcelino Abritta Teixeira Toshihiko Yamasaki Kiyoharu Aizawa 《Multimedia Tools and Applications》2012,61(1):21-49
Affective analysis of video content has greatly increased the possibilities of the way we perceive and deal with media. Different kinds of strategies have been tried, but results are still opened to improvements. Most of the problems come from the lack of standardized test set and real affective models. In order to cope with these issues, in this paper we describe the results of our work on the determination of affective models for evaluation of video clips using audiovisual low-level features. The affective models were developed following two classes of psychological theories of affect: categorial and dimensional. The affective models were created from real data, acquired through a series of user experiments. They reflect the affective state of a viewer after watching a certain scene from a movie. We evaluate the detection of Pleasure, Arousal and Dominance coefficients as well as the detection rate of six affective categories. For this end, two Bayesian network topologies are used, a Hidden Markov Model and an Autoregressive Hidden Markov Model. The measurements were done using audio-only models, video-only models and fused models. Fusion is done using two different methods, a Decision Level Fusion and Feature Level Fusion. All tests were conducted using localized affective models, both categorial and dimensional. Results are presented in terms of detection rate and accuracy for affective families, affective dimensions and probabilistic networks. Arousal was the best detected dimension, followed by dominance and pleasure. 相似文献
7.
Hiro-aki Nishimoto Kiyoharu Nakagawa Na-oki Ikenaga Toshimitsu Suzuki 《Catalysis Letters》2002,82(3-4):161-167
Ru-loaded Y2O3 catalyst was investigated for the partial oxidation of methane to synthesis gas. Ru(0.5 wt%)/Y2O3 catalyst afforded a high CH4 conversion of 27% at a CH4:O2 ratio of 5 to give nearly a 1:2 ratio of CO and H2 with a selectivity of 75% at 873 K. Ru(0.5 wt%)/Y2O3 catalyst maintained high catalytic activity over 10 h in the partial oxidation of methane. Carbon deposition of the catalyst surface in the reaction of CH4 was examined by thermogravimetric analyses, and it was found that no carbon deposition occurred on the Ru(0.5 wt%)/Y2O3 catalyst. The synthesis-gas production proceeded basically via a two-step reaction consisting of methane combustion to give H2O and CO2, followed by the reforming of methane from CO2 and steam. 相似文献
8.
Liquid‐phase sintering of highly Na+ ion conducting Na3Zr2Si2PO12 ceramics using Na3BO3 additive 下载免费PDF全文
Kousuke Noi Kenji Suzuki Naoto Tanibata Akitoshi Hayashi Masahiro Tatsumisago 《Journal of the American Ceramic Society》2018,101(3):1255-1265
Na3Zr2Si2PO12 (NASICON) is a promising material as a solid electrolyte for all‐solid‐state sodium batteries. Nevertheless, one challenge for the application of NASICON in batteries is their high sintering temperature above 1200°C, which can lead to volatilization of light elements and undesirable side reactions with electrode materials at such high temperatures. In this study, liquid‐phase sintering of NASICON with a Na3BO3 (NBO) additive was performed for the first time to lower the NASICON sintering temperature. A dense NASICON‐based ceramic was successfully obtained by sintering at 900°C with 4.8 wt% NBO. This liquid‐phase sintered NASICON ceramic exhibited high total conductivity of ~1 × 10?3 S cm?1 at room temperature and low conduction activation energy of 28 kJ mol?1. Since the room‐temperature conductivity is identical to that of conventional high‐temperature‐sintered NASICON, NBO was demonstrated as a good liquid‐phase sintering additive for NASICON solid electrolyte. In the NASICON with 4.8 wt% NBO ceramic, most of the NASICON grains directly bonded with each other and some submicron sodium borates segregated in particulate form without full penetration to NASICON grain boundaries. This characteristic composite microstructure contributed to the high conductivity of the liquid‐phase sintered NASICON. 相似文献
9.
Kiyoharu Nakagawa Hirokazu Oda Akira Yamashita Masahiro Okamoto Yoichi Sato Hidenori Gamo Mikka Nishitani-Gamo Kazuyuki Ogawa Toshihiro Ando 《Journal of Materials Science》2009,44(1):221-226
We developed a novel spherical carbon material. The spherical carbon is composed of a high density of carbon nanotubes or
nanofilaments, and includes an oxidized diamond particle as a core. Syntheses of this carbon in high volume with high selectivity
may be possible. It is expected that this carbon will be useful as a catalyst material for fuel cells, electric double-layer
capacitors, etc. 相似文献
10.
Masahiro Tatsumisago Akitoshi Hayashi 《International Journal of Applied Glass Science》2014,5(3):226-235
Sulfide glass-ceramic electrolytes with Li+ or Na+ ion conduction have been developed in last decade. High-temperature phases of Li7P3S11 and cubic Na3PS4 are precipitated from mother glasses, and the obtained glass-ceramics show higher conductivity than the mother glasses. It is difficult to synthesize those high-temperature phases by conventional solid-state reaction, and glass electrolytes are thus important as a precursor for forming high-temperature phases. The highest conductivities at 25°C of 1.1 × 10−2 S/cm for Li+ ion conductor (Li7P3S11) and 7.4 × 10−4 S/cm for Na+ ion conductor (Na3.06P0.94Si0.06S4) are achieved in sulfide glass-ceramic electrolytes. All-solid-state batteries with sulfide glass-ceramic electrolytes were fabricated by cold press at room temperature. Sulfide electrolytes have favorable mechanical properties to form favorable solid–solid contacts in solid-state batteries by pressing without heat treatment. All-solid-state Li-In/S and Na-Sn/TiS2 cells using sulfide glass-ceramic electrolytes operate as secondary batteries and exhibit good cycle performance at room temperature. 相似文献