Mathematical modelling and numerical simulation of ordered porosity metal materials formation

Ordered porosity metal materials belong to a relatively new class of porous materials named gasars. This paper presents a mathematical model of the complex physical phenomena in the production of gasars. Analyses for heat transfer, solidification kinetics and gas diffusion were coupled to describe the formation of unique gasar structure. Several criterial functions were introduced to provide significant quantitative information about the relationship between the operating technological parameters and the final structure. The computational outcomes of the numerical simulation were compared with the characteristics of real gasar ingots. The model was applied to determine the boundary conditions that would provide approximately constant physical conditions on the solidification front. The structure sensitiveness of gasars with respect to the different technological parameters is discussed.     

Particle distribution control in cast aluminium alloy-mica composites

A suspension of mica particles (40m diameter and 3.7 thick) obtained in a mechanically stirred Al-4 wt % Cu-1.5 wt % Mg melt was poured and solidified in a variety of moulds under different heat flow configurations. The resulting cast structure showed a non-uniform distribution of dispersed mica particles with mica-depleted and segregated zones due to their flotation before and during solidification. The experimentally observed profiles of mica-free regions deviate significantly from those computed on the basis of Stokes's law and freezing-time computations. In relatively thick castings, segregation of mica could be minimized by using low pouring temperatures and/or side as well as bottom chilling. It was found, however, that thin castings (12.5 mm) could easily be produced with a homogeneous distribution of mica particles.     

Novel Ultrahigh-Energy Materials

This paper reviews the recent work carried out in the field of modern high-energy materials (HEMs) with the emphasis on homoleptic polynitrogen compounds. A large volume of quantum-chemical investigations have predicted the possibility of existence of polynitrogen compounds not only as short-lived transient species but also in the form of isolable discrete molecules. Despite the theoretical speculations, only a few polynitrogen ions are known today in addition to well-entrenched N _1– ³ discovered almost 100 year ago. Extraordinary potential of these green molecules to deliver high amounts of energy in comparison with todays and tomorrows most powerful HEMs, namely, hexanitrohexaazaisowurtzitane (CL-20) and octanitrocubane (ONC), has fuelled the imagination of propellant and explosive engineers and technologists. Research activities are in progress in many quantum-chemical schools to explore the possibility of other promising polynitrogen compounds. After the recent discovery of key synthons/building blocks Mg(N₅)₂, N ₁₊ ⁵ SbF _1– ⁶ , N ₁₊ ⁵ SbF₁₁, N ₁₊ ⁵ , N ₁₊ ⁵ SnF₆, and N ₁₊ ⁵ Sn(CF₃)₄, the wealth of polynitrogen compounds is just waiting to be harvested by the HEMs community. There are ambitious plans all over the globe to realize N₆₀, which only prove a eco-friendly dense powerhouse of energy.__________Translated from Fizika Goreniya i Vzryva, Vol. 41, No. 3, pp. 29–45, May–June, 2005.     

Viscous Potential Flow Analysis of Kelvin–Helmholtz Instability of a Cylindrical Flow with Heat and Mass Transfer

A linear analysis of Kelvin–Helmholtz instability of a cylindrical interface has been carried out when there is heat and mass transfer across the interface, using viscous potential flow theory. Both fluids are considered as incompressible, viscous, and thermally conducting with different kinematic viscosities. Both axisymmetric as well as asymmetric disturbances are considered. Stability criterion is given by a critical value of relative velocity and stability is discussed theoretically as well as numerically. Various graphs with respect to physical parameters such as wave number, viscosity ratio, heat transfer coefficients, Reynolds number, etc., have been drawn and the effect of various parameters have been described. A comparison with the linear stability analysis of inviscid fluids (Lee [10]) has been made and it is observed that viscosity has a stabilizing effect on the stability of the system. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res, 43(6): 489–503, 2014; Published online 3 October 2013 in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21092     

Experimental investigation of tool wear and machining rate in rotary ultrasonic machining of nickel alloy

Nickel alloys possess the excellent potential at high temperature and resistance to oxidation/corrosion owing to its high nickel content. These materials necessitate non-traditional machining methods. The rotary ultrasonic machining (RUM) process comes into existence as a superior alternative to the conventional machining of nickel alloys. The processing of these alloys using RUM needs attention. This article details the multi-response optimization in RUM of nickel alloy using the desirability concept. The present work is carried out with two shapes of the tool: (i) Plain tool and (ii) lateral slotted tool. During RUM, the process parameters—power rating tool rotation, abrasive diamond grit size and feed rate are varied. Compared with the plain tool, the lateral slotted tool shows the more efficient machining rate (MR) with less tool wear (TW). The micro-graphs disclose the mechanism of MR and TW during RUM.     

Effect of CoFe2O4 mole percentage on multiferroic and magnetoelectric properties of Na0.5Bi0.5TiO3/CoFe2O4 particulate composites

Na_0.5Bi_0.5TiO₃ (NBT), CoFe₂O₄ (CFO) as well as particulate composites containing different mole percentages of NBT and CFO were synthesized by the solid-state sintering route and characterized for their ferroelectric and ferrimagnetic hysteresis loops, magnetostriction and magnetoelectric (ME) output. The mole% of CFO was found to influence the ferroelectric and ferrimagnetic hysteresis loops as well as magnetostriction and piezomagnetic coefficients which in turn had a significant effect on the magnetoelectric voltage coefficient. The highest magnetoelectric voltage coefficient (α) of 0.5 mV/cm/Oe was recorded in (65) NBT–(35) CFO composite.     

Reinforced cast metals: Part II Evolution of the interface

Interface evolution in metal-matrix composites is a thermodynamic necessity and interface design a kinetics challenge. The synergistic interaction between processing science and surface engineering has led to considerable progress in understanding, modelling and tailoring the fibre–matrix interface at the microstructural, crystallographic and atomic levels. The chemical, morphological, crystallographic and thermoelastic compatibilities between the fibre and the matrix influence the interfacial adhesion strength. This article examines the role of material properties and fabrication conditions in chemical interactions between the fibre and the matrix in metal-matrix composites synthesized using the solidification and casting techniques. © 1998 Chapman & Hall     

Synthesis, characterization, thermolysis and performance evaluation of mercuric-5-nitrotetrazole (MNT)

Mercuric-5-nitrotetrazole (MNT) was synthesized on using a reported method. The product having bulk density of 1.5 g/cm3, was obtained during this work using mercuric nitrate doped with additives such as cephol/dextrin in the process. Synthesized MNT was characterized by metal content analysis, IR and ESCA. The DTA profile indicated the thermal stability of MNT up to 200 degrees C. It revealed its higher thermally sensitive [thermal sensitive figure (S) approximately 0.8] in comparison to that of service lead azide (SLA) [S approximately 0.4]. Percussion sensitivity data also showed higher sensitivity of MNT. However, it was found less friction sensitive than SLA. The chemical stability of MNT in a carbon dioxide environment was evaluated in comparison to SLA by determining mercury (gravimetrically) and lead azide (volumetrically) contents respectively. Results obtained indicated that no discernable changes occurred in MNT, even after storage for 90 days while in case of SLA, drastic change in lead azide content was observed. IR spectra of MNT sample stored in a closed aluminum dish for 5-10 years could be superimposed on that of the freshly prepared MNT sample. The performance of MNT filled detonator no. 27 assessed in terms of extent of damage on a witness plate was found equivalent to that of the standard ASA (azide, styphynate and aluminium) composition filled detonator.     

Viscous potential flow analysis of electrohydrodynamic Kelvin–Helmholtz instability with heat and mass transfer

Viscous potential flow analysis of Kelvin–Helmholtz instability with heat and mass transfer in presence of a horizontal electric field has been carried out. Stability criterion is given by a critical value of relative velocity of two fluids as well as critical value of the applied electric field. Various graphs with respect to physical parameters, such as wave-number, viscosity ratio, ratio of dielectric constants of two fluids, heat transfer coefficients have been drawn and effect of various parameters have been described.