Effect of Annealing on the Surface Microstructure of Y-Ba-Cu-O Superconducting Ceramics

Precusors to the YBa₂Cu₃O_7-δ material were prepared by both the oxalate precipitation method and conventional ceramic processing. Second-phase grains were observed to develop on the exposed fracture surface during annealing at 500° to 600°C in an ambient atmosphere. The second-phase grains were identified to be BaCO₃ using EDX and XRD. The liquid phase, which was formed because of local chemical inhomogeneity in the Y-Ba-Cu-O system, contributed to the formation of second-phase grains as a source of Ba.     

The study of forming gas plasma on HSG-7000 silsesquioxane-based low-k dielectric film using X-ray photoelectron spectroscopy

HSG-7000 is a spin-on glass (SOG) low k dielectric material, manufactured by Hitachi Chemical and is silesquioxane (SSQ) based. The dielectric constant (k) of HSG-7000 is claimed to be 2.2. Cu diffusion through nanoporous structure of SSQ based material in Cu/Low k interconnects has been reported as a concern. Approaches to minimize Cu diffusion involve the implementation of a barrier layer between Cu and the low k dielectric material, or surface densification via plasma treatment. This paper discusses the effects of forming gas (93% N₂ + 7% H₂) plasma in an attempt to reduce Cu diffusion through the HSG-7000 film without significant increase in the dielectric constant (k). The FTIR and XPS results suggest a formation of C–N bonds due to the plasma treatment. The depth profile measurement of Cu using XPS confirms the reduction of Cu diffusion through the film with plasma treatment. Results show that plasma treatment of 30–40 s on HSG-7000 will provide a reasonable Cu diffusion resistance while ensuring the increase in k is below 2.4.     

Dominant Mechanisms that Shape the Airborne Particle Size and Composition Distribution in Central California

The size and composition of ambient airborne particulate matter is reported for winter conditions at five locations in (or near) the San Joaquin Valley in central California. Two distinct types of airborne particles were identified based on diurnal patterns and size distribution similarity: hygroscopic sulfate/ammonium/nitrate particles and less hygroscopic particles composed of mostly organic carbon with smaller amounts of elemental carbon. Daytime PM₁₀ concentrations for sulfate/ammonium/nitrate particles were measured to be 10.1 μ g m^?3, 28.3 μ g m^?3, and 52.8 μ g m^?3 at Sacramento, Modesto and Bakersfield, California, respectively. Nighttime concentrations were 10–30% lower, suggesting that these particles are dominated by secondary production. Simulation of the data with a box model suggests that these particles were formed by the condensation of ammonia and nitric acid onto background or primary sulfate particles. These hygroscopic particles had a mass distribution peak in the accumulation mode (0.56–1.0 μ m) at all times. Daytime PM₁₀ carbon particle concentrations were measured to be 9.5 μ g m^?3, 15.1 μ g m^?3, and 16.2 μ g m^?3 at Sacramento, Modesto, and Bakersfield, respectively. Corresponding nighttime concentrations were 200–300% higher, suggesting that these particles are dominated by primary emissions. The peak in the carbon particle mass distribution varied between 0.2–1.0 μ m. Carbon particles emitted directly from combustion sources typically have a mass distribution peak diameter between 0.1–0.32 μ m. Box model calculations suggest that the formation of secondary organic aerosol is negligible under cool winter conditions, and that the observed shift in the carbon particle mass distribution results from coagulation in the heavily polluted concentrations experienced during the current study. The analysis suggests that carbon particles and sulfate/ammonium/nitrate particles exist separately in the atmosphere of the San Joaquin Valley until coagulation mixes them in the accumulation mode.     

Wedge splitting experiments on three-layered particleboard and consequences for cutting

Three layered particleboard is a widely used and important plate material used for construction and furniture production. This implies that material parameters such as strength and elasticity in bending are determined. However, usually little or nothing is known about the fracture properties. This paper has the goal to investigate the material fracture properties in the three layers and discuss the linear and non-linear fracture mechanical properties with regard to board production and its consequences for cutting. It could be shown that the fracture properties of the solid boards are dominated by the bigger chips in the core of the plate and the fracture properties of boards are best characterized by the specific fracture energy. The linear elastic- and the non-linear elastic fracture mechanics approach of the outer layers shows essentially similar results, represented by brittle fracture. For the prediction of the cutting performance, linear elastic fracture mechanics parameters are considered to be more appropriate because these parameters describe the limit of linear elastic behaviour and therefore the case of smallest deformation zone. High stress concentration at the tool tip and low permanent deformation in the bulk material give the best cutting quality.     

Long-term effect of continuous cropping of irrigated rice on soil and yield trends in the Sahel of West Africa

The effects of 18 years continuous cropping of irrigated rice on soil and yields were studied in two long-term fertility experiments (LTFE) at Ndiaye and Fanaye in the Senegal River Valley (West Africa). Rice was planted twice in a year during the hot dry season (HDS) and wet season (WS) with different fertilizer treatments. Soil organic carbon (SOC) under fallow varied from 7.1 g kg⁻¹ at Fanaye to 11.0 g kg⁻¹ at Ndiaye. Rice cropping maintained and increased SOC at Ndiaye and Fanaye, respectively and fertilizer treatments did not affect SOC. Soil available P and exchangeable K were maintained or increased with long-term application of NPK fertilizers. Without any fertilizer, yields decreased by 60 kg ha⁻¹ (1.5%) and 115 kg ha⁻¹ (3%) per year at Fanaye and Ndiaye, respectively. The highest annual yield decreases of 268 kg ha⁻¹ (3.6%) and 277 kg ha⁻¹ (4.1%) were observed at Fanaye and Ndiaye, respectively when only N fertilizer was applied. Rice yields were only maintained with NPK fertilizers supplying at least 60 kg N, 26 kg P and 50 kg K ha⁻¹. It was concluded that the double cropping of irrigated rice does not decrease SOC and the application of the recommended doses of NPK fertilizer maintained rice yields for 18 years.     

Molecular Subtyping of Invasive Breast Cancer Using a PAM50-Based Multigene Expression Test-Comparison with Molecular-Like Subtyping by Tumor Grade/Immunohistochemistry and Influence on Oncologist’s Decision on Systemic Therapy in a Real-World Setting

In intermediate risk hormone receptor (HR) positive, HER2 negative breast cancer (BC), the decision regarding adjuvant chemotherapy might be facilitated by multigene expression tests. In all, 142 intermediate risk BCs were investigated using the PAM50-based multigene expression test Prosigna® in a prospective multicentric study. In 119/142 cases, Prosigna® molecular subtyping was compared with local and two central (C1 and C6) molecular-like subtypes relying on both immunohistochemistry (IHC; HRs, HER2, Ki-67) and IHC + tumor grade (IHC+G) subtyping. According to local IHC, 35.4% were Luminal A-like and 64.6% Luminal B-like subtypes (local IHC+G subtype: 31.9% Luminal A-like; 68.1% Luminal B-like). In contrast to local and C1 subtyping, C6 classified >2/3 of cases as Luminal A-like. Pairwise agreement between Prosigna® subtyping and molecular-like subtypes was fair to moderate depending on molecular-like subtyping method and center. The best agreement was observed between Prosigna® (53.8% Luminal A; 44.5% Luminal B) and C1 surrogate subtyping (Cohen’s kappa = 0.455). Adjuvant chemotherapy was suggested to 44.2% and 88.6% of Prosigna® Luminal A and Luminal B cases, respectively. Out of all Luminal A-like cases (locally IHC/IHC+G subtyping), adjuvant chemotherapy was recommended if Prosigna® testing classified as Prosigna® Luminal A at high / intermediate risk or upgraded to Prosigna® Luminal B.     

Surface properties of wood and MDF after ultrasonic-assisted cutting

Surfaces created by ultrasonic-assisted cutting (UC) of beech and spruce and of medium density fibreboard (MDF) are compared to surfaces obtained by conventional linear cutting (CC) using a sharp tool. Topography is evaluated performing roughness measurements and scanning electron microscopy. No effect of UC procedure on mean roughness is found. The surface of MDF and large areas of the surfaces of the woods appear similar after UC and CC, whereas other regions show impact marks and microscopic reels produced by the periodic oscillation of the tool in UC. The wettability of surfaces produced with both wood processing techniques is similar. Surface free energy measurements indicate accelerated ageing caused by UC, probably due to heating.     

Comparison of PCR and quantitative real-time PCR methods for the characterization of ruminant and cattle fecal pollution sources

The State of California has mandated the preparation of a guidance document on the application of fecal source identification methods for recreational water quality management. California contains the fifth highest population of cattle in the United States, making the inclusion of cow-associated methods a logical choice. Because the performance of these methods has been shown to change based on geography and/or local animal feeding practices, laboratory comparisons are needed to determine which assays are best suited for implementation. We describe the performance characterization of two end-point PCR assays (CF128 and CF193) and five real-time quantitative PCR (qPCR) assays (Rum2Bac, BacR, BacCow, CowM2, and CowM3) reported to be associated with either ruminant or cattle feces. Each assay was tested against a blinded set of 38 reference challenge filters (19 duplicate samples) containing fecal pollution from 12 different sources suspected to impact water quality. The abundance of each host-associated genetic marker was measured for qPCR-based assays in both target and non-target animals and compared to quantities of total DNA mass, wet mass of fecal material, as well as Bacteroidales, and enterococci determined by 16S rRNA qPCR and culture-based approaches (enterococci only). Ruminant- and cow-associated genetic markers were detected in all filters containing a cattle fecal source. However, some assays cross-reacted with non-target pollution sources. A large amount of variability was evident across laboratories when protocols were not fixed suggesting that protocol standardization will be necessary for widespread implementation. Finally, performance metrics indicate that the cattle-associated CowM2 qPCR method combined with either the BacR or Rum2Bac ruminant-associated methods are most suitable for implementation.