醋酸甲酯在Cs_(1.5)PW/SiO_2催化剂上的水解反应

通过改变阳离子的种类与配比,制备了一系列SiO2负载的磷钨酸盐催化剂,考察了制备方法对催化剂性能的影响,采用傅里叶变换红外光谱、X射线衍射、X射线荧光光谱、环境扫描电子显微镜等方法对催化剂进行了表征,并考察了该系列催化剂对醋酸甲酯水解反应的活性。实验结果表明,Cs1.5PW/SiO2催化剂的活性最好,当Cs1.5PW负载量(质量分数)为30%时,Cs1.5PW的Keggin结构保持完好,没有硅钨酸阴离子形成,Cs1.5PW在SiO2载体上高度分散;在反应温度55℃、反应时间2h的条件下,醋酸甲酯的转化率为35.79%,约为均相磷钨酸催化剂的1.3倍。该催化剂重复使用4次后,醋酸甲酯的转化率稳定在25%;80℃下反应2h,与NKC-9磺酸树脂催化剂相比,醋酸甲酯的转化率提高了5.17%。     

Shear-induced crystallization of poly(phenylene sulfide)

The crystalline morphology of poly(phenylene sulfide) (PPS) isothermally crystallized from the melt under shear has been observed by polarized optical microscope (POM) equipped with a CSS450 hot-stage. The shish–kebab-like fibrillar crystal structure is formed at a higher shear rate or for a longer shear time, which is ascribed to the tight aggregation of numerous oriented nuclei in the direction of shear. The crystallization induction time of PPS decreases with the shear time, indicating that the shear accelerates the formation of stable crystal nuclei. Under shear, the increase of spherulite growth rate results from highly oriented chains. The melting behavior of shear-induced crystallized PPS performed by differential scanning calorimetry (DSC) shows multiple melting peaks. The lower melting peak corresponds to melting of imperfect crystal, and the degree of crystal perfection decreases as the shear rate increases. The higher melting peak is related to the orientation of molecular chains. These oriented molecular chains form the orientation nuclei which have higher thermal stability than the kebab-like lamellae that are developed later. A new model based on the above observation has been proposed to explain the mechanism of shish–kebab-like fibrillar crystal formation under shear flow.     

Semi‐global output feedback control for nonlinear systems with uncertain time‐delay and output function

This paper considers semi‐global output feedback control for more general nonlinear systems with unknown time‐delay and output function whose derivative is unbounded from above. By introducing a new observer and using the backstepping design method and the Razumikhin stability theorem, an output feedback controller is constructed to achieve a semi‐global stability. Copyright © 2016 John Wiley & Sons, Ltd.     

Lanthanum-Promoted Ru／Sepiolite in Ammonia Synthesis

Theiron basedcatalystsforammoniasynthesishavethecommonproblemsoflowefficiency ,highconsumptionofenergy ,strictrequirementforequip ment,andlowoperationflexibility ,etc .,anditishardtoradicallylowerenergyconsumptionbysimplyimprovingiron basedcatalystsproper…     

Effects of ZrO2 Content on Structure and Performance of Cu/CeO2-ZrO2 Catalysts for Water-Gas Shift Reaction

Water-gas shift(WGS)is a critical step in fuelprocessors for preli minary COclean-up and additionalhydrogen generation prior to the CO clean-up stage,which opened up new potential applications for WGScatalysts.Recently several formulations of noble-met-al…     

Economic analysis of two processes for biodiesel production

In this study, two continuous processes for biodiesel production, alkali catalyzed process and solid acid catalyzed process, are discussed with the help of Aspen Plus. By comparing some economic indicators, it can be found that solid acid catalysis could be a good choice for investors in the near future.     

浅谈智能家居综合布线的几点体会

介绍了家庭综合布线系统的标准、特点,以及现代住宅所涉及的各种弱电子系统及其布线方式,提出了采用家具综合布线系统的解决方案     

南京长江水源突发性污染应急水处理技术应用研究

通过对南京长江水源地的调研,对长江南京水源地污染物进行了预测分析,提出可能对南京水源地造成威胁的污染物依次为油类物质、硫酸、农药、苯酚和重金属镉.针对以上的突发性污染物,提出可采用常规工艺强化、吸油围栏、碱(石灰)中和、粉末活性炭吸附、化学氧化和化学沉淀等应急水处理技术及措施,为全市安全供水提供有效的技术保障.     

江西谷酒的生产工艺

以贡米谷酒为例，本文对江西另一种生产小曲白酒（谷酒）的传统工艺，首次进行较系统的整理和总结，并对谷酒夏季不停产的原因从理论上作了初步的探讨。