High performance multi-layer varistor (MLV) from doped ZnO nanopowders by water based tape casting: Rheology,sintering, microstructure and properties

In this work, we report the fabrication of a high performance multi-layer varistor (MLV) via water based tape casting method using novel compositions of nanomaterials. Bi₂O₃, CaO and Co₃O₄ doped ZnO nanopowders were prepared by solution combustion synthesis (SCS) route, calcined at different temperatures (550, 650, 750 and 850?°C) and characterized by TEM, XRD, SEM and AFM. The nanopowder (crystallite size ~30?nm) calcined at 650?°C for 1?h was used as the starting material for MLV fabrication. Compositions of the slurry containing doped ZnO nanopowders, binder and plasticizer in water solvent were optimized for the fabrication of thick film. The rheological properties of the slurries having different solid loadings were analysed and thick films of various thicknesses (50–500?µm) were prepared by varying the feeding rate of tape casting. The film roughness of 38.3?nm for the thick film made from 40?wt% solid slurry was found to be superior compared to other samples due to the presence of reduced crack and shrinkage. MLV fired at 950?°C for 1.5?h exhibited a coefficient of nonlinearity of 18 and breakdown voltage of 291.5?V that yields superior properties compared to commercial MLVs.     

Densification characteristics of corn cobs

Corn cobs are potential feedstocks for producing heat, power, fuels, and chemicals. Densification of corn cobs into briquettes/pellets would improve their bulk handling, transportation, and storage properties. In this study, densification characteristics of corn cobs were studied using a uniaxial piston-cylinder densification apparatus. With a maximum compression pressure of 150 MPa, effects of particle size (0.85 and 2.81 mm), moisture content (10 and 20% w.b.), and preheating temperature (25 and 85 °C) on the density and durability of the corn cob briquettes (with diameter of about 19.0 mm) were studied. It was found that the durability (measured using ASABE tumbling can method) of corn cob briquettes made at 25 °C was 0%. At both particle sizes, preheating of corn cob grinds with about 10% (w.b.) moisture content to 85 °C produced briquettes with a unit density of > 1100 kg m^-3 and durability of about 90%.     

Reducing life cycle greenhouse gas emissions of corn ethanol by integrating biomass to produce heat and power at ethanol plants

A life-cycle assessment (LCA) of corn ethanol was conducted to determine the reduction in the life-cycle greenhouse gas (GHG) emissions for corn ethanol compared to gasoline by integrating biomass fuels to replace fossil fuels (natural gas and grid electricity) in a U.S. Midwest dry-grind corn ethanol plant producing 0.19 hm³ y⁻¹ of denatured ethanol. The biomass fuels studied are corn stover and ethanol co-products [dried distillers grains with solubles (DDGS), and syrup (solubles portion of DDGS)]. The biomass conversion technologies/systems considered are process heat (PH) only systems, combined heat and power (CHP) systems, and biomass integrated gasification combined cycle (BIGCC) systems. The life-cycle GHG emission reduction for corn ethanol compared to gasoline is 38.9% for PH with natural gas, 57.7% for PH with corn stover, 79.1% for CHP with corn stover, 78.2% for IGCC with natural gas, 119.0% for BIGCC with corn stover, and 111.4% for BIGCC with syrup and stover. These GHG emission estimates do not include indirect land use change effects. GHG emission reductions for CHP, IGCC, and BIGCC include power sent to the grid which replaces electricity from coal. BIGCC results in greater reductions in GHG emissions than IGCC with natural gas because biomass is substituted for fossil fuels. In addition, underground sequestration of CO₂ gas from the ethanol plant’s fermentation tank could further reduce the life-cycle GHG emission for corn ethanol by 32% compared to gasoline.     

Factors affecting strength and durability of densified biomass products

Effectiveness of a densification process to create strong and durable bonding in densified products such as pellets, briquettes, and cubes can be determined by testing the strength (i.e., compressive resistance, impact resistance, and water resistance), and durability (i.e., abrasion resistance) of the densified products. These tests can indicate the maximum force/stress that the densified products can withstand, and the amount of fines produced during handling, transportation, and storage. In this article, the procedures used for measuring the strength and durability of the densified products are discussed. The effects of constituents of the feed such as starch, protein, fiber, fat, lignin and extractives; feed moisture content; feed particle size and its distribution; feed conditioning temperature/preheating of feed; added binders; and densification equipment variables (forming pressure, and pellet mill and roll press variables) on the strength and durability of the densified products are reviewed. This article will help select process parameters to produce strong and durable densified products from new biomass feedstocks or animal feed formulations. Guidelines for developing standards on criteria for the acceptance levels of strength and durability of the densified products are presented.     

Synthesis and characterization of Co and Mn doped NiO nanoparticles

Diluted magnetic semiconductors (DMS) are intensively studied for their potential spintronics applications, especially those with Curie temperature above the room temperature. Ni_1?x Mn _x O and Ni_1?x Co _x O (x=1% & 2%), nanoparticles with size around 40–50 nm, were prepared by co-precipitation method. An NiO single phase structure was confirmed by powder X-ray diffraction measurements. Also, diffraction peaks show a systematic shift towards higher angle with an increase in Mn concentration, which is associated with the lattice variation. The samples were pelleted and examined for its magnetic property using a vibrating sample magnetometer (VSM); it indicates paramagnetic-like behavior at room temperature. The increase in a.c conductivity with increasing temperature is attributed to the increase in drift mobility of the charge carriers.     

Anti-Obesity Efficacy of Pediococcus acidilactici MNL5 in Canorhabditis elegans Gut Model

In the present study, thirty two lactic acid bacteria (LAB) were isolated from fermented Indian herbal medicine. In comparison to other strains, MNL5 had stronger bile salt hydrolase (BSH) and cholesterol-lowering properties. Furthermore, it can withstand the extreme conditions found in the GI tract, due to, e.g., pepsin, bile salts, pancreatin, and acids. Pediococcus acidilactici MNL5 was identified as a probiotic candidate after sequencing the 16S rRNA gene. The antibacterial activity of P. acidilactici MNL5 cell-free supernatants (CFS) against Escherichia coli, Staphylococcus aureus, Helicobacter pylori, Bacillus cereus, and Candida albicans was moderate. A Caenorhabditis elegans experiment was also performed to assess the effectiveness of P. acidilactici MNL5 supplementation to increase life span compared to E. coli supplementation (DAF-2 and LIU1 models) (p < 0.05). An immense reduction of the lipid droplets of C. elegans was identified through a fluorescent microscope. The drastic alteration of the expression of fat genes is related to obesity phenotypes. Hence, several paths are evolutionary for C. elegans; the results of our work highlight the nematode as an important model for obesity.     

Low-temperature aeration to control Indianmeal moth, Plodia interpunctella (Hübner), in stored grain in twelve locations in the United States: a simulation study

Aeration management strategies were developed to control cold-acclimated and diapausing Indianmeal moth, Plodia interpunctella (Hübner), larvae in grain bins during winter in north- and east-central regions of the US. The application in this study focuses on corn because it is the dominant crop in these regions, but we believe that the analyses can be applied to other grains as well. Contour maps for hours below −10 °C for the months of December, January, and February were developed to help effective planning and management of aeration to control overwintering stored-grain insects. Two cumulative lethality index (CLI) models were developed to estimate mortality of laboratory-reared (diapausing without cold-acclimation) and field-collected (cold-acclimated, and diapausing with cold-acclimation) P. interpunctella larvae under changing temperature conditions. The CLI models were used for evaluating aeration management strategies. Simulation studies were conducted using 30 years of weather data for 12 locations in north- and east-central regions of the US to evaluate different aeration management strategies for controlling P. interpunctella larvae. For each strategy, temperatures of headspace air and grain in the top meter of the grain mass were simulated using an existing model for the period of December-February. The tested management strategies included no aeration, continuous aeration, and intermittent aeration by controlling fan operation. During aeration, air was pulled from the headspace downward through the grain with an airflow rate of 0.11 m³/min-t (0.1 cfm/bu). Simulation results indicated that a fan control strategy that turned the aeration fan on when the grain temperature at 0.4-m depth was greater than the headspace-air temperature was the best strategy for managing P. interpunctella larvae in all tested locations. For this strategy, the CLI model indicated that 100% mortality of P. interpunctella larvae could be achieved at a grain depth of 0.4 m from the top grain surface in all locations. For this strategy, the aeration fan operated about 10% of the time from December to February. The average cost of electrical energy required for aeration fan operation with this strategy for all locations was 1.3 ¢/t (0.033 ¢/bu) based on an electrical energy cost of 7 ¢/kWh.