Boron-doped activated carbon from the stems of Prosopis juliflora as an effective electrode material in symmetric supercapacitors

For a supercapacitor electrode, carbon-based materials have received great attention for their high surface area and stability. In this work, sustainable and cost-effective synthesis of boron-doped activated biomass-derived carbon from the stems of Prosopis juliflora has been reported for supercapacitor applications. The activation by KOH creates pores and boron induces p-type doping in the carbon matrix. The material gave a higher specific capacitance of 307.14 F/g at a current density of 0.5 A/g. The symmetric supercapacitor device delivered 156.29 F/g of specific capacitance with 98.1% of energy efficiency. The observed energy and power densities were 7.81 Wh/Kg and 150 W/Kg, respectively. The device was further studied with stability test for 1000 charge/discharge cycles and showed 98.6% of capacitance retention and 97.9% of coulombic efficiency.

     

Prototype test on X-bracing panels using cold-formed lipped angles

The behavior and suitability of cold-formed lipped angle members for X-bracing with redundant have been studied. For the purpose, two full-scale panel tests were carried out. The first panel was designed so that the compression member would fail by buckling in flexural mode and the second panel in flexural-torsional mode. The members were designed using ASCE Manual No. 52. Theoretical aspects of least radius of gyration and buckling behavior of this bracing system have been discussed. The investigation on first panel, revealed that the member would buckle only in the flexural-torsional mode although flexural buckling would govern the design. The second panel test result showed that, the buckling mode and strength of the system for lipped angle sections can be predicted reasonably well.     

Multipartite entangled magnon states as quantum communication channels

We investigate the entanglement properties of the two magnon states and explicate conditions under which, the two magnon state becomes useful for several quantum communication protocols. We systematically study the temporal behaviour of concurrence to find out the effect of exchange interaction on entanglement. The two magnon state, which is potentially realizable in quantum dots using Heisenberg exchange interaction, is found to be suitable for carrying out deterministic teleportation of an arbitrary two qubit composite system. Further, conditions for which the channel capacity reaches “Holevo bound”, allowing four classical bits to be transmitted through two qubits are derived. Later, an unconventional protocol is given to demonstrate that this state can be used for sharing of a two qubit entangled state among two parties.     

Preparation of NiAl2O4/SiO2 and Co2+-Doped NiAl2O4/SiO2 Nanocomposites by the Sol–Gel Route

NiAl₂O₄/SiO₂ and Co²⁺-doped NiAl₂O₄/SiO₂ nanocomposite materials of compositions 5% NiO – 6% Al₂O₃– 89% SiO₂ and 0.2% CoO – 4.8% NiO – 6% Al₂O₃– 89% SiO₂, respectively, were prepared by a sol–gel process. NiAl₂O₄ and cobalt-doped NiAl₂O₄ nanocrystals were grown in a SiO₂ amorphous matrix at around 1073 K by heating the dried gels from 333 to 1173 K at the rate of 1 K/min. The formations of NiAl₂O₄ and cobalt-doped NiAl₂O₄ nanocrystals in SiO₂ amorphous matrix were confirmed through X-ray powder diffraction, Fourier transform infrared spectroscopy, differential scanning calorimeter, transmission electron microscopy (TEM), and optical absorption spectroscopy techniques. The TEM images revealed the uniform distribution of NiAl₂O₄ and cobalt-doped NiAl₂O₄ nanocrystals in the amorphous SiO₂ matrix and the size was found to be ∼5–8 nm.     

Vapor-Phase Alkylation of Toluene with Isopropanol over Mg/Al, Ni/Al and Cu/Al Hydrotalcites (Layered Double Hydroxide)

Vapor-phase isopropylation of toluene has been carried out over Mg/Al, Ni/Al and Cu/Al calcined hydrotalcites (CHTs). Reaction conditions were optimized for alkylation by varying temperature, weight hourly space velocity and reactant mole ratio. Side-chain alkylation is found to be more predominant than ring alkylation over Mg/Al CHT, while Ni/Al and Cu/Al CHTs favored ring alkylation. The main products were isobutylbenzene and cymene. The combined participation of acidic and basic sites of the materials is found to be crucial for both side-chain and ring alkylation of toluene with isopropanol. An X-ray diffraction pattern of the resulting oxide indicates a diffuse MgO structure. The incorporation of small amounts of Al³⁺ to MgO generates new surface Lewis acid--base pair sites.     

Enhanced electrochemical performance and thermal stability of La2O3-coated LiCoO2

An enhanced electrochemical performance LiCoO₂ cathode was synthesized by coating with various wt.% of La₂O₃ to the LiCoO₂ particle surfaces by a polymeric method, followed by calcination at 923 K for 4 h in air. The surface-coated materials were characterized by XRD, TGA, SEM, TEM, BET and XPS/ESCA techniques. XRD patterns of La₂O₃-coated LiCoO₂ revealed that the coating did not affect the crystal structure, α-NaFeO₂, of the cathode material compared to pristine LiCoO₂. TEM images showed a compact coating layer on the surface of the core material that had an average thickness of about ∼15 nm. XPS data illustrated that the presence of two different environmental O 1s ions corresponds to the surface-coated La₂O₃ and core material. The electrochemical performance of the coated materials by galvanostatic cycling studies suggest that 2.0 wt.% coated La₂O₃ on LiCoO₂ improved cycle stability (284 cycles) by a factor of ∼7 times over the pristine LiCoO₂ cathode material and also demonstrated excellent cell cycle stability when charged at high voltages (4.4, 4.5 and 4.6 V). Impedance spectroscopy demonstrated that the enhanced performance of the coated materials is attributed to slower impedance growth during the charge-discharge processes. The DSC curve revealed that the exothermic peak corresponding to the release of oxygen at ∼464 K was significantly smaller for the La₂O₃-coated cathode material and recognized its high thermal stability.     

Vapor-Phase Isopropylation of Phenol over Fe-Containing Al-MCM-41 Molecular Sieves

Al-MCM-41 and Fe-containing MCM-41 molecular sieves are hydrothermally synthesized. The low-angle XRD analysis shows that iron incorporation in Al-MCM-41 retains the hexagonal structure of MCM-41. The higher d-spacing values of Fe-Al-MCM-41 catalysts than those of Al-MCM-41 indicate the incorporation of iron into the framework. The mesoporous nature of the materials was confirmed by nitrogen adsorption isotherms. Electron paramagnetic resonance (EPR) and diffuse reflectance spectra (DRS) techniques confirm the tetrahedral coordination of iron into the Al-MCM-41 framework. Acidity of the synthesized catalysts was analyzed by both TPD of ammonia and pyridine-adsorbed FT-IR spectroscopy. The acidity measurements indicate that iron incorporation increases both Lewis and Brønsted acidity of the catalysts. Vapor-phase isopropylation of phenol with the new'alkylating agent isopropyl acetate was carried over the H-forms of the above catalysts. The phenol to isopropyl acetate ratio of 1?:?2 and the phenol space velocity of 1.1 h^-1 were found to be the optimum conditions for better phenol conversion and para isomer (4-isopropyl phenol) selectivity. On comparison, the Fe-incorporated Al-MCM-41 catalysts show significantly higher phenol conversion and selectivity toward the important product 4-isopropyl phenol (4-IPP) may be due to stronger Brønsted acid sites generated by the strengthening effect of nearby Lewis acid sites. Further, the undesired and dialkylated products selectivity are found to be lower over Fe-incorporated Al-MCM-41 than pure Al-MCM-41 catalysts.     

Vapour phase esterification of butyric acid with 1-pentanol over Al-MCM-41 mesoporous molecular sieves

Al-MCM-41 molecular sieves with Si/Al ratios 25, 50, 75 & 100 were synthesized hydrothermally and characterized systematically by various analytical and spectroscopy techniques. Their catalytic activity was evaluated for the vapour phase reaction of butyric acid with 1-pentanol. Pentyl butyrate was obtained as the only product. Reaction parameters such as temperature, molar ratio and feed rate were optimized for higher butyric acid conversion. The time-on-stream study was carried out at optimum conditions resulting in gradual decrease in the activity of the catalyst.     

Topological alternate centrality measure capturing drug targets in the network of MAPK pathways

A new centrality of the nodes in the network is proposed called alternate centrality, which can isolate effective drug targets in the complex signalling network. Alternate centrality metric defined over the network substructure (four nodes – motifs). The nodes involving in alternative activation in the motifs gain in metric values. Targeting high alternative centrality nodes hypothesised to be destructive free to the network due to their alternative activation mechanism. Overlapping and crosstalk among the gene products in the conserved network of MAPK pathways selected for the study. In silico knock‐out of high alternate centrality nodes causing rewiring in the network is investigated using MCF‐7 breast cancer cell line‐based data. Degree of top alternate centrality nodes lies between the degree of bridging and pagerank nodes. Node deletion of high alternate centrality on the centralities such as eccentricity, closeness, betweenness, stress, centroid and radiality causes low perturbation. The authors identified the following alternate centrality nodes ERK1, ERK2, MEKK2, MKK5, MKK4, MLK3, MLK2, MLK1, MEKK4, MEKK1, TAK1, P38alpha, ZAK, DLK, LZK, MLTKa/b and P38beta as efficient drug targets for breast cancer. Alternate centrality identifies effective drug targets and is free from intertwined biological processes and lethality.Inspec keywords: biochemistry, molecular biophysics, cellular biophysics, cancer, drugs, genetics, biomedical materialsOther keywords: MAPK pathways, complex signalling network, pagerank nodes, node deletion, drug targets, MCF‐7 breast cancer cell line‐based data, cellular mechanisms, ERK1 nodes, ERK2 nodes, MEKK2 nodes, MKK5 nodes, MKK4 nodes, MLK3 nodes, MLK2 nodes, MLK1 nodes, MEKK4 nodes, MEKK1 nodes, TAK1 nodes, P38alpha nodes, ZAK nodes, DLK nodes, LZK nodes, MLTKa/b nodes, P38beta nodes     

Modifications in the AA5083 Johnson-Cook Material Model for Use in Friction Stir Welding Computational Analyses

Johnson-Cook strength material model is frequently used in finite-element analyses of various manufacturing processes involving plastic deformation of metallic materials. The main attraction to this model arises from its mathematical simplicity and its ability to capture the first-order metal-working effects (e.g., those associated with the influence of plastic deformation, rate of deformation, and the attendant temperature). However, this model displays serious shortcomings when used in the engineering analyses of various hot-working processes (i.e., those utilizing temperatures higher than the material recrystallization temperature). These shortcomings are related to the fact that microstructural changes involving: (i) irreversible decrease in the dislocation density due to the operation of annealing/recrystallization processes; (ii) increase in grain-size due to high-temperature exposure; and (iii) dynamic-recrystallization-induced grain refinement are not accounted for by the model. In this study, an attempt is made to combine the basic physical-metallurgy principles with the associated kinetics relations to properly modify the Johnson-Cook material model, so that the model can be used in the analyses of metal hot-working and joining processes. The model is next used to help establish relationships between process parameters, material microstructure and properties in friction stir welding welds of AA5083 (a non-age-hardenable, solid-solution strengthened, strain-hardened/stabilized Al-Mg-Mn alloy).