Fuzzy functions based ARX model and new fuzzy basis function models for nonlinear system identification

In this study, auto regressive with exogenous input (ARX) modeling is improved with fuzzy functions concept (FF-ARX). Fuzzy function with least squares estimation (FF-LSE) method has been recently developed and widely used with a small improvement with respect to least squares estimation method (LSE). FF-LSE is structured with only inputs and their membership values. This proposed model aims to increase the capability of the FF-LSE by widening the regression matrix with lagged input–output values. In addition, by using same idea, we proposed also two new fuzzy basis function models. In the first, basis of the fuzzy system and lagged input–output values are structured together in the regression matrix and named as “L-FBF”. Secondly, instead of using basis function, the membership values of the lagged input–output values are used in the regression matrix by using Gaussian membership functions, called “M-FBF”. Therefore, the power of the fuzzy basis function is also enhanced. For the corresponding models, antecedent part parameters for the input vectors are determined with fuzzy c-means (FCM) clustering algorithm. The consequent parameters of the all models are estimated with the LSE. The proposed models are utilized and compared for the identification of nonlinear benchmark problems.     

Robust microencapsulated phase change materials in concrete mixes for sustainable buildings

For passive building applications, phase change materials (PCMs) are microencapsulated to avoid leakage of PCM from concrete structure. The primary challenge of using microencapsulated PCM (MPCM) is its weak shell structure. New MPCMs with different shell compositions to prevent breakage during mixing in fresh concrete are needed. In this study, free radical polymerization method to microencapsulate capric acid–myristic acid mixture as PCM with two different methyl methacrylate co‐polymers is proposed to produce robust MPCMs for building applications. Two new microcapsules (MPCM‐1 and MPCM‐2) having latent heats of 91.9 and 97.3 J/g were synthesized. SEM analyses showed the size of microcapsules being in the range of 400–850 nm for MPCM‐1 and 250–475 nm for MPCM‐2. Analyses also reveal that the shells of MPCMs were not harmed, as they were added into concrete mixes. The microsphere's geometry was preserved, and distribution was homogeneous. The MPCMs were also studied under thermal tests of 1000 heating/cooling cycles. No significant changes in thermal properties were observed after thermal cycling tests. Copyright © 2016 John Wiley & Sons, Ltd.     

Statistical thermal stability of PVC

Experimental design was used to optimize the processing parameters for the decomposition of poly(vinyl chloride). Factorial design and face centered composite design (FCC) were applied to determine the optimum conditions. A total of 10 g PVC powder was mixed with different amounts of zinc stearate (ZnSt₂) and natural zeolite and tested for thermal stability. Factorial fitted model was explained by first order pattern due to the significant main effect regression constants, and FCC model was described by second order model owing to higher order polynomial coefficients. FCC design was superior to factorial design as FCC considers not only its pure quadratic effects contribution but also its higher overall desirability for thermal stability of PVC. For factorial design the optimum conditions were determined as 163.06 mg for ZnSt₂, 399.99 mg for zeolite, and 140°C for temperature with desirability of 0.933. However, 400 mg for ZnSt₂, 333.24 mg for zeolite, and 140°C for temperature with desirability of 0.956 were obtained as the optimum conditions by FCC design. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

A novel approach to simulate growth of multi-stem willow in bioenergy production systems with a simple process-based model (3PG)

An important requirement for commercialization of willow biomass production in short-rotation crop (SRC) plantations is the reliable and cost-efficient estimation of biomass yield. Predictions and simulations of willow stand biomass have been problematic due to issues with modeling the multi-stem growth form of willow. The aim of this paper was to develop a new approach for managing allometric measurements from multi-stemmed willow for stand growth simulations. The 3PG model (Physiological Principles in Predicting Growth) was parameterized for willow and was used for biomass yield simulation for an entire 22-yr cycle (seven 3-yr rotations) of willow in SRC plantations. The multi-stemmed growth form was transformed into a single-stem modeling form by deriving whole plant willow allometric relationships using detailed stem-level measurements of basal area, stem biomass and volume. 3PG model predictions for plant diameter, height, biomass, and stand biomass and volume were within the 95% confidence range of mean plot values. Model simulations showed that after seven 3-yr rotations only 20% of planted cuttings would survive (a decrease from 15,152 to 3022 plants ha⁻¹), but stand volume would increase continuously with each subsequent rotation. 3PG predictions for cumulative (for 22 yr) aboveground biomass was 272 Mg ha⁻¹ and mean annual yield was 12 Mg ha⁻¹ yr⁻¹, comparing favorably with other findings. To our knowledge, this work is the first where the 3PG model was calibrated and used for willow species. Once parameterized for a specific willow clone, 3PG can predict biomass accumulation for any agricultural land in North America using only available soil and climate data.     

Biosorption of copper (II) from aqueous solutions by wheat shell

The adsorption capacity of wheat shell for copper (II) was studied at various pH (2-7), agitation speeds (50-250 rpm) and initial metal ion concentrations (Co, from 10 to 250 mg.L⁻¹). Maximum biosorption of copper onto wheat shell occurred at 240 rpm agitation speed and at pH between 5 and 6. The biosorption values of copper (11) were increased with increasing pH from 2 to 5 and decreased with increasing copper/wheat shell (x/m) ratios from 0.83 to 10.84 mgCu(II).g⁻¹ wheat shell. The biosorption efficiencies at these x/m ratios were 99% and 52%, respectively, at the end of the 120 min contact time (t). The equilibrium isotherms and kinetics were obtained from batch adsorption experiments at 298 K. It was observed that wheat shell was a suitable biosorbent for removing Cu(II) from aqueous solutions.     

High-surface-area SBA-15–SO3H with enhanced catalytic activity by the addition of poly(ethylene glycol)

The influence of poly(ethylene glycol) (PEG) and synthesis temperature in the synthesis of SBA-15–SO₃H was investigated to evaluate the catalytic activity in the esterification of propionic acid with methanol. The catalysts were characterized by means of surface and structure analyses; X-ray diffraction, FT-IR, scanning electron microscopy, Thermo-gravimetric and N₂ adsorption/desorption techniques. It was found that, by the addition of PEG, the surface area and porosity of SBA-15–SO₃H increased, while the structure and size of mesopores remained unchanged. Nitrogen sorption measurements indicate that PEG introduces additional pores into the pore walls of SBA-15–SO₃H. Thus, a simple way of improving the porosity of mesoporous SBA-15–SO₃H was presented that could enhance transport of substrates through the porous system and allow the generation of stable mesoporous replicas, important for catalytic applications and also beneficial for replication and nanocasting purposes.     

Effect of area on color harmony in simulated interiors

The main aim of this study is to examine the effect of area on color harmony in simulated interior spaces. The secondary aim of the study is to investigate how the term color harmony is defined and the link between color harmony and related terms used to define it. These terms can explain why a color scheme is evaluated as harmonious. Four sets of three-color combinations created by using the hues red, blue, yellow, green, purple, and orange were studied in a simulated office interior emphasizing different proportional use of each color. Firstly, participants evaluated harmony content of the images. Secondly, they evaluated each image regarding the terms related to color harmony. Findings indicated that area had an effect on color harmony for two of the color combinations (warm & cool). However, there were no strong but rather moderate and weak correlations between color harmony and the terms.     

Effects of gonadotropin and testosterone treatments on prostate volume and serum prostate specific antigen levels in male hypogonadism

Various monosialo- and disialo-gangliosides and their derivatives were examined by delayed ion extraction matrix-assisted laser desorption ionization time-of-flight mass spectrometry (DE MALDI-TOF MS) in the reflector mode with alpha-cyano-4-hydroxycinnamic acid or 2,5-dihydroxybenzoic acid used as the matrix. Native gangliosides were generally found to give good spectra in the negative ion mode. 2,5-Dihydroxybenzoic acid was a better matrix for gangliosides than alpha-cyano-4-hydroxycinnamic acid, because this matrix seemed to minimize loss of sialic acid and carbon dioxide of gangliosides. About 1 pmol of ganglioside was able to be detected with this matrix. When "A-series" gangliosides such as GD1a and GalNAc-GD1a gave undesirable extra peaks probably due to loss of sialic acid besides molecule-related ion peaks, the methyl-esterification of the gangliosides at the carboxyl groups of sialic acids was found to be necessary to obtain good DE MALDI-TOF mass spectra in the positive ion mode. In contrast, "B-series" gangliosides such as GD1b, GD2, and GD3 gave rise to major dehydrated molecule-related ion [M-H2O-H]- peaks in the negative ion mode without the pretreatment of methyl-esterification. The DE MALDI-TOF mass spectrometric analysis enabled us to distinguish between GD1a and GD1b, which have the same molecular weight. It was also found that not only a purified sample, but also a mixed sample of various gangliosides was amenable to the identification of them by DE MALDI-TOF MS.     

Synthesis and Properties of Polyimides from 1,3-di(p- dimethylamino benzyl)-imidazolidine-2-thion

Summary A synthetic strategy is presented that allows the preparation of dimethylamino functionalized heterocyclic system 1,3-di (p-dimethylaminobenzy1)-imidazolidine-2-thion that was then used to prepare polyimides by the two-stage polycondensation method. The key to this success was the development of an efficient procedure leading highly pure dimethylamino monomer. Polyimides derived from 1,3-di(p-dimethylaminobenzyl)-imidazolidine-2-thion and commercial dianhydrides exhibited excellent solubility in various polar solvents. These polymers showed glass transition temperatures between 290–360°C, and initial decomposition temperature 490–485 °C and 10% mass loss ranging from 505–75°C in air. Received: 17 April 2002/Revised version: 25 January 2003/ Accepted: 14 March 2003 Correspondence to Turgay Seckin     

Hybrid poplar growth in bioenergy production systems: Biomass prediction with a simple process-based model (3PG)

Establishing short-rotation tree plantations for bioenergy and fiber production on agricultural land (abandoned farmland) would provide significant environmental and economic benefits for rural communities and society as a whole. Walker hybrid poplar (Populus deltoides x P. nigra) is one of the most commonly used varieties cultivated in Saskatchewan, Canada; however, there are no existing hybrid poplar growth models in the literature. The aim of this work was to parameterize and evaluate the 3PG model (Physiological Principles in Predicting Growth) to predict Walker tree growth in the climate and soils of Saskatchewan. We used annual data from Walker poplar trials (4- to 11-yr old stands) established at three spacing levels (2.4, 3.0, and 3.7 m) at three sites located in central Saskatchewan, Hnr, BH, and ML sites. The data were split into two sets – the modeling set from the Hnr site was used to parameterize 3PG, and the testing sets from the BH and ML sites were used to evaluate Walker growth predictions made by 3PG. The bias, sum(predicted minus observed) divided by number of observations, for tree height predictions ranged from ?1.76 to 1.45 m, and bias for diameter at breast height (DBH) ranged from ?2.61 to 0.66 cm. Regression R-square values of 3PG-predicted versus observed height and DBH ranged from 0.75 to 0.98. Our results indicated that, once parameterized, 3PG could predict Walker hybrid poplar growth with desirable accuracy by only utilizing commonly available soils and climate data for marginal or more productive agricultural land across Saskatchewan.