Current trends in structural development and modification strategies for metal-organic frameworks (MOFs) towards photocatalytic H2 production: A review

Photocatalytic H₂ generation using semiconductor photocatalysts is considered as a cost-effective and eco-friendly technology for solar to energy conversion; however, the present photocatalysts have been recognized to depict low efficiency. Currently, porous coordination polymers known as metal-organic frameworks (MOFs) constituting flexible and modifiable porous structure and having excess active sites are considered to be appropriate for photocatalytic H₂ production. This review highlights current progress in structural development of MOF materials along with modification strategies for enhanced photoactivity. Initially, the review discusses the photocatalytic H₂ production mechanism with the concepts of thermodynamics and mass transfer with particular focus on MOFs. Elaboration of the structural categories of MOFs into Type I, Type II, Type III and classification of MOFs for H₂ generation into transition metal based, post-transition metal based, noble-metal based and hetero-metal based has been systematically discussed. The review also critically deliberate various modification approaches of band engineering, improvement of charge separation, efficient irradiation utilization and overall efficiency of MOFs including metal modification, heterojunction formation, Z-scheme formation, by introducing electron mediator, and dye based composites. Also, the MOF synthesized derivatives for photocatalytic H₂ generation are elaborated. Finally, future perspectives of MOFs for H₂ generation and approaches for efficiency improvement have been suggested.     

The Effects of Survey Administration on Disclosure Rates to Sensitive Items Among Men: A Comparison of an Internet Panel Sample with a RDD Telephone Sample

Research using Internet surveys is an emerging field, yet research on the legitimacy of using Internet studies, particularly those targeting sensitive topics, remains under-investigated. The current study builds on the existing literature by exploring the demographic differences between Internet panel and RDD telephone survey samples, as well as differences in responses with regard to experiences of intimate partner violence perpetration and victimization, alcohol and substance use/abuse, PTSD symptomatology, and social support. Analyses indicated that after controlling for demographic differences, there were few differences between the samples in their disclosure of sensitive information, and that the online sample was more socially isolated than the phone sample. Results are discussed in terms of their implications for using Internet samples in research on sensitive topics.     

Recent developments in catalyst synthesis using DBD plasma for reforming applications

The catalyst has a significant role in gas processing applications such as reforming technologies for H₂ and syngas production. The stable catalyst is requisite for any industrial catalysis application to make it commercially viable. Several methods are employed to synthesize the catalysts. However, there is still a challenge to achieve a controlled morphology and pure catalyst which majorly influences the catalytic activity in reforming applications. The conventional methods are expansive, and the removal of the impurities are major challenges. Nevertheless, it is not straightforward to achieve the desired structure and stability. Therefore, significant interest has been developed on the advanced techniques to take control of the physicochemical properties of the catalyst through non-thermal plasma (NTP) techniques. In this review, the systematic evolution of the catalyst synthesis using NTP technique is elucidated. The emerging DBD plasma to synthesized and effective surface treatment is reviewed. DBD plasma synthesized catalyst performance in reforming application for H₂ and syngas production is summarised. Furthermore, the status of DBD plasma for catalyst synthesis and proposed future avenues to design environmentally suitable and cost-effective synthesis techniques are discussed.     

Optical,electrical, mechanical,and thermal properties and non-isothermal decomposition behavior of poly(vinyl alcohol)–ZnO nanocomposites

Iranian Polymer Journal - Poly(vinyl alcohol) (PVA) nanocomposites incorporated with ZnO nanofiller were prepared and examined to study the influence of nanofiller on their properties. All the...     

Regulation of Autophagy Machinery in Magnaporthe oryzae

Plant diseases cause substantial loss to crops all over the world, reducing the quality and quantity of agricultural goods significantly. One of the world’s most damaging plant diseases, rice blast poses a substantial threat to global food security. Magnaporthe oryzae causes rice blast disease, which challenges world food security by causing substantial damage in rice production annually. Autophagy is an evolutionarily conserved breakdown and recycling system in eukaryotes that regulate homeostasis, stress adaption, and programmed cell death. Recently, new studies found that the autophagy process plays a vital role in the pathogenicity of M. oryzae and the regulation mechanisms are gradually clarified. Here we present a brief summary of the recent advances, concentrating on the new findings of autophagy regulation mechanisms and summarize some autophagy-related techniques in rice blast fungus. This review will help readers to better understand the relationship between autophagy and the virulence of plant pathogenic fungi.     

Performance of the MEWMA-CoDa control chart in the presence of measurement errors

This paper can be considered as an extension of the work of Tran et al (for monitoring compositional data using a multivariate exponentially weighted moving average MEWMA-compositional data [CoDa] chart) by taking into account potential measurement errors that are known to highly affect production processes. A linearly covariate error model with a constant error variance is used to study the impact of measurement errors on the MEWMA-CoDa control chart. In particular, the influence of the device parameters (σ_M,b), the number of independent observations m, and the the number of variables p are investigated in terms of the MEWMA optimal couples (r,H) as well as in terms of their corresponding ARLs. A comparison between the Hotelling-CoDa T² and the proposed chart is made in order to show that the MEWMA-CoDa chart is more efficient in detecting shifts in the presence of measurement errors. A real-life example of muesli production, using multiple measurements for each composition, is used to estimate the parameters and also to demonstrate how the MEWMA-CoDa can handle measurement errors to detect shifts in the process.     

Inseminated Female Mice (Mus musculus) Investigate Rather Than Avoid Novel Males That Disrupt Pregnancy, but Sires Protect Pregnancy.

Experiment 1 replicated the Bruce effect, showing pregnancy termination in CF1 strain female mice (Mus musculus) housed underneath novel heterogeneous strain (HS) males. In a 4-arm maze in Experiment 2, inseminated CF1 females approached novel HS males more often than CF1 sires or unfamiliar CF1 males. In Experiment 3, inseminated females showed random nesting sites when housed continuously underneath 4 compartments containing the sire, a novel CF1 male, a novel HS male, and no stimulus. In Experiment 4, when inseminated females were housed with or without the sire below novel HS males, the sire's presence decreased female interaction with novel males and mitigated the Bruce effect. Inseminated females do not reliably avoid males that disturb pregnancy unless the sire is immediately present. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Synergistically improved charge separation in bimetallic Co–La modified 3D g-C3N4 for enhanced photocatalytic H2 production under UV–visible light

Synergistically improved Lanthanum (La) and Cobalt (Co) co-modified g-C₃N₄ was synthesized for photocatalytic H₂ generation from methanol-water mixture under UV–visible light irradiation. The g-C₃N₄ was synthesized by thermal polymerization and co-modification was carried out by wet impregnation method. Photocatalytic H₂ production by Co₂/La₁-g-C₃N₄ was carried out in a slurry photoreactor with the highest H₂ production of 250 μmol g^?1h^?1, which was 2.5, 1.35, and 1.25 times increased as compared to pristine g-C₃N₄, La₁-g-C₃N_4, and Co₂-g-C₃N_4, respectively. The enhanced activity can be associated with the synergistic effect for proficient charge separation due to electron trapping ability of Co and La, and C–H bond cleavage ability of La for enhanced oxidation. Among the sacrificial agents, highest H₂ generation rate was observed with triethanolamine which generated 8.1, 3.6, 1.7, 2.4, and 4.2 times boosted H₂ generation than water, ethanol, methanol, ethylene glycol, and glycerol, respectivel, because of the effectual binding of triethanolamine onto amine-containing g-C₃N₄. Moreover, it also depicted good photostability towards photocatalytic H₂ generation. Therefore, Co and La co-modification was proved to be effective for efficient charge separation and reduction of charge carrier's recombination and would be beneficial for other solar energy applications.