Substitutes for 1-naphthylamine. Part 1-a comparative study of monoazo anionic dyes from 5-acetaniidoaniline-2-sulphonic acid and 1-naphthylamine

5-Acetamidoaniline-2-sulphonic acid has been evaluated as a substitute for 1-naphthylamine by synthesising and evaluating a parallel series of monoazo dyes derived from both components.     

Enhanced anti-biofilm activity of facile synthesized silver oxide nanoparticles against K. pneumoniae

Journal of Inorganic and Organometallic Polymers and Materials - The silver oxide nanoparticle was successfully synthesized using floral waste by simple one pot, cost effective method. The complete...     

Using a soft core in a SoC design: experiences with picoJava

Through our experience in synthesis, validation, test, and integration of the picoJava processor core in a system-on-chip (SoC) design we point out the challenges faced and issues to address in efficient reuse of a soft core     

Nitrites Derived From Foneiculum Vulgare (Fennel) Seeds Promotes Vascular Functions

Abstract: Recent evidence has demonstrated that nitrites play an important role in the cardiovascular system. Fennel (Foneiculum vulgare) seeds are often used as mouth fresheners after a meal in both the Indian sub‐continent and around the world. The present study aims to quantify the nitrite and nitrates in fennel seeds as well as elucidating the effect of fennel derived‐nitrites on vascular functions. Results from our study show that fennel seeds contain significantly higher amount of nitrites when compared to other commonly used post‐meal seeds. Furthermore our study confirmed the functional effects of fennel derived‐nitrites using in vitro and ex vivo models that describe the promotion of angiogenesis, cell migration, and vasorelaxation. We also showed that chewing fennel seeds enhanced nitrite content of saliva. Thus our study indicates the potential role of fennel derived‐nitrites on the vascular system. Practical Application: This study is focused on determining the effect of fennel‐derived nitrites on angiogenesis (the formation of new blood vessels from pre‐existing ones), cell migration, and vasorelaxation (dilation of blood vessels) thereby preserving cardiovascular health.     

Synthesis and characterisation of CuS nanomaterials using hydrothermal route

Copper sulphide (CuS) nanomaterials with interesting morphology were synthesised using copper nitrate trihydrate, thiourea and water as a solvent by a simple hydrothermal route. A systematic investigation was carried out to investigate the effect of reaction time (5, 16 and 24?h) at 150°C on the morphology of the materials. Without the use of any template or additives, shape controlled synthesis of CuS nanocrystallites were achieved. The possible mechanism for the formation of the various nanostructures of CuS in this system is discussed. The prepared materials were characterised by X-ray diffraction, field emission scanning electron microscopy (FE-SEM) and DRS-UV–Vis absorption analysis. The UV–Vis spectrum shows that it is the promising material which can absorb in the visible region and hence could be used for photocatalytic applications. In addition, the electrochemical characteristic of the synthesised material was investigated by cyclic voltammetric analysis, which shows that CuS could be used for electrocatalytic applications.     

Effects of Drying Temperature and Particle Size on Hydration Properties of Dietary Fiber Powder from Lime and Cabbage By-Products

The use of by-products from fruit and vegetable processing plants as sources of dietary fiber and bioactive agents is currently of interest, both from the waste management and from the production of value-added products points of view. This work aimed at studying the use of lime residues and outer leaves of white cabbage to produce dietary fiber powder, which included the study of the product pretreatment and preparation, drying, and grinding dried residues into powder. Dietary fiber content during each processing step was determined to calculate the loss of functionality of the products through the process. Hydration properties, i.e., water holding capacity (WHC) and swelling capacity (SWC), of the two residues were also determined after hot air drying at 60–80°C. The effect of particle size of dietary fiber powder, which was obtained by grinding dried residues, in the range of 63–450 μm, on the hydration properties was also evaluated and discussed.     

In situ synthesised TiO2 ‐chitosan‐chondroitin 4–sulphate nanocomposites for bone implant applications

The artificial materials for bone implant applications are gaining more importance in the recent years. The series titania‐chitosan‐chondroitin 4–sulphate nanocomposites of three different concentrations (2:1:x, where x ‐ 0.125, 0.25, 0.5) have been synthesised by in situ sol–gel method and characterised by various techniques. The particle size of the nanocomposites ranges from 30–50 nm. The bioactivity, swelling nature, and the antimicrobial nature of the nanocomposites were investigated. The swelling ability and bioactivity of the composites is significantly greater and they possess high zone of inhibition against the microorganisms such as Staphylococcus aureus and Escherichia coli. The cell viability of the nanocomposites were evaluated by using MG‐63 and observed the composites possess high cell viability at low concentration. The excellent bioactivity and biocompatibility makes these nanocomposites a promising biomaterial for bone implant applications.Inspec keywords: titanium compounds, filled polymers, nanocomposites, bone, orthopaedics, biomedical materials, sol‐gel processing, nanofabrication, particle size, swelling, microorganisms, cellular biophysics, nanomedicine, prostheticsOther keywords: in situ synthesised TiO₂ ‐chitosan‐chondroitin 4‐sulphate nanocomposites, bone implant applications, artificial materials, in situ sol‐gel method, particle size, swelling nature, antimicrobial nature, microorganisms, Staphylococcus aureus, Escherichia coli, cell viability, MG‐63, biomaterial, size 30 nm to 50 nm, TiO₂      

Hot Corrosion Behaviour of Detonation-Gun Sprayed Cr3C2–NiCr Coating on Inconel-718 in Molten Salt Environment at 900 °C

Detonation gun sprayed Cr₃C₂–NiCr coating was deposited on nickel-based superalloy Inconel-718. Hot corrosion studies were conducted on uncoated as well as Cr₃C₂–NiCr coated superalloy in 75 wt% Na₂SO₄ + 25 wt% NaCl salt environment at 900 °C for 50 cycles. The thermo-gravimetric technique was used to establish kinetics of corrosion. X-ray diffraction and scanning electron microscopy/energy-dispersive X-ray analysis techniques were used to analyze the corrosion products. The uncoated superalloy suffered intense spalling, while the Cr₃C₂–NiCr coating provided good protection against hot corrosion in the given salt environment.