Photoelectrocatalytic humic acid degradation kinetics and effect of pH,applied potential and inorganic ions

This study addresses the removal of humic acid (HA) dissolved in an aqueous medium by a photoelectrocatalytic process. UV₂₅₄ removal and the degradation of color (Vis₄₀₀) followed pseudo‐first order kinetics. Rate constants were 1.1 × 10^?1 min^?1, 8.3 × 10^?2 min^?1 and 2.49 × 10^?2 min^?1 (R² > 0.97) for UV₂₅₄ degradation and 1.7 × 10^?1 min^?1, 6.5 × 10^?2 min^?1 and 2.0 × 10^?2 min^?1 for color removal from 5 mg dm^?3, 10 mg dm^?3 and 25 mg dm^?3 HA respectively. Following a 2 h irradiation time, 96% of the color, 98% of the humic acid and 85% of the total organic carbon (TOC) was removed from an initial 25 mg dm^?3 HA solution in the photoanode cell. Photocatalytic removal on the same photoanode was also studied in order to compare the two methods of degradation. Results showed that the photoelectrocatalytic method was much more effective than the photocatalytic method especially at high pH values and with respect to UV₂₅₄ removal. The effect of other important reaction variables, eg pH, external potential and electrolyte concentration, on the photoelectrocatalytic HA degradation was also studied. Copyright © 2003 Society of Chemical Industry     

Functional polyamides. 3. Synthesis and chelating properties of a new poly(amide thioether)

Polymerization of β,β′-(ethylenedithio)dipropionitrile

1 IUPAC name: 4,7-dithiadecane dinitrile.

with formaldehyde in the presence of sulfuric acid was carried out in order to permit the synthesis of polymides containing thioether groups. The obtained poly(amide thioether)s were characterized; they coordinate mercury (II) with a high degree of selectivity.     

Topology-Aware Multiple Routing Configurations for Fault Tolerant Networking

Real-time services require reliable and fault tolerant communication networks to support their stringent Quality of Service requirements. Multi Topology Routing based IP Fast Re-route (MT-IPFRR) technologies provide seamless forwarding of IP packets during network failures by constructing virtual topologies (VTs) to re-route the disrupted traffic. Multiple Routing Configurations (MRC) is a widely studied MT-IPFRR technique. In this paper, we propose two heuristics, namely mMRC-1 and mMRC-2, to reduce the number of VTs required by the MRC to provide full coverage for single link/node failures, and hence, to decrease its operational complexity. Both heuristics are designed to construct more robust VTs against network partitioning by taking their topological characteristics into consideration. We perform extensive experiments on 3200 topologies with diverse structural properties using our automated topology generation and analysis tool. Numerical results show that the amount of reductions in VT requirements get higher up to 31.84 %, as the networks tend to have more hub nodes whose degree is much higher than the rest of the network.     

Physical and Mechanical Properties of PP Composites based on Different Types of Lignocellulosic Fillers

The presents preparation and characterization of different types of lignocellulosic fillers (pine wood sawdust/ walnut shell flour/ black rice husk powder) reinforced polypropylene composites were presented. The effect of MAPP as coupling agent (4wt%) on the physical and mechanical properties was also investigated. Polypropylene composites were prepared at different rates of filler/matrix (wt%) by using extrusion (for melt blending) and hot compression molding process. Maximum values of tensile and flexural strength were obtained as 26.1 and 43.4 MPa, respectively, whereas the elongation at break value was 4.11% at 10% pine wood sawdust reinforced PP. Tensile and flexural modulus of composites reached the maximum values as 3855 and 3633 MPa with the composite of 30% walnut shell flour reinforced PP. Characterization of composites was carried out by using tensile test, flexural test, FT-IR, and SEM.     

An overview of recommender systems in the healthy food domain

Recently, food recommender systems have received increasing attention due to their relevance for healthy living. Most existing studies on the food domain focus on recommendations that suggest proper food items for individual users on the basis of considering their preferences or health problems. These systems also provide functionalities to keep track of nutritional consumption as well as to persuade users to change their eating behavior in positive ways. Also, group recommendation functionalities are very useful in the food domain, especially when a group of users wants to have a dinner together at home or have a birthday party in a restaurant. Such scenarios create many challenges for food recommender systems since the preferences of all group members have to be taken into account in an adequate fashion. In this paper, we present an overview of recommendation techniques for individuals and groups in the healthy food domain. In addition, we analyze the existing state-of-the-art in food recommender systems and discuss research challenges related to the development of future food recommendation technologies.     

Transcranial Magnetic Stimulation of the Supplementary Motor Area in the Treatment of Obsessive-Compulsive Disorder: A Multi-Site Study

Recently, strategies beyond pharmacological and psychological treatments have been developed for the management of obsessive-compulsive disorder (OCD). Specifically, repetitive transcranial magnetic stimulation (rTMS) has been employed as an adjunctive treatment in cases of treatment-refractory OCD. Here, we investigate six weeks of low frequency rTMS, applied bilaterally and simultaneously over the sensory motor area, in OCD patients in a randomized, double-blind placebo-controlled clinical trial. Twenty-two participants were randomly enrolled into the treatment (ACTIVE = 10) or placebo (SHAM = 12) groups. At each of seven visits (baseline; day 1 and weeks 2, 4, and 6 of treatment; and two and six weeks after treatment) the Yale-Brown Obsessive Compulsive Scale (Y-BOCS) was administered. At the end of the six weeks of rTMS, patients in the ACTIVE group showed a clinically significant decrease in Y-BOCS scores compared to both the baseline and the SHAM group. This effect was maintained six weeks following the end of rTMS treatment. Therefore, in this sample, rTMS appeared to significantly improve the OCD symptoms of the treated patients beyond the treatment window. More studies need to be conducted to determine the generalizability of these findings and to define the duration of rTMS’ clinical effect on the Y-BOCS. Clinical Trial Registration Number (NCT) at www.clinicaltrials.gov: {"type":"clinical-trial","attrs":{"text":"NCT00616486","term_id":"NCT00616486"}}NCT00616486.     

An experimental investigation on the low velocity impact response of composite plates repaired by VARIM and hand lay-up processes

This paper presents results of an experimental investigation on the impact response of repaired and unrepaired glass/epoxy composite plates. Repaired samples were prepared by two different manufacturing methods; vacuum assisted resin infusion process and hand lay-up technique. In order to compare impact response of the repaired and unrepaired samples a number of single impact tests were performed under various impact energies. Damage process of the samples is analyzed from cross-examining load–deflection curves and damaged specimens. From the visual inspection, for the impacted side of the samples, it is noted that the main damage modes for repaired samples are matrix and fiber cracks around point of impact and delaminations while severe matrix cracks expanded through fiber directions are the dominant damage mode for unrepaired samples. At the back surfaces, delaminations and fiber–matrix debonding oriented in the fiber directions are observed for unrepaired samples. However, for repaired samples the fiber fractures through repair line as well as the delaminations become dominant modes. For a reasoning justification in discussing impact test results, interlaminar fracture toughness (Mode I and Mode II) and flexural tests for repaired and non-repaired samples were also conducted.     

Explanations for over-constrained problems using QuickXPlain with speculative executions

Conflict detection is used in various scenarios ranging from interactive decision making (e.g., knowledge-based configuration) to the diagnosis of potentially faulty models (e.g., using knowledge base analysis operations). Conflicts can be regarded as sets of restrictions (constraints) causing an inconsistency. Junker’s QuickXPlain is a divide-and-conquer based algorithm for the detection of preferred minimal conflicts. In this article, we present a novel approach to the detection of such conflicts which is based on speculative programming. We introduce a parallelization of QuickXPlain and empirically evaluate this approach on the basis of synthesized knowledge bases representing feature models. The results of this evaluation show significant performance improvements in the parallelized QuickXPlain version.

     

Salmonellosis in Indonesia: phage type distribution of Salmonella typhi

The distribution of phage types was studied among 577 strains of Salmonella typhi from Indonesia. Chemotype, colicinogeny, and tetrathionate reductase activity were also studied for most of these strains. The current phage type formula for Java was determined to be: A, D2, D6, E1a, E2, M1, and 46, but two other large groups of strains were also found, I + IV and degraded Vi+ strains. Significant differences in S. typhi strain distributions were noted between two localities on Java with respect to phage type and tetrathionate reductase activity. Comparisons were made with past phage typing studies in Jakarta as well as with more recent studies in other parts of south-east Asia. Phage types A, D1, D2, and E1 persisted at a rather steady level in Jakarta for 28 years. Evidence was found for epidemiological links to European and Asian areas. Antibiotic resistance among these Indonesian S. typhi strains was rare.     

Preparation of multiphase block copolymers by redox polymerization process

Redox polymerization of methylmethacrylate (MMA) using Ce(IV) with poly(oxyethylene) having azo and hydroxy functions was carried out to yield methylmethacrylate-ethylene glycol block copolymers with labile azo linkages in the main chain. These prepolymers were used to initiate the radical polymerization of styrene through the thermal decomposition of the azo group, resulting in the formation of multiblock copolymers. Successful blocking has been confirmed by fractional precipitation, a strong change in the molecular weight distribution and spectral measurements.