NiCoFe/C cathode electrocatalysts for direct ethanol fuel cells

A direct ethanol fuel cell (DEFC), which is less prone to ethanol crossover, is reported. The cell consists of PtRu/C catalyst as the anode, Nafion^® 117 membrane, and Ni–Co–Fe (NCF) composite catalyst as the cathode. The NCF catalyst was synthesized by mixing Ni, Co, and Fe complexes into a polymer matrix (melamine-formaldehyde resins), followed by heating the mixture at 800 °C under inert atmosphere. TEM and EDX experiments suggest that the NCF catalyst has alloy structures of Ni, Co and Fe. The catalytic activity of the NCF catalyst for the oxygen reduction reaction (ORR) was compared with that of commercially available Pt/C (CAP) catalyst at different ethanol concentrations. The decrease in open circuit voltage (V_oc) of the DEFC equipped with the NCF catalysts was less than that of CAP catalyst at higher ethanol concentrations. The NCF catalyst was less prone to ethanol oxidation at cathode even when ethanol crossover occurred through the Nafion^®117 film, which prevents voltage drop at the cathode. However, the CAP catalyst did oxidize ethanol at the cathode and caused a decrease in voltage at higher ethanol concentrations.     

Polymerization of epoxide with aluminum complex/silanol catalyst. VII. Thermal and electrical properties of epoxy resin cured with the new catalyst

Curing catalyst for epoxy resins was newly found. The catalyst consists of aluminum complex and silanol. Lack of one component of the pair does not cure epoxy resins. The epoxy resins cured with the catalyst are characterized by excellent electrical properties, especially at high temperature, due to the absence of strong acid species in the cured epoxy resin matrix. Heat-resistant property of the resin was also excellent. These properties were compared with those of epoxy resin cured with commonly used BF₃ complex.     

个旧有色冶化公司一期低浓度铜烟气制酸工程简介

介绍90 kt/a铜冶炼烟气制酸装置的设计和运行情况。采用三段式净化工艺与污水处理系统相结合, 有效地解决了用高砷、氟铜精砂生产硫酸的问题。采用多孔板支撑缩放管气体换热器与高蓄热能力的转化器相结合,在转化器进口平均φ(SO2)约4％,而生产负荷仅为设计能力(270t/d)的74％的条件下,转化系统仍能维持自热平衡。     

抛物问题Mortar有限元的瀑布型多重网格法

对抛物问题的全离散格式采用Mortar型有限元逼近,构造了相应的瀑布型多重网格法,证明了该方法的最优性.     

非线性等式与不等式问题的信赖域算法

５１．引言 本文讨论如下非线性等式与不等式问题的求解问题：其中,吐。）是＊”＋Ｂ的连续可微函数． 非线性问题（１．１）广泛出现于优化问题、互补问题及变分不等式等应用数学领域中,因而对其算法的研究也是计算数学的一个重要部分．许多作者考察了该问题的求解,如Ｄｅｎｎｉｓ和Ｓｃｈｎａｂｅ［６］, Ｐｓｈｅｎｉｃｈｌｌｙｉ［９］, Ｒｏｂｉｎｓｏｎ［１０１等人讨论了该问题的牛顿法求解,梯度法求解,Ｂｕｒｋｅ和 Ｈａｎ［‘］讨论了高斯一牛顿法求解． Ｄｅｎｎｉｓ在［５］中首次采用了信赖域算法的求解,［５］中通过引…     

OBDDs of a Monotone Function and Its Prime Implicants

Coudert made a breakthrough in the two-level logic minimization problem with Ordered Binary Decision Diagrams (OBDDs for short) recently [3]. This paper discusses the relationship between the two OBDDs of a monotone function and its prime implicant set to clarify the complexity of this practically efficient method. We show that there exists a monotone function which has an O(n) size sum-of-products but cannot be represented by a polynomial size OBDD. In other words, we cannot obtain the OBDD of the prime implicant set of a monotone function in an output-size sensitive manner once we have constructed the OBDD of that function as in [3], in the worst case. A positive result is also given for a meaningful class of matroid functions. Received April 1997, and in revised form December 1997, and in final form February 1998.     

Cutting Force Model for a Small-diameter Helical Milling Cutter

In the milling process, the major flank wear land area (two-dimensional measurement for the wear) of a small-diameter milling cutter, as wear standard, can reflect actual changes of the wear land of the cutter. By analyzing the wearing characteristics of the cutter, a cutting force model based on the major flank wear land area is established. Characteristic parameters such as pressure parameter and friction parameter are calculated by substituting tested data into their corresponding equations. The cutting force model for the helical milling cutter is validated by experiments. The computational and experimental results show that the cutting force model is almost consistent with the actual cutting conditions. Thus, the cutting force model established in the research can provide a theoretical foundation for monitoring the condition of a milling process that uses a small-diameter helical milling cutter.     

基于事例推理技术在火炮设计中的应用

从基于事例推理技术理论出发,在Ｎａｖｉｎｃｈａｎｄｒａ、Ｂａｒｄａｓｚ、ＺｅｉｄＩ）等学者提出的设计事例表示方法基础上提出更为通用、有效的设计事例表示形式,即设计事例３级表示方法和它的组织结构,并结合火炮总体设计的具体特点,给出火炮总体设计事例表示形式定义、组织及推理策略,以及火炮设计专家系统模型。通过研究表明,采用事例形式的知识表示可以有效地利用火炮设计经验,提高火炮设计质量、缩短周期,有力地推     

实现机床颤振早期诊断的一个新的特征量

本文通过大量试验信号的互谱分析,找出了颤振建立过程中切削力和振动加速度信号互谱的特征变化:主频带的移动及其相位差的变化.然后,基于互谱与互相关函数的关系.分析了一步互相关系数的变化与互谱上述两种特征变化的内在联系.从而可将一步互相关系数作为机床颤振早期诊断的一个特征量.试验结果表明,该特征量是有效的.