Unsaturated elasto-plastic constitutive equations for compacted kaolin under consolidated drained and shearing-infiltration conditions

Transient process of water flow changes the equilibrium conditions of an unsaturated soil, resulting in volume change of a soil. The volume change alters the hydraulic properties of the soil and thus influences the transient process of water flow through the soil. Therefore, the interactive processes between stress-strain behavior and pore-water pressure are the primary processes affecting the mechanical behavior of unsaturated soils. This paper presents coupled elasto-plastic constitutive equations for unsaturated compacted kaolin under consolidated drained and shearing-infiltration conditions. The study focused on the development of the suction increase (SI) yield curve that incorporates changes in matric suction during transient processes. In addition, the relationship of change in specific water volume with respect to net mean stress and matric suction was also proposed by incorporating the hysteresis of soil-water characteristic curve. The simulated results by the proposed constitutive model were compared with those obtained from isotropically consolidated drained tests and shearing infiltration tests of compacted kaolin to verify the proposed model. The simulated results are in close agreement with the experimental results.     

Effect of different soaking and germination methods on bioactive compounds of germinated brown rice

Germination of brown rice can be completed by full soaking and partial soaking methods. This study aimed to analyse the influence of germination methods on the bioactive accumulations in germinated brown rice (GBR). Germination was conducted in four treatments: (i) membrane reactor with full (RFS) and (ii) partial soaking method soaking (RAG), (iii) manual soaking for complete germination (MFS) and (iv) partial manual soaking in combination with atmospheric germination (MAG). The results showed that soaking BR in membrane reactor accelerated the shoots' growth and increased GABA (γ-aminobutyric acid) content compared with the manual soaking method. The RAG treatment achieved higher GABA content (up to 125 mg/100 g), total phenolic and flavonoid content, and antioxidant activity than other germination methods. The main finding of this research indicates that membrane reactor effectively enhances the growth of sprouts. The combination of partial soaking in membrane reactor and atmospheric germination (RAG) is a suited method to increase GABA accumulation in GBR.     

Effects of Groundwater Table Position and Soil Properties on Stability of Slope during Rainfall

Rainfall, hydrological condition, and geological formation of slope are important contributing factors to slope failures. Parametric studies were carried out to study the effect of groundwater table position, rainfall intensities, and soil properties in affecting slope stability. Three different groundwater table positions corresponding to the wettest, typical, and driest periods in Singapore and four different rainfall intensities (9, 22, 36, and 80 mm/h) were used in the numerical analyses. Typical soil properties of two main residual soils from the Bukit Timah Granite and the sedimentary Jurong Formation in Singapore were incorporated into the numerical analyses. The changes in factor of safety during rainfall were not affected significantly by the groundwater table near the ground surface due to the relatively small changes in matric suction during rainfall. A delay in response of the minimum factor of safety due to rainfall and a slower recovery rate after rainfall were observed in slopes from the sedimentary Jurong Formation as compared to those slopes from the Bukit Timah Granite. Numerical analyses of an actual residual soil slope from the Bukit Timah Granite at Marsiling Road and a residual soil slope from the sedimentary Jurong Formation at Jalan Kukoh show good agreement with the trends observed in the parametric studies.     

Shear Strength Equations for Unsaturated Soil under Drying and Wetting

Shear strength of unsaturated soil is an important engineering property in various geotechnical designs. In response to varying climatic conditions, unsaturated soil behaves differently under the drying and wetting processes due to hysteresis. Many research works were conducted and numerous equations were proposed for unsaturated shear strength, however, most of them were limited to the soil under the drying process. In this study, shear strength equations were categorized according to the nature of equation, i.e., fitting and prediction type equations. The purpose of this study is to propose prediction type shear strength equations for unsaturated soil under drying and wetting. Twelve published shear strength equations were selected for evaluation. A series of unsaturated consolidated drained triaxial tests were conducted on statically compacted sand-kaolin specimens under drying and wetting to examine the validity of the proposed equations. The experimental results indicated that the specimens on the drying path had a higher shear strength and exhibited more ductility, less stiffness, and contraction during shearing while the specimens on the wetting path had a lower shear strength and exhibited more brittleness, more stiffness, and dilation during shearing. The proposed equations were shown to provide the best predictions on the drying and wetting shear strength results from this study as well as published data in the comparison study.     

Effect of NaBF4 addition on the anodic synthesis of TiO2 nanotube arrays photocatalyst for production of hydrogen from glycerol–water solution

Addition of NaBF₄ during anodic synthesis of TiO₂ nanotube arrays (TNTAs) photocatalyst and its application for generating hydrogen from glycerol–water solution has been investigated. The TNTAs were synthesized by anodic oxidation of titanium metal in glycerol electrolyte solution containing NH₄F. During the process, the NaBF₄ with different concentrations were added to the solution. Annealing of the formatted TNTAs were performed at 500 °C for 3 h under 20% H₂ in argon atmosphere, to produce crystalline phase photocatalyst. FESEM analysis showed that self-organized and well ordered TNTAs have range of inner diameters, wall thicknesses and lengths approximately 62–130 nm, 27 nm and 1.53 μm, respectively. FTIR analysis indicated that carbon, nitrogen and boron were incorporated into the TNTAs lattice. Refer to UV–Vis DRS and XRD analysis, the TNTAs photocatalysts prepared have the band gap range of 2.70–3.10 eV, with mostly have anatase phase. The NaBF₄ addition during synthesis, resulted modified TNTAs that can reduce the recombination of photo-induced electrons-holes. Photocatalytic hydrogen production test, from glycerol–water solution, indicated that TNTAs with the addition of NaBF₄ during anodic synthesis process showed higher hydrogen production comparing to the one without NaBF₄ addition. Among them the TNTAs,b (with the addition 5 mM of NaBF₄) showed up to 32% improvement in the hydrogen production and can be considered as the optimum condition.     

Concomitant extracellular accumulation of alpha-keto acids and higher alcohols by Zygosaccharomyces rouxii

Alpha-keto acids are key intermediates in the formation of higher alcohols, important flavor components in soy sauce, and produced by the salt-tolerant yeast Zygosaccharomyces rouxii. Unlike most of the higher alcohols, the alpha-keto acids are usually not extracellularly accumulated by Z. rouxii when it is cultivated with ammonium as the sole nitrogen source. To facilitate extracellular accumulation of the alpha-keto acids from aspartate-derived amino acid metabolism, the amino acids valine, leucine, threonine and methionine were exogenously supplied during batch and A-star cultivations of (routants of) Z. rouxii. It was shown that all alpha-keto acids from the aspartate-derived amino acid metabolism, except alpha-ketobutyrate, could be extracellularly accumulated. In addition, it appeared from the concomitant extracellular accumulation of alpha-keto acids and higher alcohols that in Z. rouxii, valine, leucine and methionine were converted via Ehrlich pathways similar to those in Saccharomyces cerevisiae. Unlike these amino acids, threonine was converted via both the Ehrlich and amino acid biosynthetic pathways in Z. rouxii.     

Shear Strength of Compacted Soil under Infiltration Condition

Landslides in residual soil slopes are commonly induced by rainfall infiltration. These residual soils are typically in an unsaturated state with negative pore-water pressures or matric suctions since the groundwater tables in steep slopes are often deep. The net normal and shear stresses of the soil remain essentially constant during rainwater infiltration into the slope. Failure of the slope during rainfall can be primarily associated with the decrease in the matric suction of the soil. The objective of the study was to investigate the strength and deformation characteristics of a residual soil of the Bukit Timah Granitic Formation during infiltration that leads to slope failure. There were two modified direct shear apparatuses used. One apparatus was used for the determination of shear strength under controlled suction conditions while the other apparatus was used for shearing-infiltration tests. The shearing-infiltration test results were compared with the shear strength values obtained from the shearing tests under constant suction. The shearing-infiltration test results indicate a close relationship between the decreasing matric suction and the increasing displacement rate of the soil specimen. At the initial part of the infiltration process, there is a rapid reduction in matric suction that is accompanied by little movement in the soil. When failure of the soil is imminent, the soil movement will accelerate.     

The phytate and phytase of soybean tempeh

Soybeans were fermented into tempeh by Rhizopus oligosporus NRRL 2710. The phytic acid content of soybeans was reduced by about one-third as a result of this fermentation, while an equivalent amount of phosphate was released in the tempeh. The reduction of phytic acid was due to phytase elaborated by the mould of the fermentation. The pH optimum of this enzyme was 5.6 and the K_m of the phytase-phytate reaction was 0.28 × 10^?3 M.     

非饱和土孔隙气、水、汽、热耦合运动之模拟(英文)

旨在介绍一个描述非饱和土孔隙气、水、汽、热耦合运动的理论模型。该模型假定孔隙气和孔隙水运动分别遵循达西定律 ,而影响水蒸汽运动的两种主要因素分别是分子扩散和孔隙气运动 ,其中受分子扩散影响的孔隙水蒸汽运动可用Fick定律描述。热转移则主要包括了三种形式 ,即传导、对流和汽化潜热。根据有限单元法 ,编制了一个三维的计算机程序用以模拟非饱和土孔隙气、水、汽、热的耦合运动。通过数值分析与干沙试验结果之比较 ,验证了文中之理论模型和计算机程序的可靠性