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排序方式: 共有440条查询结果,搜索用时 234 毫秒
1.
An increase in hydrogen evolution from the hydrogen-evolving enzyme in the actinomycete Frankia was recorded in the presence of nickel. Immunogold localisation analysis of the intracellular distribution of hydrogenase proteins indicated that they were evenly distributed in the membranes and cytosol of both hyphae and vesicles. In addition, molecular characterisation of the hydrogen-evolving enzyme at the proteomic level, using two-dimensional gel electrophoresis combined with mass spectrometry, confirmed that the Frankia hydrogen-evolving enzyme is similar to the cyanobacterial bidirectional hydrogenase of Anabena siamensis. 相似文献
2.
3.
The dielectric behavior of sol-gel derived Ba0.80Sr0.20(ZrxTi1−x)O3 (0.0 ≤ x ≤ 0.50) thin films is studied. A relaxor behavior is observed for x ≥ 0.35. The degree of relaxation increases with Zr content. The frequency dependence of the polar regions follows Vogel-Fulcher relation with a characteristic cooperative freezing at freezing temperature (Tf). Below Tf, a long range polarization ordering is likely to take place. The plausible mechanism of the relaxor behavior of BSZT thin films with Zr contents ≥ 0.35 has been proposed based on the measured temperature as well as frequency dependent dielectric data. The solid solution system is visualized as a mixture of Ti+ 4 rich polar regions and Zr+ 4 rich regions; with the increase in Zr content the volume fraction of the polar regions is progressively reduced. At and above 35.0 at.% Zr substitution the polar regions exhibit typical relaxor behavior. 相似文献
4.
Name resolution using the Domain Name System (DNS) is integral to today’s Internet. The resolution of a domain name is often dependent on namespace outside the control of the domain’s owner. In this article we review the DNS protocol and several DNS server implementations. Based on our examination, we propose a formal model for analyzing the name dependencies inherent in DNS. Using our name dependency model we derive metrics to quantify the extent to which domain names affect other domain names. It is found that under certain conditions, more than half of the queries for a domain name are influenced by namespaces not expressly configured by administrators. This result serves to quantify the degree of vulnerability of DNS due to dependencies that administrators are unaware of. When we apply metrics from our model to production DNS data, we show that the set of domains whose resolution affects a given domain name is much smaller than previously thought. However, behaviors such as using cached addresses for querying authoritative servers and chaining domain name aliases increase the number and diversity of influential domains, thereby making the DNS infrastructure more vulnerable. 相似文献
5.
Silicon - The primary purpose of this work is to study the effect of symmetric and asymmetric variation of underlap regions both on source and drain side of 3D SOI n-FinFET. Underlap length is... 相似文献
6.
The present paper deals with the extraction of cobalt from a solution containing cobalt and nickel in a sulphate medium similar
to the leach liquor obtained by the dilute sulphuric acid pressure leaching of the Pacific Ocean nodules matte followed by
copper extraction. The commercial extractant Cyanex 272 (bis (2, 4, 4-trimethylpentyl) phosphinic acid) is used for this purpose.
The leach liquor used for the present study contains Co =1.78 g/L and Ni=16.78 g/L. Before cobalt extraction, impurities,
such as copper and iron, are removed from the leach liquor by the precipitation method. Increasing the concentration of Cyanex
272 increased the extraction percentage of cobalt due to the increase of equilibrium pH. Cobalt extraction efficiency of >99.9
% is achieved with 0.20 M Cyanex 272 in two counter-current stages at an aqueous: organic (A:O) phase ratio of 1.5∶1. Complete
stripping of cobalt from the loaded organic containing 2.73 g/L Co was carried out at pH 1.4 by a synthetic cobalt spent electrolyte
in two stages at an A:O ratio of 1∶2. The enrichment of cobalt during extraction and stripping operations was about 3.5 times.
A complete process flowsheet for the separation and recovery of cobalt is presented. 相似文献
7.
Isomorphously substituted cobalt(II) hexagonal mesoporous aluminophosphate (CoHMA) molecular sieves were synthesized hydrothermally and characterized by various analytical and spectroscopic techniques. It was deduced that cobalt ions exhibit a divalent oxidation state in tetrahedral coordination in mesoporous aluminophosphates. Further, unlike cobalt-containing microporous aluminophosphate molecular sieves, Co(II) ions remain in a tetrahedral geometry even after calcination. The catalytic activity of CoHMA was tested for the cyclohexane oxidation reaction under mild conditions. Remarkable substrate conversion and product (cyclohexanol) selectivity were obtained compared to several previously reported heterogeneous catalysts. 相似文献
8.
In this work, one step process of synthesis of silver nanoparticles (Agnp) embedded in insitu formed calcium alginate (CA) beads is stated. CA, formed from the reaction between sodium alginate and calcium hydroxide, acts as reducing and stabilizing agent as well as support for nanoparticles. The reaction mechanism for the formation and stabilization of Agnp is proposed where the vicinal dihydroxy groups of alginate are assumed to act as the reducing agent for Ag+ to Ag°. Transmission electron microscopy (TEM), x‐ray diffraction (XRD), UV‐vis spectroscopy, field emission scanning electron microscopy (FESEM), and atomic absorption spectroscopy (AAS) were used to characterize the Agnp. The formation of spherical nanoparticles with average size range of 4‐5 nm was confirmed by TEM. Catalytic activity of this nano silver‐calcium alginate (Agnp‐CA) composite was evaluated in the reduction of p‐nitrophenol. Concentrations of sodium alginate, calcium hydroxide, and AgNO3 are found to be the parameters that critically affect the synthesis of Agnp. The efficacy of the catalyst is expressed on the basis of suitable reaction parameters. Both pseudo‐homogeneous and heterogeneous kinetic models are proposed for the reaction to find the best model and the Eley‐Riedel model is found to fit well with the experimental data. The novelty of this work is that the tandem process of CA bead formation, Agnp formation, and Agnp entrapment in CA have been transformed into a single‐step process. Moreover, elaborations of each step of the ionic mechanisms of Agnp formation and p‐NP reduction with Agnp and the establishment of a heterogeneous kinetic model for the reaction are reported for the first time here. 相似文献
9.
Selin Sagbas Suner Subhra Mohapatra Ramesh S. Ayyala Venkat R. Brethanabotla Nurettin Sahiner 《应用聚合物科学杂志》2021,138(24):50576
Catechin (CAT) was crosslinked with trimethylolpropane triglycidyl ether (TMPTGE) to obtain degradable poly(CAT) particles in a single step. Spherical p(CAT) particles with tens of micrometer size range and an isoelectronic point at pH 1.2 were obtained. The hydrolytic degradation of p(CAT) particles provided sustainable and extended release with 264 mg/g CAT release within 10 days at pH 7.4. The antioxidant capacity of 55.0 ± 0.9 μg/ml gallic acid equivalent in terms of total phenol content, and 0.88 ± 0.3 μmol/g trolox equivalent were estimated for p(CAT) particles displaying strong radical scavenging capability. Blood clotting and hemolysis assays demonstrated dose-dependent blood compatibility revealing higher blood compatibility for p(CAT) particles up to 10 μg/ml concentration. The cytotoxicity results show that p(CAT) particles have almost no toxicity for CCD841 normal colon cells at 250 μg/ml concentration in 24 h incubation time giving ~97% cell viability, whereas CAT molecules only provide ~34% cell viability. 相似文献
10.
Arun K. Ray Mamata Jenamani Pratap K.J. Mohapatra 《Expert systems with applications》2011,38(5):4689-4697
Behavioral uncertainty of a supplier is a major challenge to a buyer operating in e-procurement setting. Modeling suppliers’ behavior from past transactions, estimation of possible future performance and integrating this knowledge with the winner determination process can bring a new dimension to procurement process automation. We propose a states-space model to capture the uncertainty involved in long-term supplier behavior. The states represent the performance level of a supplier. This behavioral aspect is then integrated with the winner determination process of a multi-attribute reverse auction for efficient supplier selection using parallel MDP. We also propose an implementation framework to collect the feedback on supplier, generate an aggregate performance score and integrate it with the winner determination process. The performance aggregation and winner determination with help of Markov decision process effectively uses the past performance information. In addition, it updates performance information in regular invervals and allevates the problem of maintaining a long history. We compare the MDP-based selection with that of performance score-based selection through a simulation experiment. It is observed that our scheme gives better buyer utility, selects best suppliers and fetches better quality product. The benefits realized through these attributes to the buyer increases the efficiency of the MDP-based selection process. 相似文献