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1.
In the present research, nanostructured Pd–Cd alloy electrocatalysts with different compositions were produced using the electrodeposition process. The morphology of the samples was studied by scanning electron microscopy analysis. Also, the elemental composition of the samples was determined by energy-dispersive X-ray spectroscopy and elemental mapping tests. Tafel polarization and electrochemical impedance spectroscopy methods were employed to determine the electrochemical corrosion properties of the synthesized samples in a solution containing 0.5 M sulfuric acid and 0.1 M formic acid. The linear sweep voltammetry, cyclic voltammetry, and chronoamperometry techniques were also employed to evaluate the electrocatalytic activity of prepared samples toward the oxidation of formic acid. In this respect, the influence of some factors such as formic acid and sulfuric acid concentrations and also potential scan rate was investigated. Compared to the pure Pd sample, the Pd–Cd samples were more reactive for the oxidation of formic acid. Besides, the sample with a lower amount of Pd (Pd1·3Cd) demonstrated much higher electrocatalytic activity than the Pd7·1Cd and Pd2·1Cd samples. The observed high mass activity of 15.06 A mg?1Pd for the Pd1·3Cd sample which is 21.1 times higher than Pd/C is an interesting result of this study. 相似文献
2.
Epoxy novolac/anhydride cure kinetics has been studied by differential scanning calorimetry under isothermal conditions. The system used in this study was an epoxy novolac resin (DEN431), with nadic methyl anhydride as hardener and benzyldimethylamine as accelerator. Kinetic parameters including the reaction order, activation energy and kinetic rate constants, were investigated. The cure reaction was described with the catalyst concentration, and a normalized kinetic model developed for it. It is shown that the cure reaction is dependent on the cure temperature and catalyst concentration, and that it proceeds through an autocatalytic kinetic mechanism. The curing kinetic constants and the cure activation energies were obtained using the Arrhenius kinetic model. A suggested kinetic model with a diffusion term was successfully used to describe and predict the cure kinetics of epoxy novolac resin compositions as a function of the catalyst content and temperature. Copyright © 2003 Society of Chemical Industry 相似文献
3.
We consider the problem of scheduling jobs on related machines owned by selfish agents. We provide a 5-approximation deterministic
truthful mechanism, the first deterministic truthful result for the problem. Previously, Archer and Tardos showed a 2-approximation
randomized mechanism which is truthful in expectation only (a weaker notion of truthfulness). In case the number of machines
is constant, we provide a deterministic Fully Polynomial-Time Approximation Scheme (FPTAS) and a suitable payment scheme that
yields a truthful mechanism for the problem. This result, which is based on converting FPTAS to monotone FPTAS, improves a
previous result of Auletta et al., who showed a (4 + ε)-approximation truthful mechanism. 相似文献
4.
Christian Azar 《Energy》1994,19(12):1255-1261
Haraden's model for estimating the economic cost of global warming is analysed. We change his method of discounting and some of his input parameters in a manner consistent with physical and economic theory as well as empirical data. We then find much higher costs than Haraden found. These costs are compared to the cost of reducing CO2 emissions and we find that deep cuts of the emissions of CO2 are preferable. A check of the sensitivity of our results with respect to some crucial parameter values does not alter that conclusion. 相似文献
5.
6.
Sten Kaiser 《International Journal of Fracture》1985,29(2):85-99
The stability of a cracked, nonlinear component connected to an elastic structure and subjected to an arbitrary number of
controlled loads or displacements, is discussed. First this is done with a general instability criterion expressed in terms
of loads and displacements of the cracked part. Then general expressions for the tearing modulus are given for different loading
situations. Finally the given equations are applied to SEN specimens under bending and tension.
Résumé On discute de la stabilité d'un composant fissuré et non linéaire assemblé à une structure élastique et soumis à un monbre quelconque de charges ou de déplacements, appliqués dans des conditions connues. Ceci est réalisé en faisant appel, en premier lieu, à un critère général d'instabilité exprimé en termes the sollicitation et de déplacement de la portion fissurée. Ensuite, on fournit des expressions générales pour le module d'arrachement, correspondant à diverses situations de mise en charge. Enfin, les équations obtenues sont appliquées à des éprouvettes à entaille latérale simple soumises à flexion et traction.相似文献
7.
Katarzyna Jasieniecka-Gazarkiewicz Kamil Demski Satinder K. Gidda Sylwia Kliska Janusz Niedojado Ida Lager Anders S. Carlsson Elena A. Minina Robert T. Mullen Peter V. Bozhkov Sten Stymne Antoni Bana 《International journal of molecular sciences》2021,22(6)
Arabidopsis thaliana possesses two acyl-CoA:lysophosphatidylethanolamine acyltransferases, LPEAT1 and LPEAT2, which are encoded by At1g80950 and At2g45670 genes, respectively. Both single lpeat2 mutant and double lpeat1 lpeat2 mutant plants exhibit a variety of conspicuous phenotypes, including dwarfed growth. Confocal microscopic analysis of tobacco suspension-cultured cells transiently transformed with green fluorescent protein-tagged versions of LPEAT1 or LPEAT2 revealed that LPEAT1 is localized to the endoplasmic reticulum (ER), whereas LPEAT2 is localized to both Golgi and late endosomes. Considering that the primary product of the reaction catalyzed by LPEATs is phosphatidylethanolamine, which is known to be covalently conjugated with autophagy-related protein ATG8 during a key step of the formation of autophagosomes, we investigated the requirements for LPEATs to engage in autophagic activity in Arabidopsis. Knocking out of either or both LPEAT genes led to enhanced accumulation of the autophagic adaptor protein NBR1 and decreased levels of both ATG8a mRNA and total ATG8 protein. Moreover, we detected significantly fewer membrane objects in the vacuoles of lpeat1 lpeat2 double mutant mesophyll cells than in vacuoles of control plants. However, contrary to what has been reported on autophagy deficient plants, the lpeat mutants displayed a prolonged life span compared to wild type, including delayed senescence. 相似文献
8.
Performance analysis of support vector machines classifiers in breast cancer mammography recognition
Support vector machine (SVM) is a supervised machine learning approach that was recognized as a statistical learning apotheosis for the small-sample database. SVM has shown its excellent learning and generalization ability and has been extensively employed in many areas. This paper presents a performance analysis of six types of SVMs for the diagnosis of the classical Wisconsin breast cancer problem from a statistical point of view. The classification performance of standard SVM (St-SVM) is analyzed and compared with those of the other modified classifiers such as proximal support vector machine (PSVM) classifiers, Lagrangian support vector machines (LSVM), finite Newton method for Lagrangian support vector machine (NSVM), Linear programming support vector machines (LPSVM), and smooth support vector machine (SSVM). The experimental results reveal that these SVM classifiers achieve very fast, simple, and efficient breast cancer diagnosis. The training results indicated that LSVM has the lowest accuracy of 95.6107 %, while St-SVM performed better than other methods for all performance indices (accuracy = 97.71 %) and is closely followed by LPSVM (accuracy = 97.3282). However, in the validation phase, the overall accuracies of LPSVM achieved 97.1429 %, which was superior to LSVM (95.4286 %), SSVM (96.5714 %), PSVM (96 %), NSVM (96.5714 %), and St-SVM (94.86 %). Value of ROC and MCC for LPSVM achieved 0.9938 and 0.9369, respectively, which outperformed other classifiers. The results strongly suggest that LPSVM can aid in the diagnosis of breast cancer. 相似文献
9.
Microsomes of developing soya bean cotyledons transfer oleate from oleoyl-CoA to phosphatidylcholine (PC) by two different
mechanisms: one in which oleate transfer is accompanied by the release of free CoA and another which results in the exchange
of oleate from oleoyl-CoA for unsaturated 18-carbon fatty acids of PC. The acyl exchange can be demonstrated only when bovine
serum albumin is present in the incubation medium. ATP-dependent acyl-CoA synthetase is not involved in the exchange process,
which apparently does not require any cofactors. In light of this exchange process, the oleate desaturase system was reinvestigated
in order to determine what the actual substrate for this system is. Upon incubation of microsomes with high concentrations
of [14C] oleoyl-CoA, bovine serum albumin and NADH, it could be conclusively demonstrated that most oleic acid is desaturated while
part of the PC molecule. The amounts of [14C] linoleoyl-CoA formed could be explained entirely by the acyl exchange. The physiological significance of the acyl exchange
system is discussed. A new method for separation of acyl-CoA from other lipids and free CoA using reversed phase column chromatography
also is described. 相似文献
10.
Maureen Bafor Allan Keith Stobart Sten Stymne 《Journal of the American Oil Chemists' Society》1990,67(4):217-225
Microsomal membrane preparations from the developing seeds of safflower (Carthamus tinctorius, var. Gila) and turnip-rape (Brassica campestris, var. Bele) catalyzed the assembly of triacylglycerols (triglycerides) from sn-glycerol 3-phosphate and acyl-CoA. The membrane
preparations were used to assess the acyl specificity properties of the initial acylating enzymes—glycerol 3-phosphate acyltransferase
(GPAT) and 1-acylglycerol 3-phosphate acyltransferase (lysophosphatidic acid acyltransferase, LPAAT)—that are responsible
for the fatty acids at positions sn-1 and sn-2 of the sn-triacylglycerol, respectively. In spectrophotometric assays it was
possible to evaluate, to some extent, how these enzymes will utilize unusual and foreign fatty acids that are not normally
found in these particular plant species. The acylating enzymes from both plants used, to varying extents, a comprehensive
range of acyl-CoA donor species and some kinetic properties of the substrates involved are presented. The enzymes from safflower,
however, were generally the more selective, whereas the turnip-rape was less particular and could utilize a range of acyl
substrates. The enzymes from both plants hardly utilized erucate (C22∶1), and the significance of this is discussed in terms
of mechanisms which have evolved in order to exclude certain, perhaps detrimental, fatty acids from structural membrane lipids
and dedicate them to storage lipid assembly.
The ability of the microsomal preparations, from the developing seeds of both plants, to synthesize cocoabutter type fats
was investigated. Microsomal membranes were incubated with glycerol 3-phosphate and equimolar amounts of palmitate, oleate
and stearate. Safflower preparations catalyzed the construction of sn-triacylglycerol with largely palmitate, oleate and stearate
in positions sn-1, 2 and 3, respectively. The selectivity for acyl species in rape was less pronounced, however, substantial
saturated-unsaturated-saturated oils were still produced. The results are discussed in terms of the acyl selectivity properties
of the glycerol acylating enzymes. It is evident that given the correct composition of fatty acids, the plant can produce
cocoabutter or other exotic fats. 相似文献