Silicon Nitride Derived from an Organometallic Polymeric Precursor: Preparation and Characterization

Partially crystalline Si₃N₄, with nanosized crystals and a specific surface area greater than 200 m²/g, is obtained by pyrolysis of a commercially available vinylic polysilane in a stream of anhydrous NH₃ to 1000°C. This polymer does not contain N initially. Crystallization to high-purity α-Si₃N₄ proceeds with additional heating above 1400°C under N₂. The changes in crystallinity, powder morphology, infrared spectra, and elemental compositions, for samples annealed from 1000° to 1600°C under N₂, are consistent with an amorphous-to-crystalline transformation. Although macroscopic consolidation and local densification occur at 1400°C, volatilization and accompanying weight loss limit bulk densification. The effect of temperature on specific surface area is examined and related to the sintering process. These results are applicable to pyrolysis, decomposition, and crystallization studies of ceramics synthesized by polymeric precursor routes.     

Cement mortar impregnated with poly(methyl methacrylate-co-styrene)

Polymer-impregnated mortars were prepared by copolymerization of a monomer mixture of methyl methacrylate and styrene in the ratios of 13:87 and 40:60 using Co-60 gamma radiation. The copolymerization characteristics viz. the rate of polymerization, the extent of monomer loss, polymer loading, etc., were studied. The nature and molecular weight of the extractable polymer from the composite were determined. The flexural strength of the copolymer-impregnated composites was found to be better than that of the composites impregnated with component homopolymers.     

New block copolymers II. Synthesis and characterization of an ABA-type block copolymer

A new regular ABA-type triblock copolymer has been synthesized by polycondensation of the acid chloride of carboxy-terminated butadience-acrylonitrile rubber (CTBN) with hydroxyterminated polyethylene isophthalate (PEI) oligomer. This block copolymer was characterized by elemental (nitrogen) analysis, vapor pressure osmometry, viscometry, and IR and NMR spectroscopy. Quantitative estimation of block segments has been carried out by measuring the area under peaks assigned to various protons in the NMR spectrum of the polymer. NMR spectral analysis has been found to agree well with the nitrogen analysis of the polymer. The solubility and solution viscosity behavior of the polymer has also been studied.     

Removal of Cr(VI) using co-immobilized activated carbon and <Emphasis Type="Italic">Bacillus subtilis</Emphasis>: fixed-bed column study

Fixed-bed column studies were conducted to evaluate the potential of co-immobilized (activated carbon and Bacillus subtilis) (CI) beads for the removal of Cr(VI) from aqueous solution. The impact of various parameters such as initial Cr(VI) concentrations (100, 150, and 200 mg/L), flow rate (3, 9, and 15 mL/min), and bed depth (10, 15, and 20 cm) on Cr(VI) adsorption onto CI beads were investigated. The breakthrough time increased with a decrease in initial Cr(VI) concentration and flow rate, and an increase in bed height. The breakthrough data obtained for Cr(VI) removal was more adequately described by the Thomas model with high correlation coefficients (R ² = 0.982). The eluent, 0.1 M NaOH, provided high elution efficiencies (~90 %) in all the six cycles. Obtained results pointed out that CI beads could potentially be used for the removal of Cr(VI) from aqueous solution.     

Fault containment in weakly stabilizing systems

Research on fine tuning stabilization properties has received attention for more than a decade. This paper presents probabilistic algorithms for fault containment. We demonstrate two exercises in fault containment in a weakly stabilizing system, which expedite recovery from single failures, and confine the effect of any single fault to the constant-distance neighborhood of the faulty process. The most significant aspect of the algorithms is that the fault gap, defined as the smallest interval after which the system is ready to handle the next single fault with the same efficiency, is independent of the network size. We argue that a small fault gap increases the availability of the fault-free system.     

Partition of unity enrichment for bimaterial interface cracks

Partition of unity enrichment techniques are developed for bimaterial interface cracks. A discontinuous function and the two‐dimensional near‐tip asymptotic displacement functions are added to the finite element approximation using the framework of partition of unity. This enables the domain to be modelled by finite elements without explicitly meshing the crack surfaces. The crack‐tip enrichment functions are chosen as those that span the asymptotic displacement fields for an interfacial crack. The concept of partition of unity facilitates the incorporation of the oscillatory nature of the singularity within a conforming finite element approximation. The mixed‐mode (complex) stress intensity factors for bimaterial interfacial cracks are numerically evaluated using the domain form of the interaction integral. Good agreement between the numerical results and the reference solutions for benchmark interfacial crack problems is realized. Copyright © 2004 John Wiley & Sons, Ltd.     

Study of a simulated stream machine for dataflow computation

In this paper, a stream-based dataflow architecture is proposed, and its simulation model, which has helped to evaluate the effectiveness of the proposed architectural concept, is discussed. The machine integrates the conventional Von Neumann type of control flow subsystem with a dataflow processing element of token storage type. The control flow unit tackles the dynamic nature of the stream structure including input/output whereas the dataflow unit does the computation part in an applicative style. A pipelined version of the stream machine is also discussed. The effectiveness of the machine is studied by running a few example programs in the simulated machine. The machine is expected to be useful in real time signal processing applications.     

A Case Study on Optimization of Biomass Flow During Single-Screw Extrusion Cooking Using Genetic Algorithm (GA) and Response Surface Method (RSM)

In the present study, response surface method (RSM) and genetic algorithm (GA) were used to study the effects of process variables like screw speed, rpm (x ₁), L/D ratio (x ₂), barrel temperature (°C; x ₃), and feed mix moisture content (%; x ₄), on flow rate of biomass during single-screw extrusion cooking. A second-order regression equation was developed for flow rate in terms of the process variables. The significance of the process variables based on Pareto chart indicated that screw speed and feed mix moisture content had the most influence followed by L/D ratio and barrel temperature on the flow rate. RSM analysis indicated that a screw speed?>?80 rpm, L/D ratio?>?12, barrel temperature?>?80 °C, and feed mix moisture content?>?20% resulted in maximum flow rate. Increase in screw speed and L/D ratio increased the drag flow and also the path of traverse of the feed mix inside the extruder resulting in more shear. The presence of lipids of about 35% in the biomass feed mix might have induced a lubrication effect and has significantly influenced the flow rate. The second-order regression equations were further used as the objective function for optimization using genetic algorithm. A population of 100 and iterations of 100 have successfully led to convergence the optimum. The maximum and minimum flow rates obtained using GA were 13.19?×?10^?7 m³/s (x ₁?=?139.08 rpm, x ₂?=?15.90, x ₃?=?99.56 °C, and x ₄?=?59.72%) and 0.53?×?10^?7 m³/s (x ₁?=?59.65 rpm, x ₂?=?11.93, x ₃?=?68.98 °C, and x ₄?=?20.04%).